Reactivity of Surface Hydroxyl Groups with Metal Complex Compounds

  • T. Yamada
  • Y. Kuroda
  • A. Fukuoka
  • M. Ichikawa
  • K. Tanaka
Conference paper
Part of the Springer Series in Materials Science book series (SSMATERIALS, volume 17)

Abstract

The surface reaction of the adsorbed hydroxyl group OH(a) with
$$Rh{\left( {CO} \right)_2}\left( {\pi - {C_3}{H_5}} \right)$$
delivered from the gas phase:
$$OH\left( a \right) + Rh{\left( {CO} \right)_2}\left( {\pi - {C_3}{H_5}} \right)\left( g \right) \to O - Rh{\left( {CO} \right)_2}\left( a \right) + {C_3}{H_6}\left( {a/g} \right)$$
has been studied on Ni(110), Ni(100) and ZnO(
$$10\bar 10$$
) mainly by HREELS and TPRS. On Ni(110), p(2 × 1)-OH(a) was completely diminished by adsorption of
$$Rh{\left( {CO} \right)_2}\left( {\pi - {C_3}{H_5}} \right)$$
below 300 K. C3H6 stayed on the surface after this reaction. On ZnO(
$$10\bar 10$$
) OH(a) was deposited with surface defects introduced by Ar ion bombardment. The sane reaction occurred with OH(a) on ZnO(
$$10\bar 10$$
), but not completely on Ni(100) which was covered with oxide layers.

Keywords

Zinc Hydroxyl Argon Catalysis Propylene 

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Copyright information

© Springer-Verlag Berlin, Heidelberg 1992

Authors and Affiliations

  • T. Yamada
    • 1
  • Y. Kuroda
    • 1
  • A. Fukuoka
    • 1
  • M. Ichikawa
    • 1
  • K. Tanaka
    • 1
  1. 1.The Institute for Solid State PhysicsThe University of TokyoMinato-ku, Tokyo 106Japan

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