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Intercalation of Graphite Fibers

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Graphite Intercalation Compounds II

Part of the book series: Springer Series in ((SSMATERIALS,volume 18))

Abstract

Intercalated carbon fibers are of interest for both applications and basic science. The availability of intercalation compounds in fibrous form opens up a number of scientific opportunities, many of which exploit the favorable geometry of fibrous samples. For example, the large aspect ratio (length/diameter) greatly improves the sensitivity of transport measurements such as resistivity, magnetoresistance, thermopower, and thermal conductivity, thereby allowing systematic investigations of these properties to be made in graphite intercalation compounds (GICs). For this reason, there is a strong connection between the study of transport properties in GICs (Chap. 6) and the present review of intercalated carbon fibers. For example, with fibrous intercalation compounds it has been possible to separate the lattice and electronic contributions to the thermal conductivity of GICs by measuring the thermal and electrical conductivities on the same fiber sample and invoking the Wiedemann-Franz law [8.1]. The small fiber diameters are of particular utility for structural studies using transmission electron microscopy, where observations can be made directly without thinning of the specimens. The small fiber diameters also allow preparation of compounds not readily synthesized in bulk form, such as stage-1 NiCl2 GICs.

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Authors
  1. Mildred S. Dresselhaus
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  2. Morinobu Endo
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Editors and Affiliations

  1. Fakultät für Physik und Astronomie, Ruhr-Universität Bochum, Universitätsstrasse 150, W-4630, Bochum 1, Fed. Rep. of Germany

    Hartmut Zabel

  2. NEC Research Institute, Inc., 4 Independence Way, 08540, Princeton, NJ, USA

    Stuart A. Solin Ph. D.

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Dresselhaus, M.S., Endo, M. (1992). Intercalation of Graphite Fibers. In: Zabel, H., Solin, S.A. (eds) Graphite Intercalation Compounds II. Springer Series in Materials Science , vol 18. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84479-9_8

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  • DOI: https://doi.org/10.1007/978-3-642-84479-9_8

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84481-2

  • Online ISBN: 978-3-642-84479-9

  • eBook Packages: Springer Book Archive

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