Across the Periodic Table

  • C. Bréchignac
  • M. F. Jarrold
  • E. E. B. Campbell
  • T. P. Martin
  • H. Haberland
  • U. Buck
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 52)

Abstract

Because of the freely mobile electrons the alkali metals are often considered as prototypes of metals well described with the free electron methods. In connection with that alkali clusters are also considered as prototypes of metals clusters. However the applicability of methods based on concepts well proven in solid state physics can start to be questionable when a cluster is very small. Going from atom to the bulk the question is from what cluster size the electronic properties of alkali clusters can be described with the free electron model? Moreover how does the quantum size effect affect their electronic structure? On the other hand how can notions such as surface tension or surface curvature be employed to interpret deviation from bulk properties concerning ionization potentials or binding energies per atom?

Keywords

Entropy Manifold Benzene Cage Arsenic 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1994

Authors and Affiliations

  • C. Bréchignac
  • M. F. Jarrold
  • E. E. B. Campbell
  • T. P. Martin
  • H. Haberland
  • U. Buck

There are no affiliations available

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