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Subpicosecond Infrared Spectroscopy: The Condensed Phase Photochemistry of Iron Carbonyls

  • P. A. Anfinrud
  • C. Han
  • T. Lian
  • R. M. Hochstrasser
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 53)

Abstract

The photochemistry of dinuclear transition metal carbonyls has been extensively studied in isolated matrices [1,2] and low temperature liquids [3,4] using conventional IR spectroscopic methods, and in ambient solution [5–8] using microsecond time-resolved IR techniques. While these studies have revealed long-lived photoproducts formed by visible and UV photolysis, they lack the time resolution necessary to address issues related to the primary events in the photodissociation of organometallic compounds.

Keywords

Iron Carbonyl Homolytic Cleavage Geminate Recombination Ultrafast Phenomenon Multipass Amplifier 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin, Heidelberg 1990

Authors and Affiliations

  • P. A. Anfinrud
    • 1
  • C. Han
    • 1
  • T. Lian
    • 1
  • R. M. Hochstrasser
    • 1
  1. 1.Department of ChemistryUniversity of PennsylvaniaPhiladelphiaUSA

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