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Resonant Desorption from Clean and Carbon-Covered Alkali Halide Surfaces: State-Specific Detection by REMPI

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Desorption Induced by Electronic Transitions DIET IV

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 19))

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Abstract

Desorption of NO from multilayer systems condensed on NaC1(100) as well as on C-films evaporated onto NaCl(100) was induced by resonant excitation of the symmetric stretch vibration υ1 of the NO cis-dimer with the frequency doubled radiation of a CO2 laser. On C-film-NaC1(100), additional non-resonant desorption was observed at lower condensate coverages (≈16 monolayers). Translational temperatures as derived from the time-of-flight distributions of the desorbed NO monomers are higher than or equal to the calculated maxima of the laser-induced surface temperatures. State-selective detection of desorbed NO molecules by resonance enhanced multi-photon ionization (REMPI) indicates rotational temperatures of 190 ± 20 K at corresponding desorbate translational temperatures of 120 K.

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Author information

Author notes

  1. H.-C. Langowski

    Present address: Philips and DuPont Optical Deutschland GmbH, Dev/PM, Postfach 1409, Hannover 1, D-3000, Fed. Rep. of Germany

Authors and Affiliations

  1. Institut für Physikalische Chemie und Elektrochemie, Universität Hannover, Callinstr. 3-3A, Hannover 1, D-3000, Fed. Rep. of Germany

    J. Heidberg, W. Claas, H.-C. Langowski, M. Suhren & M. Warskulat

Authors
  1. J. Heidberg
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  2. W. Claas
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  3. H.-C. Langowski
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  4. M. Suhren
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  5. M. Warskulat
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Editor information

Editors and Affiliations

  1. Institut für Allgemeine Physik, Technische Universität, Wiedner Hauptstrasse 8-10, Wien, A-1040, Austria

    Gerhard Betz  & Peter Varga  & 

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© 1990 Springer-Verlag Berlin, Heidelberg

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Heidberg, J., Claas, W., Langowski, HC., Suhren, M., Warskulat, M. (1990). Resonant Desorption from Clean and Carbon-Covered Alkali Halide Surfaces: State-Specific Detection by REMPI. In: Betz, G., Varga, P. (eds) Desorption Induced by Electronic Transitions DIET IV. Springer Series in Surface Sciences, vol 19. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-84145-3_28

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  • DOI: https://doi.org/10.1007/978-3-642-84145-3_28

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-84147-7

  • Online ISBN: 978-3-642-84145-3

  • eBook Packages: Springer Book Archive

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