Abstract
We explore the effects that the geometric details of heterogeneous catalysts have on their performance, in order to suggest guide-lines for the design of catalysts with optimal structures. The following geometric parameters are investigated: (a) The (fractal and non-fractal) distribution pattern of surface active sites; (b) the particle size of the catalyst; (c) the surface fractal dimension; (d) the average pore size.
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References
P. Laszlo: Acc. Chem. Res. 19, 121 (1986)
P. Laszlo: In Preparative Chemistry Using Supported Reagents ed. by P. Laszlo, Chap. 1 (academic Press, San-Diego, 1987)
G.A. Somorjai: Chemistry in Two Dimensions: Surfaces, (Cornell University Press, Ithaca, 1981)
U. Müller, K.K. Unger: In Characterization of Porous Solids, ed. by K.K. Unger, J. Rouquerol, K.S.W. Sing, H. Kral (Elsevier, Amsterdam, 1988), p. 101
B.B. Mandelbrot: The Fractal Geometry of Nature (Freeman, San-Francisco, 1982); b) H. Takayasu: Fractals (Asakura-Shoten, Toyou, 1986)
J. Feder: Fractals (Plenum, New-York, 1988); H.E. Stanley, N. Ostrowski: ed’s, On Growth and Form NATO ASI Ser. (Nijhoff, Dordrecht, 1986); L. Pietronero, E. Tossati: ed’s, Fractals in Physics (North Holland, Amsterdam, 1986)
D. Avnir, ed.: The Fractal Approach to Heterogeneous Chemistry (Wiley, Chichester, 1989)
A. Le-Mehaute: Chap. 4.1.4 in ref. 6
R. Kopelman: J. Stat. Phys. 42, 185 (1986)
L.W. Anacker, R. Kopelman: Phys. Rev. Lett. 58, 289 (1987)
J. Prasad, R. Kopelman: J. Phys. Chem. 91, 265 (1987)
G. Daccord, L. Lenormand: Nature (London) 325, 41 (1987)
G. Daccord: Phys. Rev. Lett. 58, 479 (1987)
D. Farin, D. Avnir: J. Phys. Chem. 91, 5517 (1987)
D.P.C. Fung, C. Fairbridge, R. Anderson: Fuel, 67, 753 (1988)
E. Ignatzek, P.J. Plath, U. Hundorf: Z. Phys. Chem. (Leipzig) 268, 859 (1987)
R.M. Ziff, K. Fichthorn: Phys. Rev. B 34, 2038 (1986)
K.A. Fichthorn, R.M. Ziff, E. Gulari: In Catalysis 1987 ed. by J.W. Ward (Elsevier, Amsterdam, 1988), p. 883
W.-G. Ackerman, H. Spindler: Z. Phys. Chem. (Leipzig) 269, 1000 (1988)
N. Vlachopoulos, P. Liska, J. Augusinski, M. Gratzel: J. Am. Chem. Soc. 110, 1216 (1988)
C.-I. Yang, M.A. El-Sayed, S.L. Suib: J. Phys. Chem. 91, 4440 (1987)
J.J. Carbery: J. Catal. 107, 248 (1987)
J.J. Carbery: J. Catal. 114, 277 (1988)
P. Meakin: Chem. Phys. Lett. 123, 428 (1986)
P. Pfeifer, D. Avnir, D. Farin: J. Stat. Phys. 36, 699 (1984)
P. Pfeifer, D. Avnir, D. Farin: J. Stat. Phys. 39, 263 (1985)
P. Pfeifer: Chimia 39, 120 (1985)
D. Farin, D. Avnir: In Characterization of Porous Solids ed. by K.K. Unger, D. Behrens, H. Kral, p. 421 (Elsevier, Amsterdam, 1988)
D. Farin, D. Avnir: J. Am. Chem. Soc. 110,2039 (1988)
D. Farin, D. Avnir: In Proc. 9th Congress on Catalysis,Vol. 3, p. 998, Characterization and Metal Catalysts ed. by M.J. Phillips, M. Ternan (Chem. Inst. Canada, 1988)
A. Seri-Levy, J. Samuel, D. Farin, D. Avnir: In Photochemistry on Solid Surfaces ed. by M. Anpo, T. Matsuura (Elsevier, Amsterdam, 1989), p. 353
T.H.P. Chang et al: IBM J. Res. Develop. 32, 462 (1988)
C.B. Roxolo, H.W. Beck, B. Abeles: Phys. Rev. Lett. 57, 2462 (1986)
G. Guo, X. Huang, Y. Tang: preprint, 1988
S. Aubry: J. Phys. 44, 147 (1983)
T. Kleiser, M. Boceck: Z. Metallkde 77, 582 (1986);
B. Sprusil, F. Hnilica: Czech. J. Phys. 35, 897 (1985)
R. Silva, O.L. Perez, A.E. Gonzalez, M.J. Yacaman: Phys. Rev. Lett. 57, 2552 (1986)
T. Pajkossy, L. Nyikos: Electrochim. Acta 34, 181 (1989)
M.L. Kagan, O. Citri, R. Kosloff, D. Avnir: J. Phys. Chem. 93, 2728 (1989)
D. Kosloff, R. Kosloff: J. Compt. Phys. 52, 35 (1983)
A. Seri-Levy, D. Farin, O. Citri, D. Avnir: Proc. Klaus Symp. on Tribology,ACS Symp. Ser. ed by S. Hsu et al (1989, in press)
O. Citri et al: in preparation
D. Avnir, D. Farin, P. Pfeifer: J. Colloid Interface Sci. 103, 112 (1985)
D. Avnir, D. Farin, P. Pfeifer: Nature (London) 308, 261 (1984)
H. Van Damme, J.J. Fripiat: J. Chem. Phys. 82, 2785 (1985)
C. Fair-bridge, H.S. Ng, A.D. Palmer: Fuel 65, 1759 (1986)
S.H. Ng, C. Fairbridge, B.H. Kaye: Langmuir 3, 340 (1987)
R.R. Mather: Preprint 1989
M. Ben Ohud, F. Obrecht, L. Gatineau, P. Levitz, H. Van Damme: J. Coll. Interface Sci. 156, 124 (1988)
H. Van Damme, P. Levitz, L. Gatineau, J.F. Alcover, J.J. Fripiat: J. Colloid Interface Sci. 122, 1 (1988)
P. Pfeifer, D. Avnir: J. Chem. Phys. 79, 3558 (1983)
P. Pfeifer, D. Avnir: J. Chem. Phys. 80, 4573 (1984)
M. Boudart, G. Djega-Mariadassou: Kinetics of Heterogeneous Catalytic Reactions (Princeton University Press, Princeton, 1982)
M. Silverberg, D. Farin, A. Ben-Shaul, D. Avnir: Ann. Isr. Phys. Soc. 8, 451 (1986)
C.W. Curtis, J.A. Guin, B.L. Kamajian, B.L. Moody: Fuel Process Technol. 12, 111 (1986)
L. Nyikos, T. Pajkossy: Electrochim. Acta 31, 1347 (1986)
P.-G. de-Gennes: C.R. Hebd. Sc. Acad. Sci. Ser. II 295, 685 (1982)
A. Seri-Levy, P. Pfeifer, D. Avnir: in preparation
N.J. Turro: Tetrahedron 43, 1589 (1987)
E. Wellner, M. Ottolenghi, D. Avnir, D. Huppert: Langmuir 2, 616 (1986)
J.M. Drake, P. Levitz, N.J. Turro, K.S. Nitche, K.F. Cassidy: J. Phys. Chem. 92, 4680 (1988)
H.H. Weetal: In Methods in Enzymology ed. by K. Moosbach, Vol. 44 (Academic Press, New-York, 1976)
T. Medinger, F. Wilkinson: Trans. Faraday Soc. 62, 1785 (1962)
D. Pines, D. Huppert: Chem. Phys. Lett. submitted, 1989
A. Hohr, H.-B. Neuman, M. Steiner, P.W. Schmidt, P. Pfeifer, D. Avnir: Phys. Rev. B 38, 1462 (1988)
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Avnir, D., Citri, O., Farin, D., Ottolenghi, M., Samuel, J., Seri-Levy, A. (1989). Optimization of Heterogeneous-Catalyst Structure: Simulations and Experiments with Fractal and Non-Fractal Systems. In: Plath, P.J. (eds) Optimal Structures in Heterogeneous Reaction Systems. Springer Series in Synergetics, vol 44. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83899-6_3
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DOI: https://doi.org/10.1007/978-3-642-83899-6_3
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