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Electron Transport Properties Connected with Oxygen Nonstoichiometry

  • Bernard Raveau
  • Claude Michel
  • Maryvonne Hervieu
  • Daniel Groult
Chapter
  • 99 Downloads
Part of the Springer Series in Materials Science book series (SSMATERIALS, volume 15)

Abstract

Of the copper oxides described in Chap.2, only those whose structure is either an oxygen-deficient perovskite, or an intergrowth of the rock-salt-type structure and the perovskite structure, present various electron transport properties leading to semiconducting, metallic or superconducting behavior. These properties are due to copper, which exhibits a mixed valence in these oxides that seems to be enhanced by the localization of copper in the perovskite parts of the structures. In this chapter we focus our attention on the electron transport properties of cuprates whose structures are related to the perovskite structure, whether they are superconductors or not. As will be shown, these properties are greatly influenced by the oxygen content, which governs the mixed valence of copper, and depends on the thermal treatment and on the composition. For superconducting materials, only the properties of the 40 and 90 K superconductors and the influence of cationic substitutions not on copper sites will be discussed here; substitutions for copper will be treated in Chap.4.

Keywords

Oxygen Vacancy Seebeck Coefficient Thermoelectric Power Superconducting Property Anionic Vacancy 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1991

Authors and Affiliations

  • Bernard Raveau
    • 1
  • Claude Michel
    • 1
  • Maryvonne Hervieu
    • 1
  • Daniel Groult
    • 1
  1. 1.Lab. de Cristallographie et Sciences des MatériauxCaen CedexFrance

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