Abstract
In this chapter, starting from the equation of motion for molecules, we briefly summarize the formulas for molecular energy states and levels, including molecular electronic states, vibration-rotational levels and Rydberg states. We treat the energy-level shifts and splittings due to the intramolecular dynamics and angular-momentum couplings as individual perturbations, and list the selection rules for various molecular transitions. Fundamentals and discussions may be found in [2.1, 2].
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References
G. Herzberg: Molecular Spectra and Molecular Structure I. Spectra of Diatomic Molecuels; II. Infrared and Raman Spectra of Polyatomic Molecules; and III. Electronic Spectra and Electronic Structure of Polyatomic Molecules (Van Nostrand, New York 1950; 1945; and 1966 )
C.H. Townes, A.L. Schawlow: Microwave Spectroscopy( McGraw-Hill, New York 1955 )
G. Jeung: J. Phys. B: At. Mol. Phys. 16, 4289 (1983)
Li Li, S.F. Rice, R.W. Field: J. Mol. Spectrosc. 105, 344 (1984)
Yao Zhao, Zhiye Shen, Qingshi Zhu, Cunhao Zhang: J. Mol. Spectrosc. 115, 34 (1986)
I. Kovacs: Foundation of the theory of diatomic molecules. In Atoms, Molecules and Lasers, Lectures International Winter College ( IAEA, Vienna 1974 ) p. 377
H. Lefebvre-Brion: Perturbations in the spectra of diatomic molecules. In ibid. p.411
W.G. Sturrus, P.E. Sobol, S.R. Lumdeen: Phys. Rev. Lett. 54, 792 (1985)
C.F. Barnett, J.A. Ray, A. Russeic Phys. Rev. A5, 2110 (1972)
S.M. Tarr, J.A. Schiavone, R.S. Freund Phys. Rev. Lett. 44, 1660 (1980)
G. Herzberg, Ch. Jungen: J. Mol. Spectrosc. 41, 425 (1972)
R.A. Bernheim, L.P. Gold, T. Tipton: J. Chem. Phys. 78, 3635 (1983)
M.W. McGeoch, R.E. Schlier. Chem. Phys. Lett. 99, 347 (1983)
D. Eisel, W. Demtröder, W. Mueller, P. Botschwina: Chem. Phys. 80, 329 (1983)
B. Hemmerling, S.B. Rai, W. Demtröder. Z. Phys. A 320, 135 (1985)
N.W. Carlson, A.J. Taylor, K.M. Jones, A.L. Schawlow Phys. Rev. A 24, 822 (1981)
S. Martin, J. Chevaleyre, S. Valignat, J.P. Perrot, M. Broyer, B. Cabaud, A. Hoareau: Chem. Phys. Lett. 87, 235 (1982)
S. Leutwyler. T. Heinis, M. Jungen, H.P. Haerri, E. Schumacher. J. Phys. 76, 4290 (1982)
M. Broyer, J. Chevaleyre, G. Delacrelaz, S. Martin, L. Woeste: Chem. Phys. Lett. 99, 206 (1983)
A.F.J. Van’’Raan, J.E.M. Haverkort, B.L. Mehta, J. Korving: J. Phys. B 15, L669 (1982)
M. Raab, G. Honing, W. Demtröder, C.R. Vidal: J. Chem. Phys. 76, 4370 (1982)
Takanori Suzuki, Masao Kakimoto, Takahiro Kasuya Rem Kagaku Kenjyu 4, 13 (1982)
E.S. Chang, K. Yoshino: J. Phys. B 16, L581 (1983)
S. Chung, C.C. Lin, E.T.P. Lee: J. Chem. Phys. 82, 342 (1985)
A.R. Filippelli: Avail. Univ. Microfilms Int., Order No DA8421929. Diss. Abstr. Int. B45, 2587 (1985)
H. Sambe, D.E. Ramaker Chem. Phys. 107, 351 (1986)
S.E. Kupriyanov, A.A. Perov, A.Yu. Zayats, A.N. Stepanov: Pis’ma. Zh. Tekh. Fiz. 7, 861, (1981)
A. Sur, C.V. Ramana, S.D. Colson: J. Chem. Phys. 83, 904 (1985)
E.E. Eyler, F.M. Pipkin: Phys. Rev. A27, 2462 (1983)
P. Hvelplund, H.K. Haugen, H. Knudsen, L. Andersen, H. Damsgaard, F. Fukusawa Phys. Scr. 24, 40 (1981)
W.G. Sturrus, P.E. Sobol, S.R. Lundeen: Phys. Rev. Lett. 54, 792 (1985)
G.V. Golubkov, G.K. Ivanov, I.E. Cherlina Opt. Spektrosk. 54, 427 (1983)
H. Takagi, H. Nakamura J. Chem. Phys. 74, 5808 (1981)
G. Herzberg, Ch. Jungen: J. Chem. Phys. 77, 5876 (1982)
G.V. Golubkov, G.K. Ivanov: Zh. Eksp. Teor. Fiz. 80, 1321 (1981)
J.A. Dagata Avail. Univ. Microfilms Int., Order No. DA8409577. Diss. Abstr. Int. B 45, 1479 (1984)
E.E. Eyler, R.C. Short, F.M. Pipkin: Phys. Rev. Lett. 56, 2602 (1986)
H. Helm: Dynamic processes in molecular Rydberg states, in Fundamentals of Laser Interactions, ed. by F. Ehlotzky, Lect. Notes Phys., Vol.229 (Springer, Berlin, Heidelberg 1985 ) pp. 208–220
N. Bjerre, R. Kachru, H. Helm: Phys. Rev. A 31, 1206 (1985)
Li Jiaming, Lan Vo Ky. Commun. Theor. Phys. 2, 1175 (1983)
F. Greif), A. Kapur. J. Chem. Phys. 77, 415 (1982)
K. Kaufmann, C. Nager, M. Jungen: Chem. Phys. 95, 385 (1985)
C. Henriet, G. Verhaegen: THEOCHEM 16, 63 (1984)
Y. Houbrechts, I. Dubois, H. Bredohl J. Phys. B 15, 603 (1982)
Y. Houbrechts, I. Dubois, H. Bredohl J. Phys. B 15, 4551 (1982)
F. Grein, A. Kapur. J. Chem Phys. 78, 339 (1983)
C.Y.R. Wu: J. Chem. Phys. 76, 4301 (1982)
Y. Ono, S.H. Linn, H.F. Prest, M.E. Gress, C.Y. Ng: J. Chem. Phys. 74, 1125 (1981)
A.Yu. Zayats, A.A. Perov, A.P. Simonov: Khim. Vys. Energ. 18, 182 (1984)
A.Yu Zayats, A.A. Perov, A.P. Simonov: Khim. Fiz. (3) 333–338 (1983)
G. Herzberg: J. Chem. Phys. 70, 4806 (1979)
G. Herzberg: Faraday Discuss. 71, 165 (1981)
S. Raynor, D.R. Herschbach: J. Phys. Chem. 86, 1214 (1982)
G. Herzberg, Ch. Jungen: J. Chem. Phys. 84, 1181 (1986)
S. Raynor, D.R. Herschbach: J. Phys. Chem. 86, 3592 (1982)
M.N. Ediger, N. Marwood: Avail. Univ. Microfilms Int., Order No. DA8600167. Diss. Abstr. Int. B 46, 3955 (1986)
P.M. Dehmer. J. Chem. Phys. 83, 24 (1985)
M.A. Baig, J.P. Connerade, J. Dagata, S.P. McGlynn: J. Phys. B 14, L25 (1981)
A.M. Woodward, S.D. Colson, W.A. Chupka, M.G. White: J. Phys. Chem. 90, 274 (1986)
J.M. Wiesenfeld, B.I. Benjamin: Phys. Rev. Lett. 51, 1745 (1983)
M.A.C. Nascimento, A. William Chem. Phys. 53, 251 (1980)
M.A.C. Nascimento, A. William Chem. Phys. 53, 265 (1980)
S.R. Prasad, A. N. Singh Indian J. Phys. 59B, 1 (1985)
Ch. Jungen, E. Miescher. Can. J. Phys. 47, 1769 (1969)
E. Miescher. ibid 54, 2074 (1976)
P. Arrowsmith, W.J. Jones, R.P. Tuckett J. Mol. Spectrosc. 86, 216 (1981)
K. Yoshino, D.E. Freeman: Can. J. Phys. 62, 1478 (1984)
C.A. Mayhew, J.P. Connerade, M.A. Baigs, M.N.R. Ashfold, J.M. Bayler, R.N. Dixon, J.D. Prince: J. Chem. Soc. Faraday Trans. II, 83, Pt. 2, 417 (1987)
C.A. Mayhew, J.P. Connerrade, M.A. Baigs: J. Phys. B 19, 4149 (1986)
N.W. Carlson, F.V. Kowalski, R.E. Teets, A.L. Schawlow: Opt. Commun. 29, 302 (1979)
A.J. Taylor, K.M. Jones, A.L. Schawlow Opt. Commun. 39, 47 (1981)
F.V. Kowalski, W.T. Hill, A.L. Schawlow Opt. Lett. 2, 112 (1978)
P.M. Dehmer, W.A. Chupka: J. Chem. Phys. 65, 2243 (1976)
H.R. Xia, Z.G. Wang: In Laser, Spectroscopy and New Ideas, ed. by W.M. Yen, M.D. Levenson, Springer Ser. Opt. Sci., Vol.54 (Springer, Berlin, Heidelberg 1987 ) p. 174
U. Fano: Phys. Rev. A2, 353 (1970)
M.J. Seaton: Rep. Prog. Phys. 46, 97 (1983)
U. Fano: Rep. Prog. Phys. 46, 167 (1983)
S. Martin, J. Chevalleyre, M. Chr. Bordas, S. Valignat, M. Broyer, B. Cabaud, A. Hoareau: In Laser Spectroscopy VI, ed. by H.P. Weber, W. Lüthy, Springer Ser. Opt. Sci. Vol.40 (Springer, Berlin, Heidelberg 1983 ) p. 245
C. Bordas, M. Broyer, J. Chevaleyre, P. Labastie, B. Tribollet Stud. Phys. Theor. Chem. 35, 451 (1985)
G.V. Golubkov, G.K. Ivanov: Zh. Eksp. Teor. Fiz. 80, 1321 (1981)
H. Takagi, H. Nakamura J. Chem. Phys. 74, 5808 (1981)
G.V. Golubkov, G.K. Ivanov, I.E. Cherlina: Opt. Spektrosk. 54, 427 (1983)
J.M. Li, V.K. Lan: Commun. Theor. Phys. 2, 1175 (1983)
P.M. Dehmer. Comments At. Mol. Phys. 13, 205 (1983)
W.L. Glab, J.P. Hessler. Phys. Rev. A35, 2102 (1987)
W. Boehmer, R. Haensel, N. Schwentner, E. Boursey, M. Chergui: Chem. Phys. Lett. 91, 66 (1982)
W.G. Sturrus, P.E. Sobol, S.R. Lundeen: Phys. Rev. Lett. 54, 792 (1985)
W.G. Sturrus, E.A. Hessels, S.R. Lundeen: Phys. Rev. Lett. 57, 1863 (1986)
W. Demtröder, U. Diemer, H.J. Foth, R. Kullmer, G. Persch, H.J. Vedder, H. Weickenmeier. High resolution molecular spectroscopy with Lasers. In Colloq. Spectrosc. Int. XXIV-CSI XXIV(Springer, Berlin, Heidelberg 1986 ) pp. 109–115
K.M. Jones: Rydberg states in diatomic sodium. PhD Thesis, Stanford University (1983)
P. Labastie, M.C. Bordas, B. Tribollet, M. Broyer. Phys. Rev. Lett. 52, 1681 (1984)
Li Li, R.W. Field: J. Mol. Spectrosc. 117, 245 (1986)
G.P. Morgan, H.R. Xia, A.L. Schawlow: J. Opt. Soc. Am. 72, 315 (1982)
E.E. Eyler, R.C. Short, F.M. Pipkin: Phys. Rev. Lett. 56, 2602 (1986)
R.D. Knight, L.-G. Wang: Phys. Rev. Lett. 55, 1571 (1985)
A.J. Taylor, K.M. Jones, A.L. Schawlow J. Opt. Soc. Am. 73, 994 (1983)
H.R. Xia, L.S. Ma, J.W. Xu, M. Yuan, I.S. Cheng: Study of g-parity triplet states by near-resonant equal-frequency two-photon transitions in Na2, ‘87 Int’l Conf. on Laser, Xiamen, China (1987)
A.L. Schawlow Spectroscopy in a new light. Nobel Prize Lecture. In Les Prix Nobel(Nobel Foundation, Stockholm 1982); Rev. Modern Phys. 54, 687 (1982)
N.W. Carlson: Identification of excited states of diatomic sodium by two-step polarization labeling. PhD Thesis, Stanford University (1980)
A.J. Taylor: Two-step polarization labeling spectroscopy of excited states of diatomic sodium. PhD Thesis, Stanford University (1982)
M.N.R. Ashfold: Mol. Phys. 58, 1–20 (1986)
H. Shinohara, K. Sato, Y. Achiba, N. Nishi, K. Kimura: Chem. Phys. Lett. 130, 231 (1986)
J.L. Hall, J.A. Magyar. High resolution saturated absorption studies of methane and some methyl-halides. In High-Resolution Laser Spectroscopy, ed. by K. Shimoda, Topics Appl. Phys., Vol.13 (Springer, Berlin, Heidelberg 1976 ) pp. 174–199
M.D. Levenson, A.L. Schawlow: Phys. Rev. A 6, 10 (1972)
J.B. Atkinson, J. Becker, W. Demtröder. Chem. Phys. Lett. 87, 92 (1982)
J.B. Atkinson, J. Becker, W. Demtröder: Chem. Phys. Lett. 87, 128 (1982)
H.R. Xia, L.S. Ma, J.W. Xu, M. Yuan, I.S. Cheng: Opt. Commun., submitted
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Wang, ZG., Xia, HR. (1991). Molecular Energy States. In: Molecular and Laser Spectroscopy. Springer Series in Chemical Physics, vol 50. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83718-0_2
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