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Cooperative Phenomena. Structural Phase Transitions

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Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 49)

Abstract

In this chapter the ordering of Jahn-Teller and pseudo-Jahn-Teller local distortions in crystals is considered. In the case of Jahn-Teller distortions the cooperative Jahn-Teller effect considered in Sect. 6.1 takes place. The ordering of pseudo-Jahn-Teller distortions as well as Jahn-Teller distortions in some noncentrosymmetrical crystals may lead to spontaneous polarization of the lattice and to ferroelectricity (Sect. 6.2). In Sect. 6.3 the vibronic model of structural phase transformations in condensed media is discussed.

Keywords

Elementary Cell Structural Phase Transition Spontaneous Polarization Ferroelectric Phase Transition Local Distortion 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Springer-Verlag Berlin Heidelberg 1989

Authors and Affiliations

  1. 1.Department of Quantum ChemistryInstitute of Chemistry Academy of Sciences MoSSRKishinevUSSR

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