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Optical Absorption Spectra of Thallous Halides in the Extreme Ultraviolet Region

  • K. Soda
  • A. Mikuni
  • H. Kanzaki
  • T. Ishii
Conference paper
Part of the Springer Series in Solid-State Sciences book series (SSSOL, volume 81)

Abstract

The Cl L2, 3 and the Tl N6, 7 absorption spectra of T1Cl and the Br M2, 3 and the Tl N6,7 absorption’ spectra of TlBr have been measured at room temperature. In the Cl L2, 3 absorption spectrum, spectral features spread in the region up to 15 ev above the threshold and a huge absorption band follows above it. The absorption intensity is relatively weak near the threshold. The Br M2, 3 absorption is very weak. The decomposed M3 and M2 spectra show a single major peak probably with a second peak on the high energy side. The Tl N6, 7 absorption spectra of T1C1 and TIBr are quite similar to each other, indicating that the corresponding electronic transition is localized on the Tl+ ion. The spin-orbit component bands, N6 and N7, have double peaks at the thresholds and no other fine structure is found. These aspects of the observed spectra are discussed in terms of the localized excitation such as the core exciton formation and the incomplete relaxation caused by the very fast decay of the excited state through the Auger process as well as the delocalized excitation such as the charge transfer transition.

Keywords

Conduction Band Chain Line Wannier Exciton Charge Transfer Type Trion State 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    A. Kotani, Y. Toyozawa: In Synchrotron Radiation, Techniques and Applications, ed. by C. Kunz (Springer-Verlag, Berlin and Heidelberg, 1979) Chapt. 4 C.-0. Almbladt, L Hedin: In Handbook on Synchrotron Radiation, ed. by E. E. Koch, D. E. Eastman, Y. Farge, Vol. 1B (North-Holland, Amsterdam, New York, Oxford, 1983) Chapt. 8Google Scholar
  2. 2.
    T. Ishii: Z. Physik B 61, 435 (1985)CrossRefADSGoogle Scholar
  3. 3.
    F. Bassani, M. Altarelli: In Handbook on Synchrotron Radiation, ed. by E. E. Koch, D. E. Eastman, Y. Farge, Vol. 1A (North-Holland, Amsterdam, New York, Oxford, 1983) Chapt. 7Google Scholar
  4. 4.
    S. Nakai, M. Obashi, T. Mitsuishi, H. Maezawa, H. Oizumi, T. Fujikawa: J. Phys. Soc. Jpn. 55, 2436 (1986)CrossRefADSGoogle Scholar
  5. 5.
    S. L Hulbert, B. A. Bunker, F. C. Brown: Phys. Rev. B30, 2120 (1984)ADSGoogle Scholar
  6. 6.
    G. Van der Laan, J. Zaanen, G. A. Sawatzky, R. Karnatak, J.-M. Esteva: Phys. Rev. B33, 4253 (1986)CrossRefMathSciNetGoogle Scholar
  7. 7.
    M. Ueta, H. Kanzaki, K. Kobayashi, Y. Toyozawa, E. Hanamura: Excitonic Processes in Solids, Springer Ser. Solid-State Sci., Vol.60 (Springer, Berlin, Heidelberg, New York, Tokyo 1986) Chapt. 7Google Scholar
  8. 8.
    M. Inoue, M. Okazaki: J. Phys. Soc. Jpn. 30, 582 (1971) ibid. 31, 1313 (1971) H. Overhof, J. Trensch: Solid State Commun. 9, 53 (1971) J. Overton, J. P. Hernandez: Phys. Rev. B7, 778 (1973) J. P. Van Dyke, G. A. Samara: Phys. Rev. B11. 4935 (1975) K. Heidrich, W. Stande, J. Treusch, H. Overhof: Solid State Commun. 16, 1043 (1975)CrossRefADSGoogle Scholar
  9. 9.
    M. Schreiber, W. Schafer: Phys. Rev. 29, 2246 (1984)ADSGoogle Scholar
  10. 10.
    K. Takahei, K. Kobayashi: J. Phys. Soc. Jpn. 43, 891 (1977)CrossRefADSGoogle Scholar
  11. 11.
    S. Sato, M. Watanabe, Y. Iguchi, S. Nakai, Y. Nakamura, T. Sagawa: J. Phys. Soc. Jpn. 33, 1638 (1972)CrossRefADSGoogle Scholar
  12. 12.
    S. Sato, T. Ishii, I. Nagakura, O. Aita, S. Nakai, M. Yokota, K. Ichikawa, G. Matsuoka, S. Kono, T. Sagawa: J. Phys. Soc. Jpn. 30, 459 (1971)CrossRefADSGoogle Scholar
  13. 13.
    D. C. Hinson, J. R. Stevenson: Phys. Rev. 159, 711 (1967)CrossRefADSGoogle Scholar
  14. 14.
    T. Ishii, M. Taniguchi, A. Kakizaki, K. Naito, H. Sugawara, I. Nagakura: Phys. Rev. B33, 5664 (1986)ADSGoogle Scholar
  15. 15.
    M. Cardona, L. Ley, (eds).: Photoemission in Solids I and II (Springer-Verlag, Berlin, Heidelberg, 1978)Google Scholar
  16. 16.
    J. C. Fuggle, N. Martensson: J. Electron Spectrosc. Relat. Phenom. 21, 257 (1980)CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • K. Soda
    • 1
  • A. Mikuni
    • 2
  • H. Kanzaki
    • 3
  • T. Ishii
    • 1
  1. 1.Institute for Solid State PhysicsUniversity of TokyoMinato-ku, Tokyo 106Japan
  2. 2.Photon FactoryNational Laboratory for High Energy PhysicsOho-machi, Ibaraki 305Japan
  3. 3.Fuji Film Research LaboratoryMinami-Ashigara, KanagawaJapan

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