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Photoemission Satellites and Their Implications for the Electronic and Magnetic Properties of 3d Transition-Metal Compounds

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Core-Level Spectroscopy in Condensed Systems

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 81))

Abstract

Satellite structures in the valence-band photoemission spectra of late 3d transition-metal oxides and sulphides have been analyzed with use of the configuration-interaction cluster model. The 3d intra-atomic Coulomb energy is found to be generally larger than the one-electron d-band width and hybridization with the ligand p states is found to be important. These findings are basically correct even for metallic systems showing Pauli paramagnetism. Therefore, the electronic and magnetic properties of these compounds should be studied in terms of the periodic Anderson model rather than the traditional Mott-Hubbard model.

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Author information

Authors and Affiliations

  1. National Institute for Research in Inorganic Materials Sakura-mura, Niihari-gun, Ibaraki 305, Japan

    A. Fujimori

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  1. A. Fujimori
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Editor information

Editors and Affiliations

  1. Department of Physics, Faculty of Science, Osaka University, Toyonaka, Osaka 560, Japan

    Junjiro Kanamori

  2. Department of Physics, Faculty of Science, Tohoku University, Aramaki, Aoba, Sendai 980, Japan

    Akio Kotani

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© 1988 Springer-Verlag Berlin Heidelberg

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Fujimori, A. (1988). Photoemission Satellites and Their Implications for the Electronic and Magnetic Properties of 3d Transition-Metal Compounds. In: Kanamori, J., Kotani, A. (eds) Core-Level Spectroscopy in Condensed Systems. Springer Series in Solid-State Sciences, vol 81. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83437-0_11

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  • DOI: https://doi.org/10.1007/978-3-642-83437-0_11

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-83439-4

  • Online ISBN: 978-3-642-83437-0

  • eBook Packages: Springer Book Archive

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