Photoemission Satellites and Their Implications for the Electronic and Magnetic Properties of 3d Transition-Metal Compounds

  • A. Fujimori
Conference paper
Part of the Springer Series in Solid-State Sciences book series (SSSOL, volume 81)

Abstract

Satellite structures in the valence-band photoemission spectra of late 3d transition-metal oxides and sulphides have been analyzed with use of the configuration-interaction cluster model. The 3d intra-atomic Coulomb energy is found to be generally larger than the one-electron d-band width and hybridization with the ligand p states is found to be important. These findings are basically correct even for metallic systems showing Pauli paramagnetism. Therefore, the electronic and magnetic properties of these compounds should be studied in terms of the periodic Anderson model rather than the traditional Mott-Hubbard model.

Keywords

Sulphide Pyrite Ferro 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1988

Authors and Affiliations

  • A. Fujimori
    • 1
  1. 1.National Institute for Research in Inorganic Materials Sakura-muraNiihari-gun, Ibaraki 305Japan

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