Abstract
The origin of satellite structures in the 2p core level photoemission spectra of the late 3d transition metal dihalides is studied. It is found that the charge-transfer model of Larsson [1] and Sawatzky et al [2,3] accounts for the positions and intensities of main and satellite peaks very well in these compounds. The parameter values in this model are reasonable, and show the expected trends along the ligand series from fluorine to bromine as well as along the transition metal series from copper to manganese. This shows that the screening response is important in the presence of a core-hole even for insulators.
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© 1988 Springer-Verlag Berlin Heidelberg
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Oh, SJ. (1988). Origin of 2p Core-Level XPS Satellites in the Late 3d Transition Metal Dihalides. In: Kanamori, J., Kotani, A. (eds) Core-Level Spectroscopy in Condensed Systems. Springer Series in Solid-State Sciences, vol 81. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83437-0_10
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DOI: https://doi.org/10.1007/978-3-642-83437-0_10
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