Skip to main content

Gas Sensors: Towards an Artificial Nose

  • Conference paper
Book cover Sensors and Sensory Systems for Advanced Robots

Part of the book series: NATO ASI Series ((NATO ASI F,volume 43))

Abstract

The design of an artificial nose requires (a) a knowledge of the “olfactory language”, i.e. the molecular parameters of the odorants that are measured by specific receptors in the nasal mucosa; (b) the availability of gas sensors, specific, reversible and sensitive, able to convert chemical informations into electric signals.

For what concerns the understanding of odour recognition at the molecular level, it is known that specific receptor proteins, present in the olfactory mucosa, discriminate the various molecular structures on the basis of size, shape and position of functional groups: in this process the hydrocarbon part of the molecule is often very critical.

Gas sensors, based on polymers of aromatic and heteroaromatic molecules, that exhibit electrical conducting properties, can be used as specific odour detectors. Their electrical resistance varies upon interaction with several substances in the gas phase, with a specificity related both to the presence of functional groups and to the shape of the hydrocarbon part of the odorant molecule.

This characteristic, together with fast responses and high stability, make such polymers suitable for designing an artificial nose. Moreover, their organic nature would allow the synthesis of new polymers tailored for detecting particular gases or for spscific needs.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Ahlgren,G. and Krische,B.: “Composites of conducting polymers”, J. Chem. Soc. Chem. Commun.. 946 (1984)

    Google Scholar 

  2. Amoore, J.E.: “A plan to identify most of the primary odors”, in “Olfaction and Taste III”. Pfaffmann C. ed., Rockefeller Univ. Press, N.Y. (1969)

    Google Scholar 

  3. Amoore, J.E.: “Four primary odor modalities in man: experimental evidence and possible significance”, in “Olfaction and Taste V”, Denton and Cochlan eds., Acad. Press, N.Y., London (1975)

    Google Scholar 

  4. Amoore,J.E., Forrester,L.J. and Pelosi,P.: “Specific anosmia to isobutyraldehyde: the malty primary odor”, Chem. Sens, and Flav.2 17 (1976)

    Google Scholar 

  5. Amoore.J.E., Pelosi,P. and Forrester,L.J.: “Specific anosmia to 5??-androst-16-en-3-one and ??? -pentadecalactone: the urinous and musky primary odors”, Chem. Sens, and Flav.2401 (1977)

    Google Scholar 

  6. Amoore, J.E.: “Specific anosmia and the concept of primary odors”, Chem. Sens, and Flav.2, 267 (1977)

    Article  Google Scholar 

  7. Beets. M.G.J.: “Structure activity relationships in human chemoreception” Appl. Sci. Publ. Ltd, London (1978)

    Google Scholar 

  8. Bignetti, E., Cavaggioni, A., Pelosi, P., Persaud, K.C., Sorbi, R. and Tirindelli, R.: “Purification and characterisation of an odorant binding protein from cow nasal tissue”, Eur. J. Biochem. 149, 227 (1985)

    Article  Google Scholar 

  9. Bredas, J.L., Themans, B., Fripiat, J.G., Andre, J.M. and Chance, R.R.: “Highly conducting polyparaphenylene, plypyrrole and polythiophene chains: an ab initio study of thje geometry and electronic-structure modifications upon doping”. Physical Review B 29, 6761 (1984)

    Article  Google Scholar 

  10. Burgmayer, P. and Murray, R.W.: “A ion gate membrane: electrochemicalm control of ion permeability through a membrane with an embedded electrode”, J. Am. Chem. Soc. 104. 6139 (1982)

    Article  Google Scholar 

  11. Cagan, R.H. and Kare, M.R., eds. “Biochemistry of Taste and Olfaction” Acad. Press. N.Y. (1981)

    Google Scholar 

  12. Carlin, C.M, Kepley, L.J. and Bard, A.J.: “Polymer films on electrodes. XVI. In situ ellipsometric measurements of polybipyrazine, polyaniline and polyvinylferrocene films”, J. Electrochem. Soc. 132, 353 (1985)

    Article  Google Scholar 

  13. Chance, R.R., Bredas, J.L. and Silbey, R.: “Bipolaron transport in doped conjugated polymers”, Phys. Rev. B 29, 4491 (1984)

    Article  Google Scholar 

  14. Chien, J.C.W.: “Polyacetylene Physics, Chemistry and Science”, Acad. Press. N.Y. (1984)

    Google Scholar 

  15. ChieruJ.C.W.: “Mechanism of electronic conduction in organic metals”, Polym. Prepr.. 262 (1985)

    Google Scholar 

  16. Cross.M.G. and Lines,R.: “Compositions comprising an electrically conductive polymer”, U.K. Pat. 83/20646.080183 (1984)

    Google Scholar 

  17. De Paoli,M.A., Waltman,R.J., Diaz,A.F. and Bargon,J.: “Conducting composites from plyvinylchloride and polypyrrole”, J. Chem. Soc. Chem. Commun. 1015 (1984)

    Google Scholar 

  18. Diaz.A.F.. Kanazawa,K.K. and Gardini,G.P.: “Electrochemical polymerization of pyrrole”, J. Chem. Soc. Chem. Commun. 635 (1979)

    Google Scholar 

  19. Feldberg, S.W.: Reinterpretation of polypyrrole electrochemistry. Consideration of capacitive currents in redox switching of conducting polymers, J. Am. Chem. Soc. 106, 4671 (1984)

    Article  Google Scholar 

  20. Fesenko, E.E, Novoselov, V.I. and Krapivinskaya, L.D.: “Molecular mechanisms of olfactory reception. IV. Some biochemical characteristics of the camphor receptor from rat olfactory epithelium”, Biochim. Biophys. Acta 587, 424 (1979)

    Article  Google Scholar 

  21. Ford, W.K., Duke, C.B. and Salaneck, W.R. : “Electronic structure of polypyrrole and oligomers of pyrrole”, J. Chem. Phys. 77, 5030 (1982)

    Article  Google Scholar 

  22. Frank. A.J. and Honda. K.: “Visible light induced water cleavage and stabilization of n-type CdS to photocorrosion with surface attached polypyrrole catalyst coating”, J. Phys. Chem. 86, 1933 (1982)

    Article  Google Scholar 

  23. Genoud, F, Guglielmi, M, Nechtschein, M, Genies, E. and Salmon, M. : “ESR study of electrochemical doping ip the conducting polymer polypyrrole”. Phys. Rev. Lett. 55. 118 (1985)

    Article  Google Scholar 

  24. Hikita, M., Niwa, O, Sugita, A. and Tamamura, T.: “Patterning of conductive polypyrrole in polymer film”, Jpn. J. Appl. Phys. Part 2. 24. L79 (1985)

    Article  Google Scholar 

  25. Hill, H.W. and Brady, D.G.: “Polymers containing sulfur”, Encyclopedia of Chemical Technology, 18, 793 (1982)

    Google Scholar 

  26. Hotta. S, Hosaka.T. and Shimotsuma. W.: “Electrochemically prepared polythienilene films”, Synth. Metals 6, 317 (1983)

    Article  Google Scholar 

  27. Kaneto.K., Yoshino.K. and Inuishi,Y.: “Electrical properties of conducting polymer. ply-thiophene, prepared by electrochemical polymerization”, Jpn. J. Appl. Phys. 21, L567 (1982)

    Article  Google Scholar 

  28. Kitani.A.. Izumi.J.. Yano,Y., Hiromoto,Y. and Sasaki.K.: “Basic behaviours and properties of electrodeposited polyaniline”. Bull. Chem. Soc. Japan 57. 2254 (1984)

    Article  Google Scholar 

  29. Inganas.O., Erlandsson,R.. Nylander,C. and Lundstrom, I.: “Proton modification of conducting polypyrrole”, J. Phys. Chem. Solids 45, 427 (1984)

    Article  Google Scholar 

  30. Jakobs.R.C.M., Janssen,L.J.J. and Barendrecht,E.: “Behaviour of polypyrrole and poly N-methylpyrrole electrodes in acetonitrile”, Reel. J. R. Neth. Chem. Soc. 103, 275 (1984)

    Google Scholar 

  31. Lecavelier,H., Devreux,F., Nechtschein,M. and Bidan,G.: “NMR studies in Polypyrrole”. Mol. Cryst. Liq. Cryst. 118, 183 (1985)

    Article  Google Scholar 

  32. Lin.J.W.P. and Dudek,L.P.: “Synthesis and properties of poly(2.5-thienilene)” J. Polym. Sci. Polym. Chem. Ed. 18, 2869 (1980)

    Article  Google Scholar 

  33. Lindsey,S.E. and Street,G.B.: “Conductive composites from polyvinylalcohol and polypyrrole”, Synth. Metals 10, 67 (1984)

    Article  Google Scholar 

  34. Mengoli.G., Munari,M.T., Bianco,P. and Musiani,M.M.: “Anodic synthesis of polyaniline coatings onto iron sheets”, J. Appl. Polym. Sci. 26, 4247 (1981)

    Article  Google Scholar 

  35. Nayak,K. and Mark,J.E.: “Electronic band structures for a p-phenilene benzoxazole polymer”, Polym. Prepr. 272 (1985)

    Google Scholar 

  36. Niwa.O. and Tamamura.T.: “Electrochemical polymerization of pyrrole on polymer coated electrodes”, J. Chem. Soc. Chem. Commun., 817 (1984)

    Google Scholar 

  37. Niwa.O., Hikita.M. and Tamamura,T.: “Polymer-polypyrrole alloy films as semitransparent organic conductors”,Appl. Phys. Lett. 46, 444 (1985)

    Article  Google Scholar 

  38. Pfluger.P. and Street,G.B.: “Chemical, electronic and structural properties of conducting heterocyclic polymers: a view by XPS”, J. Chem. Phys. 80, 544 (1984)

    Article  Google Scholar 

  39. Pfluger,P., Gubler,U.M. and Street,G.B.: “The valence electronic structure of conducting pyrrole polymers: evidence against a linear metallic chaun picture”, Solid State Commun. 49, 911 (1984)

    Article  Google Scholar 

  40. Pelosi.P. and Viti.R.: “Specific anosmia to 1-carvone: the minty primary odour”. Chem. Sens. Flav. 3, 331 (1978)

    Article  Google Scholar 

  41. Pelosi.P. and Pisanelli.A.M.: “Specific anosmia to 1,8-cineole: the camphor primary odour”, Chem. Sens. Flav. 87 (1981)

    Google Scholar 

  42. Pelosi.P.. Pisanelli.A.M.. Baldaccini,N.E. and Gagliardo.A.: “Binding of 2-isobutyl-3-methoxypyrazine to cow olfactory mucosa”, Chem. Sens. Flav. 6. 77 (1981)

    Article  Google Scholar 

  43. Pelosi.P., Baldaccini,N.E. and Pisanelli,A.M.: “Identification of a specific olfactory receptor for 2-isobutyl-3-methoxypyrazine”, Biochem. J. 201. 245 (1982)

    Google Scholar 

  44. Pelosi.P., Pasqualetto,P.L. and Lorenzi,R.: “Synthesis and olfactory properties of some thiazoles with bell pepper like odor”, J. Agric. Food Chem. 31, 482 (1983)

    Article  Google Scholar 

  45. Persaud,K.C. and Dodd,G.H.: “Biochemical mechanisms invertebrate primary olfactory neurons”, in “Biochemistry of Taste and Olfaction” (Cagan and Kare eds.), 333, Acad. Press, N.Y. (1981)

    Google Scholar 

  46. Persaud,K.C. and Dodd,G.H.: “Analysis of discrimination mechanisms in the mammalian olfactory system using a model nose”. Nature 299, 352 (1982)

    Article  Google Scholar 

  47. Scott,J.C., Pfluger,P., Krounbi,M.T. and Street,G.B.: “Electron spin resonance studies of pyrrole polymers: evidence for bipolarons”, Phys. Rev. B 282140 (1983)

    Article  Google Scholar 

  48. Shacklette.L.W.. Elsenbaumer,R.L., Chance,R.R., Sowa.J.M., Ivory,D.M. Miller.G.G. and Baughman,R.H.: “Electrochemical doping of poly(p-phenilene) with application to organic batteries”, J. Chem. Soc. Chem. Commun. 361 (1982)

    Google Scholar 

  49. Stacy,C.J.: “Molecular weight distribution of poly-(phenilene sulfide) by high temperature gel permeation chromatography”, Polym. Prepr. 180 (1985)

    Google Scholar 

  50. Street,G.B.. Clarke.T.C., Krounbi,M., Kanazawa,K., Lee,V.Y., Pfluger,P., Scott,J.C. and Weiser,G.: “Preparation and characterization of neutral and oxidized polypyrrole films”, Mol. Cryst. Liq. Cryst. 83, 253 (1982)

    Article  Google Scholar 

  51. Street.G.B., Clarke,T.C., Geiss,R.H.. Lee,V.Y., Nazzal,A.. Pfluger,P. and Scott,J.C.: Proc. Int. Conf. on Low-Dimensional Conduyctors and Superconductors. Les Arcs, 1982. J. Phys. Coll. C3 (1983)

    Google Scholar 

  52. Tanaka.S.. Sato,M. and Kaeriyama,K.: “Electrochemical preparation and characterization of poly(2,5-thiophenediyl)”, Makromol. Chem, 185, 1295 (1984)

    Article  Google Scholar 

  53. Topazzini.A.. Pelosi,P., Pasqualetto,P.L. and Baldaccini,N.E.: “Specificity of a pyrazine binding protein from cow olfactory mucosa”, Chem. Senses 45 (1985)

    Google Scholar 

  54. Tourillon.G. and Garnier,F.: “New electrochemically generated organic conducting polymers”, J. Electroanal. Chem. 135, 173 (1982)

    Article  Google Scholar 

  55. Wernet.W.. Monkenbusch,M. and Wegner,G.: “A new series of conducting polymers with layered structure: polypyrrole n-alkylsulfates and n-alkylsulfonates”. Makromol. Chem. Rapid Commun. 5 157 (1984)

    Article  Google Scholar 

  56. Yamamoto.T., Sanechika,K. and Yamamoto,A.: “Preparation of termostable and electric conducting poly(2,5-thienilene)”, J. Polym. Sci. Polym. Lett. Ed. 18. 9 (1980)

    Article  Google Scholar 

  57. Yu.L.T.. Buvet,R.E., Vallot,R., Lauwick,B., Lanore,J.C. and Detriche,P.: “Procede de detection et d’ analise de gaz notamment pour la prevention des incendies”, Eur. Pat. 0.022.028.A1 (1981)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1988 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Pelosi, P., Persaud, K. (1988). Gas Sensors: Towards an Artificial Nose. In: Dario, P. (eds) Sensors and Sensory Systems for Advanced Robots. NATO ASI Series, vol 43. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83410-3_17

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-83410-3_17

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-83412-7

  • Online ISBN: 978-3-642-83410-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics