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Redox Mechanisms in Polyaniline Films

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Electronic Properties of Conjugated Polymers

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 76))

Abstract

In situ spectroelectrochemical and EPR studies of polyaniline (PANi) synthetized in NH F,2.3HF were carried out in association with cyclic voltammetry. The results are discussed in terms of the redox reaction mechanisms. We propose that the complete redox mechanism involves four one-electron steps and two polaron — bipolaron states in PANi films.

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Author information

Authors and Affiliations

  1. Electrochimie Moléculaire, Laboratoires de Chimie, Département de Recherche Fondamentale, Centre d’Etudes Nucléaire, 85 x, F-38041, Grenoble, France

    E. M. Genies & M. Lapkowski

  2. Member of Grenoble University, France

    E. M. Genies

  3. Institut of Inorganic Chemistry and Technology, Silesian Technical University, Gliwice, Poland

    M. Lapkowski

Authors
  1. E. M. Genies
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  2. M. Lapkowski
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Editor information

Editors and Affiliations

  1. Institut für Festkörperphysik, Universität Wien, Strudlhofgasse 4, A-1090, Wien, Austria

    Hans Kuzmany

  2. Ludwig Boltzmann Institut für Festkörperphysik, Wien, Kopernikusgasse 15, A-1090, Wien, Austria

    Hans Kuzmany

  3. Physikalisches Institut II, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring

  4. Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Siegmar Roth

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© 1987 Springer-Verlag Berlin Heidelberg

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Genies, E.M., Lapkowski, M. (1987). Redox Mechanisms in Polyaniline Films. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Conjugated Polymers. Springer Series in Solid-State Sciences, vol 76. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83284-0_38

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  • DOI: https://doi.org/10.1007/978-3-642-83284-0_38

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-83286-4

  • Online ISBN: 978-3-642-83284-0

  • eBook Packages: Springer Book Archive

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