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Triplet State ODMR of Polydiacetylene Crystals

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Electronic Properties of Conjugated Polymers

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 76))

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Abstract

The triplet state of the polymer-backbone in the polydiacetylene TS-6 (toluene-sulphonate) was investigated by ODMR (optically detected magnetic resonance) detected on the triplet-triplet-absorption. From the angular dependence the fine-structure constants D and E, as well as the orientation of the triplet state in the plane of the polymer-backbone, are obtained. The signals are detected in the temperature range between 5 K and 100 K showing changes in lineshape and a decrease of intensity with increasing temperature.

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References

  1. J. Orenstein, S. Etemad and G.L. Baker, J. Phys. C 17, L 297, (1984)

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Author information

Authors and Affiliations

  1. 3. Physikalisches Institut der Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed.Rep.of Germany

    W. Rühle & H. Sixl

  2. Hoechst AG, Angewandte Physik, D-6000, Frankfurt a.M. 80, Fed.Rep.of Germany

    W. Rühle

  3. Hoechst AG, Angewandte Physik, 6230, Frankfurt, Main 80, Fed. Rep. Germany

    H. Sixl

Authors
  1. W. Rühle
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  2. H. Sixl
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Editor information

Editors and Affiliations

  1. Institut für Festkörperphysik, Universität Wien, Strudlhofgasse 4, A-1090, Wien, Austria

    Hans Kuzmany

  2. Ludwig Boltzmann Institut für Festkörperphysik, Wien, Kopernikusgasse 15, A-1090, Wien, Austria

    Hans Kuzmany

  3. Physikalisches Institut II, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring

  4. Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Siegmar Roth

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© 1987 Springer-Verlag Berlin Heidelberg

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Rühle, W., Sixl, H. (1987). Triplet State ODMR of Polydiacetylene Crystals. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Conjugated Polymers. Springer Series in Solid-State Sciences, vol 76. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83284-0_33

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  • DOI: https://doi.org/10.1007/978-3-642-83284-0_33

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-83286-4

  • Online ISBN: 978-3-642-83284-0

  • eBook Packages: Springer Book Archive

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