Abstract
We have made the first NMR measurements during the electrochemical doping of poly(acetylene). Changes in the 7Li NMR linewidth and chemical shift were observed during doping and undoping. A hysteresis in the values of linewidth was due to the presence of two lines on undoping. The presence of these two resonances suggests two types of lithium and could be evidence for two distinct intercalation stages during undoping.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
L.W. Shacklette, J.E. Toth, Phys. Rev. B, 32 5892 (1985).
C. Fite, P. Bernier, Solid State Commun., accepted.
E. Faulques, S. Lefrant, F. Rachdi, P. Bernier, Synth. Met., 9, 53 (1984).
R. H. Baughman, L. W. Shacklette, N. S. Murthy, G. G. Miller, R. L. Elsenbaumer, Mol. Cryst. Liq. Cryst., 118, 253 (1985).
M. Nechtstein, P. Devreux, R. L. Greene, T. C. Clarke, G. B. Street, Phys. Rev. Lett., 44, 356 (1980).
M. M. Maricq, J. S. Waugh, A. G. MacDiarmid, H. Shirakawa, A. J. Heeger, J. Am. Chem. Soc, 100, 7729 (1978).
M. Audenaert, P. Bernier, Mol. Cryst. Liq. Cryst., 117, 83 (1985).
F. Masin, G. Gusman, R. Deltour, Solid State Commun., 40, 513 (1981).
M. Peo, H. Foster, K. Menke, J. Hocker, J. A. Gardner, S. Roth, K. Dransfield, Solid State Commun., 38, 467 (1981).
F. Rachdi, M. Audenaert, P. Bernier, R. J. Schweizer, In Electronic Properties of Polymers and Related Compounds, ed. by H. Kuzmany, M. Mehring, S. Roth, Springer Ser. Solid-State Sciences, vol. 63, (Springer, Berlin, Heidelberg 1985) p. 278.
A. El Khodary, P. Bernier, J. Chem. Phys. 85( 4), 2243 (1986).
T. Asai, S. Kawai, R. Nagai, S. Mochizuki, J. Phys. Chem. Solids, 45, 173 (1984).
F. Rachdi, P. Bernier, these proceedings.
P. Bernier, F. Rachdi, A. El Khodary, M. Audenaert, R. J. Schweizer, In Electronic Properties of Polymers and Related Compounds, ed. by H. Kuzmany, M. Mehring, S. Roth, Springer Ser. Solid-State Sciences, vol. 63, (Springer, Berlin, Heidelberg 1985) p. 281.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Whittaker, A.K., Fite, C., Zniber, K., Bernier, P. (1987). 7Li NMR Study of the Electrochemical Doping of Poly(acetylene). In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Conjugated Polymers. Springer Series in Solid-State Sciences, vol 76. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-83284-0_31
Download citation
DOI: https://doi.org/10.1007/978-3-642-83284-0_31
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-83286-4
Online ISBN: 978-3-642-83284-0
eBook Packages: Springer Book Archive