Skip to main content

Field Emission Microscopy - Trends and Perspectives

  • Chapter
Chemistry and Physics of Solid Surfaces VI

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 5))

Abstract

Microscopy came early to the science of surfaces, but somehow was neglected in the rush of effort applied to harvesting the many kinds of information made available by the various more popular methods of surface investigation. It is fair to consider that modern surface science originated with the impressive works of Irving Langmuir. The field grew rapidly in the late 1950s with the emerging commercial availability of reliable metal ultra-high-vacuum (UHV) apparatus, coupled with the newly simplified approach to low-energy-electron diffraction (LEED), and the rapid development of various surface spectroscopies, which attracted the majority of surface scientists to nonmicroscopic approaches to the study of surfaces. By that time, of course, optical microscopy was rather mature, electron microscopy was maturing rapidly and the field emission microscopies were experiencing a flurry (albeit of modest proportions) of activity. Optical microscopy generally was relegated to use as a test for surface smoothness by the metallographer in preparing a surface for subsequent surface study, or on a few occasions was used in an actual surface investigation. Electron microscopy was occasionally used in an investigation of surface phenomena. However, in general, neither of these microscopies was integrated into the UHV regime of the surface scientists of the 60s and 70s. Only in the past approximately five years have serious efforts been made to do electron microscopy in the UHV environment with the intention of studying surface phenomena.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R.H. Fowler, L.W. Nordheim: Proc. Rov. Soc. London, Ser.A 119, 173 (1928)

    Article  CAS  Google Scholar 

  2. E.W. Müller: Z. Phys. 106, 541 (1937)

    Article  Google Scholar 

  3. E.W. Müller: Z. Phys. 131, 136 (1951)

    Article  Google Scholar 

  4. E.W. Müller: Z. Naturforsch., Teil A 11, 88 (1956); J. Appl. Phys. 27, 474 (1956)

    Google Scholar 

  5. E.W. Müller: Naturwissenschaften 29, 533 (1941)

    Article  Google Scholar 

  6. J.W. Gibbs: Trans. Conn. Acad. 3, 108 (1876); ibid. 3, 343 (1878)

    Google Scholar 

  7. W.K. Burton, N. Cabrera, F.C. Frank: Philos. Trans. R. Soc. London 243, 299 (1950)

    Article  Google Scholar 

  8. See, for example, F.C. Frank: In Metal Surfaces: Structure, Energetics and Kinetics (American Society for Metals, Cleveland, OH 1963)

    Google Scholar 

  9. C. Herring: Phys. Rev. 82, 87 (1951); In Structure and Properties of Solid Surfaces, ed. by R. Gomer, C.S. Smith (University of Chicago Press, Chicago 1953)

    Article  CAS  Google Scholar 

  10. J.M. Blakely: Introduction to the Proverties of Crystals (Pergamon, Oxford 1973)

    Google Scholar 

  11. W. Schottky: Z. Phys. 14, 63 (1923)

    Article  CAS  Google Scholar 

  12. R.H. Good, Jr., E.W. Muller: In Electron-Emission. Gas Discharges I, Handbuch der Physik, Vol. 21 (Sprinaer, Berlin, Gottingen, Heidelberq 1956) pp. 176–231

    Google Scholar 

  13. R.D. Young: Phys. Rev. 113, 110 (1959)

    Article  CAS  Google Scholar 

  14. E.W. Müller: Ergeb. Exakten Naturwiss. 27, 290 (1953)

    Article  Google Scholar 

  15. R.P. Johnson, W. Shockley: Phys. Rev. 49, 436 (1936)

    Article  CAS  Google Scholar 

  16. E.W. Müller, T.T. Tsong: Field Ion Microscopy Principles and Applications (Elsevier, New York 1969)

    Google Scholar 

  17. R. Gomer: Field Emission and Field Ionization (Harvard University Press, Cambridge, MA 1961)

    Google Scholar 

  18. R. Haefer: Z. Phys. 116, 604 (1940)

    Article  CAS  Google Scholar 

  19. W.P. Dyke, J.K. Troian: Phys. Rev. 89, 799 (1953)

    Article  Google Scholar 

  20. A.J. Melmed: In Experimental Methods of Material Research, Vol.1, ed. by H. Herman (Interscience, New York 1967)

    Google Scholar 

  21. W.P. Dyke, W.W. Dolan: Advances in Electronics and Electron Physics, Vol.8, ed. by L. Marton (Academic, New York 1956)

    Google Scholar 

  22. D.J. Rose: J. Appl. Phys. 27, 215 (1956)

    Article  CAS  Google Scholar 

  23. E.W. Müller: Z. Phys. 108, 668 (1938)

    Article  Google Scholar 

  24. J.A. Becker: Adv. Catal. 7, 136 (1955)

    Google Scholar 

  25. E.W. Müller: Z. Elektrochem. 59, 372 (1955)

    Google Scholar 

  26. E.W. Müller: Z. Phys. 120, 261 (1943)

    Article  Google Scholar 

  27. W.P. Dyke, J.K. Troian, W.W. Dolan, F.J. Grundhauser: J. Aopl. Phys. 25, 106 (1954)

    Article  Google Scholar 

  28. A.J. Melmed, J.J. Carroll: J. Vac. Sci. Technol. 10, 164 (1973)

    Article  CAS  Google Scholar 

  29. For an extensive list of references, see A. Ciszewski, A.J. Melmed: J. Cryst. Growth 69, 253 (1984)

    Article  CAS  Google Scholar 

  30. A.J. Melmed, V. Maurice, O. Frank, J.H. Block: J. Phys. (Paris) 45, C9–47 (1984)

    Google Scholar 

  31. A.J. Ashworth: Advances in Electronics and Electron Physics, Vol.3, ed. by L. Marton (Academic, New York 1951)

    Google Scholar 

  32. E.W. Müller: Z. Naturforsch., Teil A 5, 473 (1950)

    Google Scholar 

  33. P. Wolf: Z. Angew. Phys. 6, 529 (1954)

    CAS  Google Scholar 

  34. A.J. Melmed, E.W. Müller: J. Chem. Phys. 29, 1037 (1958)

    Article  CAS  Google Scholar 

  35. E.W. Müller: Z. Naturforsch., Teil A 5, 475 (1950)

    Google Scholar 

  36. R. Haefer: Acta Phys. Austriaca 8, 105 (1953)

    CAS  Google Scholar 

  37. E. Hörl, F. Stangler: Acta Phys. Austriaca 10, 1 (1956)

    Google Scholar 

  38. J.A. Becker, R.G. Brandes: J. Appl. Phys. 27, 221 (1956)

    Article  CAS  Google Scholar 

  39. R. Gomer, D.A. Speer: J. Chem. Phys. 21, 73 (1953)

    Article  CAS  Google Scholar 

  40. A.P. Komar, A.A. Komar: Zh. Tekh. Fiz, 31, 231 (1961)

    CAS  Google Scholar 

  41. I. Giaever: Surf. Sci. 29, 1 (1972)

    Article  CAS  Google Scholar 

  42. A.J. Melmed: In Field-Ion Microscopy, ed. by J.J. Hren, S. Ranganathan (Plenum, New York 1968)

    Google Scholar 

  43. A.J. Melmed: unpublished

    Google Scholar 

  44. H. Utsugi, R. Gomer: J. Chem. Phys. 37, 1706 (1962)

    Article  CAS  Google Scholar 

  45. A. Ciszewski, A.J. Melmed: Surf. Sci. 145, L509 (1984)

    Article  CAS  Google Scholar 

  46. L.A. D’Asaro: J. Appl. Phys. 29, 33 (1958)

    Article  Google Scholar 

  47. W.D. McNeil, W.B. Shepherd: Rev. Sci. Instrum. 43, 1636 (1972)

    Article  CAS  Google Scholar 

  48. F.G. Allen: Phys. Chem. Solids, 19, 87 (1961)

    Article  CAS  Google Scholar 

  49. R. Gomer, R. Wortman, R. Lundy: J. Chem. Phys. 26, 1147 (1957)

    Article  CAS  Google Scholar 

  50. R. Wortman, R. Gomer, R. Lundy: J. Chem. Phys. 27, 1099 (1957)

    Article  CAS  Google Scholar 

  51. Ch. Kleint: Surf. Sci. 25, 394 (1971)

    Article  CAS  Google Scholar 

  52. Ch. Kleint: Surf. Sci. 25, 411 (1971)

    Article  CAS  Google Scholar 

  53. R. Gomer: Surf. Sci. 38, 373 (1973)

    Article  CAS  Google Scholar 

  54. D.R. Bowman, R. Gomer, K. Muttalib, M. Tringides: Surf. Sci. 138, 581 (1984)

    Article  CAS  Google Scholar 

  55. M. Tringides, R. Gomer: 45th Ann. Conf. Physical Electronics, Milwaukee, WI (1985)

    Google Scholar 

  56. M. Drechsler: Z. Elektrochem. 58, 340 (1954)

    CAS  Google Scholar 

  57. J.P. Jones, N.T. Jones: Thin Solid Films 35, 83 (1976)

    Article  CAS  Google Scholar 

  58. A.J. Melmed: J. Appl. Phys. 37, 275 (1966)

    Article  CAS  Google Scholar 

  59. E.W. Müller: Z. Phys. 126, 642 (1949)

    Article  Google Scholar 

  60. W.W. Müllins: J. Appl. Phys. 30, 77 (1959)

    Article  Google Scholar 

  61. J.M. Blakely, H. Mykura: Acta Metall. 9(1), 23 (1961)

    Article  CAS  Google Scholar 

  62. R. Gomer: J. Chem. Phys. 26, 1333 (1957)

    Article  CAS  Google Scholar 

  63. R. Gomer: J. Chem. Phys. 28, 457 (1958)

    Article  CAS  Google Scholar 

  64. R.L. Parker, S.C. Hardy: J. Chem. Phys. 37, 1606 (1962)

    Article  CAS  Google Scholar 

  65. A.J. Melmed, R. Gomer: J. Chem. Phys. 34, 1802 (1961)

    Article  CAS  Google Scholar 

  66. See, for example, K.L. Moazed, G.M. Pound: Trans. Metall. Soc. AIME 230, 235 (1964)

    Google Scholar 

  67. J.P. Hirth, G.M. Pound: Condensation and Evaporation (Pergamon, Oxford 1963)

    Google Scholar 

  68. A.J. Melmed: J. Appl. Phys. 36, 3585 (1965)

    Article  CAS  Google Scholar 

  69. For an extensive list of references, see M. Mundschau, R. Vanselow: Surf. Sci. 155, 121 (1985)

    Article  CAS  Google Scholar 

  70. A.J. Melmed: J. Appl. Phys. 36, 3691 (1965)

    Article  CAS  Google Scholar 

  71. R. Vanselow: Phys. Status Solidi 4, 697 (1964)

    Article  CAS  Google Scholar 

  72. M. Mundschau, R. Vanselow: Phys. Rev. Lett. 53, 1084 (1984)

    Article  CAS  Google Scholar 

  73. A.J. Melmed: unpublished results

    Google Scholar 

  74. S. Hagstrom, H.B. Lyon, G.A. Somorjai: Phys. Rev. Lett. 15, 491 (1965)

    Article  CAS  Google Scholar 

  75. J.E. Henderon, R.E. Badgley: Phys. Rev. 38, 590 (1931)

    Google Scholar 

  76. J.E. Henderson, R.K. Dahlstrom, F. Abbott: Phys. Rev. 41, 261 (1932)

    Article  Google Scholar 

  77. J.E. Henderson, R.K. Dahlstrom: Phvs. Rev. 45, 764 (1934)

    Google Scholar 

  78. J.E. Henderson, R.K. Dahlstrom: Phys. Rev. 55, 473 (1939)

    Article  CAS  Google Scholar 

  79. R.K. Dahlstrom, K.V. Mackenzie, J.E. Henderson: Phys. Rev. 48, 484 (1935)

    Google Scholar 

  80. E.W. Müller, K. Bahadur: Phys. Rev. 102, 624 (1956)

    Article  Google Scholar 

  81. R.D. Young, E.W. Muller: Phys. Rev. 113, 115 (1959)

    Article  CAS  Google Scholar 

  82. L.W. Swanson, L.C. Crouser: Phys. Rev. Lett. 16, 389 (1966)

    Article  CAS  Google Scholar 

  83. L.W. Swanson, L.C. Crouser: Phys. Rev. 163, 622 (1967)

    Article  CAS  Google Scholar 

  84. This development is described in J.W. Gadzuk, E.W. Plummer: Rev. Mod. Phys. 45, 487 (1973)

    Article  CAS  Google Scholar 

  85. C.B. Duke, M.E. Alferieff: J. Chem. Phys. 46, 923 (1967)

    Article  CAS  Google Scholar 

  86. E.W. Plummer, R.D. Younq: Phys. Rev. B 1, 2088 (1970)

    Article  Google Scholar 

  87. C. Lea, R. Gomer: J. Chem. Phys. 54, 3349 (1971)

    Article  CAS  Google Scholar 

  88. E.W. Müller: Ann. Meeting Electron Microscope Soc. America, Pennsylvania State University (1955)

    Google Scholar 

  89. K.M. Bowkett, D.A. Smith: Field Ion Microscopy (North-Holiand, Amsterdam 1970)

    Google Scholar 

  90. R. Wagner: Field-Ion Microscopy, Crystals, Vol. 6 (Springer, Berlin, Heidelberg 1982)

    Book  Google Scholar 

  91. E.W. Müller: Surf. Sci. 8, 462 (1967)

    Article  Google Scholar 

  92. L.W. Swanson, D.E. Reed, A.E. Bell: 14th Field Emission Symposium, Washington, D.C. (1967)

    Google Scholar 

  93. E.W. Muller: Advances in Electronics and Electron Physics, Vol. 13, ed. by L. Marton (Academic, New York 1960)

    Google Scholar 

  94. A.J. Melmed: Surf. Sci. 8, 191 (1967)

    Article  CAS  Google Scholar 

  95. G.L. Kellog, T.T. Tsong: J. Appl. Phys. 51(2), 1184 (1980)

    Article  Google Scholar 

  96. E.W. Müllef: Z. Elektrochem. 61, 43 (1957)

    Google Scholar 

  97. G. Ehrlich, F.G. Hudda: J. Chem. Phys. 44, 1039 (1966)

    Article  CAS  Google Scholar 

  98. T.T. Tsong: Phys. Rev. B 6, 417 (1972)

    Article  CAS  Google Scholar 

  99. D.W. Bassett, D.R. Tice: In The Physical Basis for Heterogeneous Catalysis, ed. by E. Drauglis, R.I. Jaffee (Plenum, New York 1975) p. 231

    Google Scholar 

  100. R.T. Tung, W.R. Graham: Surf. Sci. 97, 73 (1980)

    Article  CAS  Google Scholar 

  101. G. Ehrlich: In The Structure of Surfaces, ed. by M.A. Van Hove, S.Y. Tong, Springer Series Surf. Sci., Vol.2 (Springer, Berlin, Heidelberg 1985) p. 375

    Google Scholar 

  102. For a summary of results and further references, see G. Ehrlich: Proc. 9th Int. Congr. and 5th Int. conf. on Solid Surfaces, ed. by J.L. de Segovia, A.S.E.V.A., Madrid (1983), Asociacion Española de Vacio y sus Aplicaciones

    Google Scholar 

  103. T.T. Tsong, M. Ahmad: In The Structure of Surfaces, ed. by M.A. Van Hove, S.Y. Tong, Springer Series Surf. Sci., Vol.2 (Springer, Berlin, Heidelberg 1985) p. 389

    Google Scholar 

  104. R.T. Tung, W.R. Graham, A.J. Melmed: Surf. Sci. 115, 576 (1982)

    Article  CAS  Google Scholar 

  105. R.T. Tung: Ph.D. Thesis, University of Pennsylvania (1980)

    Google Scholar 

  106. K. Yonehara, L.D. Schmidt: Surf. Sci. 25, 238 (1971)

    Article  CAS  Google Scholar 

  107. T.E. Fetter, R.A. Barker, P.J. Estrup: Phys. Rev. Lett. 38, 1138 (1977)

    Article  Google Scholar 

  108. M.K. Debe, D.A. King: Surf. Sci. 81, 193 (1979)

    Article  CAS  Google Scholar 

  109. P. Heilmann, K. Heinz, K. Müller: Surf. Sci. 89, 84 (1979)

    Article  CAS  Google Scholar 

  110. J.A. Walker, M.K. Debe, D.A. King: Surf. Sci. 104, 405 (1981)

    Article  CAS  Google Scholar 

  111. T.T. Tsong, J. Sweeney: Solid State Commun. 30, 767 (1979)

    Article  CAS  Google Scholar 

  112. A.J. Melmed, R.T. Tung, W.R. Graham, G.D.W. Smith: Phys. Rev. Lett. 43, 1521 (1979)

    Article  CAS  Google Scholar 

  113. T.-M. Lu, G.-C. Wang: Surf. Sci. 107, 139 (1981)

    Article  CAS  Google Scholar 

  114. A.J. Melmed, W.R. Graham: Appl. Surf. Sci. 11/12, 470 (1982)

    Article  Google Scholar 

  115. S.T. Ceyer, A.J. Melmed, J.J. Carroll, W.R. Graham: Surf. Sci. 144, L444 (1984)

    Article  CAS  Google Scholar 

  116. A. Fasolino, G. Santoro, E. Tosatti: Phys. Rev. Lett. 44, 1684 (1980)

    Article  CAS  Google Scholar 

  117. A.J. Melmed, W.R. Graham: Surf. Sci. 123, L706 (1982)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1986 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Melmed, A.J. (1986). Field Emission Microscopy - Trends and Perspectives. In: Vanselow, R., Howe, R. (eds) Chemistry and Physics of Solid Surfaces VI. Springer Series in Surface Sciences, vol 5. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82727-3_13

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-82727-3_13

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-82729-7

  • Online ISBN: 978-3-642-82727-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics