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Secondary Ion Mass Spectrometry SIMS V pp 41–44Cite as

SIMS Study of Self-Diffusion in Liquid Tin and of Associated Isotope Effects

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Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 44))

Abstract

A Spacelab collaboration project is directed at diffusivities in liquid metals under gravity-free, g(0), conditions. Terrestrial measurements yield effective diffusion coefficients, D(eff) = D + D(g) + D(w), where the last two terms are convection effects due to, respectively, gravitation and the presence of walls in the anneal vessel. Determinations of D have therefore suffered in accuracy and reproducibility, and this has impeded the testing of atomic models of liquid diffusion. In the Spacelab project D(g) is eliminated and D(w) may be assessed by measurements of D(eff) in capillaries of different diameters. The aim is an accuracy sufficient for quantitative study not only of the temperature dependence of D, but also of the isotope effect, defined as ED = 2 dlnD/dlnM (where M is the atomic mass).

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Author information

Authors and Affiliations

  1. Physics Department, Chalmers University of Technology, S-41296, Gothenburg, Sweden

    U. Södervall, H. Odelius & A. Lodding

  2. Institute of Metal Research, Technical University Berlin, D-1000, Berlin 15, Germany

    G. Frohberg, K. H. Kraatz & H. Wever

Authors
  1. U. Södervall
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  2. H. Odelius
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  3. A. Lodding
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  4. G. Frohberg
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  5. K. H. Kraatz
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  6. H. Wever
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Editor information

Editors and Affiliations

  1. Physikalisches Institut, Universität Münster, Domagkstraße 75, D-4400, Münster, Fed. Rep. of Germany

    Alfred Benninghoven

  2. Chemistry Division, Naval Research Laboratory, 20375, Washington, DC, USA

    Richard J. Colton

  3. Center for Analytical Chemistry, National Bureau of Standards, 20899, Gaithersburg, MD, USA

    David S. Simons

  4. Philips Research Laboratories, NL-Eindhoven, The Netherlands

    Helmut W. Werner

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© 1986 Springer-Verlag Berlin Heidelberg

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Södervall, U., Odelius, H., Lodding, A., Frohberg, G., Kraatz, K.H., Wever, H. (1986). SIMS Study of Self-Diffusion in Liquid Tin and of Associated Isotope Effects. In: Benninghoven, A., Colton, R.J., Simons, D.S., Werner, H.W. (eds) Secondary Ion Mass Spectrometry SIMS V. Springer Series in Chemical Physics, vol 44. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82724-2_7

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  • DOI: https://doi.org/10.1007/978-3-642-82724-2_7

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-82726-6

  • Online ISBN: 978-3-642-82724-2

  • eBook Packages: Springer Book Archive

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