Island Formation of Adspecies and LEED
If the temperature of the surface is sufficiently low, an attractive interaction among adatoms or admolecules which are bound at sites of specific symmetry on the surface will give rise to the formation of ordered islands of the adsorbate. These islands are characterized by a local density greater than the overall density of the adsorbate on the surface. This local density is related to the two-dimensional periodicity within the ordered islands. Evidence for the formation of ordered islands has been observed quite frequently with LEED [10.1–5]. Both the thermodynamic and kinetic (e.g. adsorption, desorption, and surface diffusion) properties of an overlayer that contains islands are determined by the degree of order and the size and relative positioning of the islands [10.61 This information can be obtained using LEED since the shape (angular profile) of the diffracted electron beams is determined by the size and distribution of ordered regions of scatterers on the surface [10.7–15].
KeywordsHexagonal Convolution Sine Ruthenium Deconvolution
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- 10.3M. G. Lagally, T.-M. Lu, G.-C. Wang: in Ordering in Two Dimensions, ed. by S. Sinha (Elsevier, Amsterdam 1980); and references thereinGoogle Scholar
- 10.7J. C. Tracy, J. M. Blakely: in The Structure and Chemistry of Solid Surfaces,ed. by G. A. Somorjai (Wiley, New York 1969)Google Scholar
- 10.11G. Ertl, J. Köppers: Low Energy Electrons and Surface Chemistry (Verlag Chemie, Weinheim 1974)Google Scholar
- 10.19M. E. Fisher: in Proceedings of the Enrico Fermi International School of Physics (Academic, New York 1971)Google Scholar
- 10.20D. P. Landau: Phys. Rev. B 13, 2997 (1976)Google Scholar
- 10.22W. Moritz: in Electron Diffraction 1927–77, ed. by P. J. Dobson, J. B. Pendry, C. J. Humphreys (The Institute of Physics, London 1977) p. 261Google Scholar
- 10.25E. D. Williams, W. H. Weinberg: in Proc. Fourth Int. Conf. Solid Surfaces, Cannes (1980) p. 311Google Scholar
- 10.26L.-H. Zhao, T.-M. Lu, M. G. Lagally: Appl. Surf. Sci. 11/12, 634 (1982)Google Scholar
- 10.32T. E. Madey, D. Menzel: Jpn. J. Appl. Phys., Suppl. 2, Pt. 2, 229 (1974)Google Scholar