Abstract
Several investigators have reported that for Laser Desorption Mass Spectrometry (LDMS) with pulsed infrared lasers and foci of about 1 mm the absorption and/or heat conduction properties of the substrate have a strong influence on the spectra obtained [1, 2, 3]. For these types of LDMS, resonant absorption of the laser radiation by the sample has also been shown to effect the types and intensity of desorbed ions [4, 5]. The influence of resonant absorption and of the substrate properties either singly or as combined effects are as yet unknown,or discussed controversially for UV-LDMS [6, 7, 8].
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
F. Hillenkamp: “Laser-Induced Ion Formation from Organic Solids” (Review), in Ion Formation from Organic Solids, Springer Series in Chemical Physics 25, A. Benninghoven, ed. Springer Verlag 1983
G.J.Q. van der Peyl, J. Haverkamp and P.G. Kistemaker: Int. J. Mass Spectrom. Ion Phys. 42 (1982) 125–140.
B. Schäfer and P. Hess: Int. J. Mass Spectrom. Ion Proc. 47 (1984) 47–50.
R. Stoll and F.W. Röllgen: Z. Naturforsch. 37a (1982) 9.
M. Mashni and P. Hess: Chem. Phys. Lett. 77 (1981) 541.
D.M. Hercules, R.J. Day, K. Balasanmugam, T.A. Dang and C.D. Li: Anal. Chem. 54 (1982) 280A - 290A.
V.S. Antonov, V.S. Letokhov and A.N. Shibanov: Appl. Phys. B28 (1982) 245.
M. Karas, D. Bachmann and F. Hillenkamp: Anal. Chem., in print.
D. Holtkamp, W. Lange, M. Jirikowsky and A. Benninghoven: App. Surf. Science 17 (1984) 296–308.
P. Feigi, B. Schueler and F. Hillenkamp: Int. J. Mass Spectrom. Ion Phys. 47 (1983) 15–18.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1986 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Hillenkamp, F., Holtkamp, D., Karas, M., Klüsener, P. (1986). The Influence of the Substrate on Ultraviolet Laser Desorption Mass Spectrometry of Biomolecules. In: Benninghoven, A. (eds) Ion Formation from Organic Solids (IFOS III). Springer Proceedings in Physics, vol 9. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82718-1_29
Download citation
DOI: https://doi.org/10.1007/978-3-642-82718-1_29
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-82720-4
Online ISBN: 978-3-642-82718-1
eBook Packages: Springer Book Archive