Abstract
A quasi-one-dimensional electron lattice system is not simply a highly anisotropic three-dimensional (3-d) system when it is viewed from the standpoint of an excited electronic state and its phonon coupling. In 3-d crystals, one finds almost always an excited electronic state in the form of a Wannier or a Frenkel exciton. The former case is found in typical ionic crystals and semiconductors and the latter in molecular crystals. In quasi-one-dimensional crystals composed of a bundle of linear chains, the most frequently found excited electronic state is a charge transfer exciton. In the charge transfer exciton, an electron in a ground state in one atom is excited to a different atom at a neighbouring site and the radius of the exciton is of this order. In 3-d crystals, a charge transfer exciton is rare. Perhaps the 1s exciton in alkali halides is an example, but its characteristic property does not appear as clearly as in one-dimensional (1-d) crystals.
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© 1986 Springer-Verlag Berlin Heidelberg
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Ueta, M., Kanzaki, H., Kobayashi, K., Toyozawa, Y., Hanamura, E. (1986). Excitons and Phonon Couplings in Quasi-One-Dimensional Crystals. In: Excitonic Processes in Solids. Springer Series in Solid-State Sciences, vol 60. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82602-3_9
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DOI: https://doi.org/10.1007/978-3-642-82602-3_9
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