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Resonance Raman Scattering from Polyaniline

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Book cover Electronic Properties of Polymers and Related Compounds

Part of the book series: Springer Series in Solid-State Sciences ((SSSOL,volume 63))

Abstract

Polyaniline (PANI) in its uncontrolled and uncharacterized form (aniline black) was the subject of several mainly chemical studies for a long time [1]. However, only very recently a better understanding of its nature has been developed in connection with its excellent application potentialities as a polymeric electrode in electrochemical cells [2,3]. Four different structural forms as shown in Fig.1 have been suggested. Evidence for these forms has been obtained from chemical analysis, NMR and priliminary photoelectron spectroscopy work [3,4]. The polymer can be interconverted chemically or electrochemically between these forms by proton (acid-base) or proton and electron (oxidation-reduction) reactions.

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References

  1. M. Doriomedoff, F. Hautiere-Cristofini, R. de Surville, M. Jozefowicz, L. Yu et R.Buvet: J. Chem. Phys. 68, 39 (1971).

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  4. T. Hjertberg, W.R. Salaneck, I. Lundström, N.L.D. Somasiri and A.G. MacDiarmid, unpublished

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  5. J.C. Evans, Spectroschimica Acta, 16, 428 (1960)

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Author information

Authors and Affiliations

  1. Institut für Festkörperphysik der Universität Wien, A-1090, Wien, Austria

    H. Kuzmany

  2. Ludwig Boltzmann Institut für Festkörperphysik, A-1090, Wien, Austria

    H. Kuzmany

  3. CEN-Grenoble, F-38041, Grenoble, France

    E. M. Genies & A. Syed

Authors
  1. H. Kuzmany
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  2. E. M. Genies
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  3. A. Syed
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Editor information

Editors and Affiliations

  1. Institut für Festkörperphysik, Universität Wien, Strudlhofgasse 4, A-1090, Wien, Austria

    Hans Kuzmany

  2. Ludwig Boltzmann Institut für Festkörperphysik, Wien, Kopernikusgasse 15, A-1060, Wien, Austria

    Hans Kuzmany

  3. Physikalisches Institut II, Universität Stuttgart, Pfaffenwaldring 57, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Michael Mehring

  4. Max Planck Institut für Festkörperforschung, Heisenbergstrasse 1, D-7000, Stuttgart 80, Fed. Rep. of Germany

    Siegmar Roth

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© 1985 Springer-Verlag Berlin Heidelberg

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Kuzmany, H., Genies, E.M., Syed, A. (1985). Resonance Raman Scattering from Polyaniline. In: Kuzmany, H., Mehring, M., Roth, S. (eds) Electronic Properties of Polymers and Related Compounds. Springer Series in Solid-State Sciences, vol 63. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82569-9_40

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  • DOI: https://doi.org/10.1007/978-3-642-82569-9_40

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-82571-2

  • Online ISBN: 978-3-642-82569-9

  • eBook Packages: Springer Book Archive

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