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Helium Diffraction from Oxygen-Covered Nickel Surfaces

  • Chapter
The Structure of Surfaces

Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 2))

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Abstract

Helium atom diffraction results are presented for oxygen-covered Ni(001) and Ni(110) surfaces. For 0/Ni(001) the diffraction data has clearly favored a single vertical distance for oxygen chemisorption in both the p(2 × 2) and c(2 × 2) phases. This conclusion now seems to be quite generally accepted. For 0/Ni(110) there are several competing candidates which include among others the missing row and the saw-tooth model. We have carried out simple model theoretical calculations based on the Esbjerg-Nørskov-Lang relation between the surface charge density and helium-surface repulsive potential. We have used atomic Hartree-Fock charge densities to generate surface charge densities. The corrugation coefficients have been calculated for various geometrical configurations of oxygen on Ni. These results are compared with the experimental data in order to deduce information about the chemisorption of oxygen on Ni(110).

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Author information

Authors and Affiliations

  1. IBM Research Laboratory, K33/281, San Jose, 95193, CA, USA

    Inder P. Batra

  2. Department of Chemistry, University of Washington, 98195, Seattle, WA, USA

    T. Engel

  3. IBM Zurich Research Laboratory, CH-8803, Rüschlikon, Switzerland

    K. H. Rieder

Authors
  1. Inder P. Batra
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  2. T. Engel
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  3. K. H. Rieder
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Editor information

Editors and Affiliations

  1. Department of Chemistry, University of California, 94720, Berkeley, CA, USA

    Michel A. Van Hove

  2. Department of Physics and The Laboratory for Surface Studies, The University of Wisconsin-Milwaukee, 53201, Milwaukee, WI, USA

    S. Y. Tong

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© 1985 Springer-Verlag Berlin Heidelberg

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Batra, I.P., Engel, T., Rieder, K.H. (1985). Helium Diffraction from Oxygen-Covered Nickel Surfaces. In: Van Hove, M.A., Tong, S.Y. (eds) The Structure of Surfaces. Springer Series in Surface Sciences, vol 2. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82493-7_40

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  • DOI: https://doi.org/10.1007/978-3-642-82493-7_40

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-82495-1

  • Online ISBN: 978-3-642-82493-7

  • eBook Packages: Springer Book Archive

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