High-Resolution Infrared Spectroscopy and Surface Structure

  • Y. J. Chabal
Part of the Springer Series in Surface Sciences book series (SSSUR, volume 2)


The potential of high-resolution surface infrared spectroscopy as a structural tool is assessed by combining results on the Si(100)–(2 × 1)H system with ab initio cluster calculations. It is shown that a complete determination of the geometry and vibrational parameters can be obtained.


Electron Energy Loss Spectroscopy Step Edge Step Mode Step Atom LEED Pattern 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 12.1
    S.A. Francis, A.H. Allison: J. Opt. Soc. Am. 49, 131 (1959)CrossRefGoogle Scholar
  2. 12.2
    G.E. Becker, G.W. Gobeli: J. Chem. Phys. 38, 2942 (1963)CrossRefGoogle Scholar
  3. See, for example, the excellent review of F.M. Hoffmann: Surf. Sci. Reports 3, 107 (1983) and references thereinGoogle Scholar
  4. M.K. Debe: Appl. Surf. Sci. 14, 1 (1982–1983)Google Scholar
  5. 12.5
    E.G.A. Ortega, F.M. Hoffmann, A.M. Bradshaw: Surf. Sci. 119, 79 (1982)CrossRefGoogle Scholar
  6. 12.6
    R. Shigeishi, D.A. King: Surf. Sci. 58, 379 (1976)CrossRefGoogle Scholar
  7. 12.7
    P. Hollins, J. Pritchard: Surf. Sci. 89, 489 (1979)CrossRefGoogle Scholar
  8. 12.8
    A. Crossley, D.A. King: Surf. Sci. 95, 131 (1980);CrossRefGoogle Scholar
  9. D.A. King: In Vibrational Spectroscopy of Adsorbates, ed. by R.F. Willis (Springer, Berlin, Heidelberg, New York 1980) p.179Google Scholar
  10. 12.9
    H. Pfnür, D. Menzel, F.M. Hoffmann, A. Ortega, A.M. Bradshaw: Surf. Sci. 93, 431 (1980)CrossRefGoogle Scholar
  11. 12.10
    B.N.J. Persson, R. Ryberg: Phys. Rev. Lett. 48, 549 (1982)CrossRefGoogle Scholar
  12. 12.11
    Y.J. Chabal, A.J. Sievers: Phys. Rev. B24, 2921 (1981)Google Scholar
  13. 12.12
    S. Chiang, R.G. Tobin, P.L. Richards, P.A. Thiel: Phys. Rev. Lett. 52, 648 (1984)CrossRefGoogle Scholar
  14. 12.13
    J.C. Ariyasu, D.L. Mills, K.G. Lloyd, J.C. Hemminger: Phys. Rev. B28, 6123 (1983)Google Scholar
  15. 12.14
    M. Persson, B. Hellsing: Phys. Rev. Lett. 49, 662 (1982)CrossRefGoogle Scholar
  16. 12.15
    Y.J. Chabal, E.E. Chaban, S.B. Christman: J. Electr. Spectrosc. Related Phenom. 29, 35 (1983)CrossRefGoogle Scholar
  17. 12.16
    Y.J. Chabal, G.S. Higashi, S.B. Christman: Phys. Rev. B28, 4472 (1983)Google Scholar
  18. 12.17
    Y.J. Chabal: Phys. Rev. Lett. 50, 1850 (1983)CrossRefGoogle Scholar
  19. 12.18
    J.A. Appelbaum, D.R. Hamann: Surf. Sci. 74, 21 (1978)CrossRefGoogle Scholar
  20. 12.19
    T. Sakurai, H.D. Hagstrum: Phys. Rev. B14, 1593 (1976)Google Scholar
  21. 12.20
    R. Kaplan: Surf. Sci. 93, 145 (1980)CrossRefGoogle Scholar
  22. Y.J. Chabal: Phys. Rev. B29, 3677 (1984) and Ref.12 thereinGoogle Scholar
  23. 12.22
    B.N.J. Persson, R. Ryberg: Phys. Rev. B24, 6954 (1981)Google Scholar
  24. 12.23
    Y.J. Chabal, K. Raghavachari: Phys. Rev. Lett. 53, 282 (1984)CrossRefGoogle Scholar
  25. 12.24
    G.B. Bachelet, M. Schlüter: Phys. Rev. B28, 2302 (1983)Google Scholar
  26. 12.25
    I.P. Batra, P.S. Bagus, K. Hermann: Phys. Rev. Lett. 52, 384 (1984)CrossRefGoogle Scholar
  27. 12.26
    B.E. Hayden, K. Prince, D.P. Woodruff, A.M. Bradshaw: Phys. Rev. Lett. 51, 475 (1983)CrossRefGoogle Scholar
  28. A discussion of the different techniques used for metal substrates, such as polarization and wavelength modulation, is beyond the scope of this article and the reader is referred to Ref.12.3. To date, there is no IR work which uses substrate-adsorbate vibrations to determine the structure of the adsorbates on metallic substrates. For both results presented in Ref.12.11, 12, the bonding configuration was known from EELS work and no new structural details were obtained from the the IR dataGoogle Scholar
  29. 12.28
    K.-M. Ho, C.L. Fu, B.N. Harmon: Phys. Rev. B29, 1575 (1984)Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1985

Authors and Affiliations

  • Y. J. Chabal
    • 1
  1. 1.AT&T Bell LaboratoriesMurray HillUSA

Personalised recommendations