Abstract
It is now well-known that the clean W(001) surface undergoes a reconstructive phase-transition at certain temperature Tc and exhibits a c(2×2) structure at low temperatures. From various experimental and theoretical sources, it is concluded that this surface reconstruction is a second order transition caused by spontaneous displacements of surface atoms along a direction parallel to the surface as depicted in Fig.1 [1]. The reconstructed structure of W(001)is somehow stabilized when hydrogen atoms are adsorbed, so long as the coverage of hydrogen is small [2], As to the mechanism of the phase-transition, several models have been proposed [3], but at present it seems that an accepted view point is to attribute the origin of driving transition to the competition between stabilizing band electronic force and opposing ion-core repulsive force. Among others, TERAKURA et al. gave an electronic theory of the surface reconstruction on W(001) [4] which could explain even quantitatively the relevant experimental facts for absolute zero T=0. As to temperature-variation of this transition, however, there are a few theories in which the temperature-effect is seriously considered. Probably this is due to the fact that the main source of information on the temperature-dependence of the “order parameter” is LEED experiments, which are much influenced by large surface vibration as far as the temperature-effect is concerned. Indeed, for instance, we can observe in Fig.2, with increasing temperature, strong exponential decay of the scattering intensity of the LEED patterns characteristic to the low-temperature phase [5]. If we look at Fig.2 as a temperature-dependence curve for the “order parameter” of the phase-transition, it would be quite unusual in contrast to the standard behaviour of the order parameter in the second order phase-transition: The transition-temperature is obscured by the exponential tail.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
D. A. King : Physica Scripta T4, 34(1983).
M. K. Debe and D. A. King : J. Phys. C10, L1303 (1977).
T. E. Felter, R. A. Barker and P. J. Estrup : Phys. Rev. Lett. 38, 1138 (1977).
J. E. Inglesfields : Vacuum 31, 663 (1981).
K. Terakura, I. Terakura and Y. Teraoka : Surface Sci. 80, 535 (1979).
I. Terakura, K. Terakura and N. Hamada : Surface Sci. 103, 103 (1981)
K. Masuda-Jindo, N. Hamada and K. Terakuka : J. Phys. C17, L271 (1984)
D. A. King and G. Thomas : Surface Sci. 72, 201 (1980)
R. A. Barker and P. J. Estrup : J. Chem. Phys. 74, 1442 (1981)
M. K. Debe and D. A. King : Surface Sci. 81, 193 (1979)
T. Matsubara and K. Kamiya : Prog. Theor. Phys. 58, 767 (1977).
T. Matsubara, Y. Iwase and A. Momokita : Prog. Theor. Phys. 59, 1102 (1978).
T. Hama and T. Matsubara : Prog. Theor. Phys. 59, 1407 (1978).
K. H. Lau and S-C. Ying : Phys. Rev. Lett. 44, 222 (1980)
T. Inaoka and A. Yoshimori : Surface Sci. 115, 301 (1982).
T. Matsubara and T. Odagaki : in preparation.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1985 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Matsubara, T. (1985). Temperature Effect in Surface Reconstruction of Clean and Hydrogen-Adsorbed W(001) Surface. In: Yoshimori, A., Tsukada, M. (eds) Dynamical Processes and Ordering on Solid Surfaces. Springer Series in Solid-State Sciences, vol 59. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82423-4_23
Download citation
DOI: https://doi.org/10.1007/978-3-642-82423-4_23
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-82425-8
Online ISBN: 978-3-642-82423-4
eBook Packages: Springer Book Archive