Abstract
Surface processes such as photodesorption, electron-stimulated desorption, photoluminescence, photocatalysis and photolytic decomposition rely on the population of excited electronic states in the adsorbate layer. A satisfactory description of both the excited and the ground state electronic structure of the adsorbate-substrate system is thus a necessary prerequisite for understanding these phenomena. This article attempts to explain simply some of the more important aspects of the adsorbate-substrate interaction and to describe how surface electronic structure can be probed spectroscopically.
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Bradshaw, A.M. (1984). Electronic Structure of Adsorbed Layers. In: Bäuerle, D. (eds) Laser Processing and Diagnostics. Springer Series in Chemical Physics, vol 39. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82381-7_16
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DOI: https://doi.org/10.1007/978-3-642-82381-7_16
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