Single Crystal Surface Structure Studies with Static SIMS

  • E. Bauer
  • S. Prigge
Conference paper
Part of the Springer Series in Chemical Physics book series (CHEMICAL, volume 36)


When Benninghoven demonstrated the high surface sensitivity of SIMS and introduced static SIMS 14 years ago it was natural to ask the question: If static SIMS can be used to determine the composition of the surface, can it not also be used to determine the arrangement of its constituents, that is the atomic structure of the surface? We embarked on an attempt to answer this question 12 years ago and came to a conditional “no” a few years later. The “no” was conditional in the sense that SIMS gave no structural information which could not be obtained easier and/or more accurately using other methods for surface structure analysis. This answer and the supporting experimental results were never published so that it is not surprising that the discussion of the question is still continuing, stimulated in part by computer experiments of oxygen on (Cu(100) [1,2]),in part by the claim that the bonding site of CO on metal surfaces can be determined by SIMS [3] • The CO controversy (for references see [4,5]) is not very relevant from the point of view of practical surface structure analysis because the information extractable from SIMS is inferior to that obtainable with other methods and will, therefore, not be discussed here for lack of space.


Work Function Change Cylindrical Mirror Analyzer Annealing Temperature Dependence High Surface Sensitivity Energy Distribution Measurement 
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  1. 1.
    N. Winograd, B.J. Garrison and D.E. Harrison, jr., Phys. Rev. Letters 41, 1120 (1978)CrossRefGoogle Scholar
  2. 2.
    B.J, Garrison, N. Winograd and D.E. Harrison, jr. Phys. Rev. B 18, 6000 (1978)CrossRefGoogle Scholar
  3. 3.
    M. Barber, J.C. Vickerman and J. Wolstenholme, J. Chem. Soc. Faraday Trans. I 72, 40 (1976); Surface Sci. 68, 130 (1977)CrossRefGoogle Scholar
  4. 4.
    K.E. Foley and N. Winograd, Surface Sci. 116, 1 (1982)CrossRefGoogle Scholar
  5. 5.
    A. Brown and J.C. Vickerman, Surface Sci. 124, 267 (1983)CrossRefGoogle Scholar
  6. 6.
    H. Niehus, Ph. D. thesis, Clausthal 1975Google Scholar
  7. 7.
    E. Bauer and T. Engel, Surface Sci. 71, 695 (1978)CrossRefGoogle Scholar
  8. 8.
    E. Bauer, H. Poppa and Y. Viswanath, Surface Sci. 58, 517 (1976)CrossRefGoogle Scholar
  9. 9.
    H. Froitzheim, H. Ibach and S. Lehwald, Phys. Rev. B 14, 1362 (1976)CrossRefGoogle Scholar
  10. 10.
    E. Bauer, J. Electron Spectrosc. Relat. Phenom. 15, 119 (1979)CrossRefGoogle Scholar
  11. 11.
    A. Benninghoven, E. Loebach, C. Plog and N. Treitz, Surface Sci. 39, 397 (1973)CrossRefGoogle Scholar
  12. 12.
    S. Prigge, M.S. thesis, Clausthal 1975Google Scholar
  13. 13.
    M.L. Yu, Appl. Phys. Letters 30, 654 (1977); Surface Sci. 64, 334 (1977); 71, 121 (1978); J. Vac. Sci. Technol. 15, 668 (1978)CrossRefGoogle Scholar
  14. 14.
    H.M Kramer and E. Bauer, Surface Sci. 92, 53 (1980)CrossRefGoogle Scholar
  15. 15.
    S.P. Holland, B.J. Garrison and N. Winograd, Phys. Rev. Letters 43, 220 (1979)CrossRefGoogle Scholar
  16. 16.
    S. Prigge, H. Niehus and E. Bauer, Surface Sci. 65, 141 (1977)CrossRefGoogle Scholar
  17. 17.
    W. Speckmann, M.S. thesis, Clausthal 1983Google Scholar
  18. 18.
    W. Speckmann, S. Prigge and E. Bauer, in Secondary Ion Mass Spectrometry III, ed. by A. Benninghoven, J. Giber, J. Laszlo, M. Riedel and H.W. Werner, Springer Series in Chemical Physics, Vol. 19 (Springer, Berlin, Heidelberg, New York 1982) p. 128Google Scholar
  19. 19.
    S. Prigge, H. Niehus and E. Bauer, Proc. 7th Int. Vac. Congr. and 3rd Int. Conf. Solid Surfaces, Vienna 1977, p. 1381Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1984

Authors and Affiliations

  • E. Bauer
    • 1
  • S. Prigge
    • 1
  1. 1.Physikalisches InstitutTechnische Universität ClausthalClausthal-ZellerfeldFed. Rep. of Germany

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