Abstract
Recent contributions [1–3] to the surface-enhance Raman scattering (S.E.R.S.) of absorbed species at a silver electrode clearly show an additional enhancement as the surface is illuminated by the laser beam during the oxidization-reduction cycle. This enhancement effect is only obtained when alkali halides are used as electrolytes; it suggest a photodecomposition of the silver halides into metallic clusters. The absorbed molecules may play a role of sensitizers like in the well-known photographic process [4–6].
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© 1983 Springer-Verlag Berlin Heidelberg
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Regis, A., Dumas, P., Corset, J. (1983). Contributions of Charge Transfer Complexes and Photochemical Effects to SERS at a Silver Electrode. In: Aussenegg, F.R., Leitner, A., Lippitsch, M.E. (eds) Surface Studies with Lasers. Springer Series in Chemical Physics, vol 33. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-82085-4_7
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