Abstract
Crystal growth and decrystallization (evaporation, melting, dissolution, etching, etc.) take place under the influence of a thermodynamic driving force determined by deviations in temperature, pressure, concentration, and external field intensity from their equilibrium values. Growth and decrystallization occur on interfaces whose structure and properties are close to equilibrium. Thus the basic principles governing phase equilibrium, driving force, and equilibrium interface structure and properties should be considered before entering into the kinetics of phase transformation. These aspects of equilibrium form the subject of this chapter.
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Chernov, A.A. (1984). Equilibrium. In: Modern Crystallography III. Springer Series in Solid-State Sciences, vol 36. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81835-6_1
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DOI: https://doi.org/10.1007/978-3-642-81835-6_1
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