Abstract
X-ray diffraction studies of pressure-induced intralayer and interlayer structural phase transitions in alkali GIC’s are discussed with particular emphasis on KC24 and CsC36. It is shown that such transitions involve the well-defined layer stoichiometries MC8 and MC12 which occur in ambient pressure compounds. Stage 1 MC8 compounds exhibit no structural transitions at pressures up to 13 kbar but show a Hook’s law behavior from which their compressibilities have been determined.
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Solin, S.A. (1981). X-Ray Diffraction from Graphite Intercalation Compounds Under Hydrostatic Pressure. In: Pietronero, L., Tosatti, E. (eds) Physics of Intercalation Compounds. Springer Series in Solid-State Sciences, vol 38. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81774-8_29
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DOI: https://doi.org/10.1007/978-3-642-81774-8_29
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