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180°-Flip of a Linear HF 2 -Ion in Crystals

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Abstract

The 180°-reorientation (flip) of the difluoride-ion in ionic KHF2- type crystals and iaostructural solid solutions was found by the nuclear spin lattice relaxation measurements. The interrelation of the dynamics of HF 2 -ions and phase transitions in studied crystals is discussed from the concept of the dynamic diffusion theory.

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References

  1. J.S. Waugh, F.B. Humphrey, D.M. Yoat, J.Phys.Chem., 57, 486 (1953)

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© 1979 Springer-Verlag Berlin Heidelberg

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Kriger, Y.G., Moroz, N.K., Habuda, S.P. (1979). 180°-Flip of a Linear HF 2 -Ion in Crystals. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_63

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  • DOI: https://doi.org/10.1007/978-3-642-81344-3_63

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-81346-7

  • Online ISBN: 978-3-642-81344-3

  • eBook Packages: Springer Book Archive

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