2 mm Wave Band ESR of RO2 Radicals

  • O. Ya. Grinberg
  • A. A. Dubinsky
  • A. P. Moravsky
  • V. F. Shuvalov
  • Ya. S. Lebedev

Abstract

The special 2mm ESR technique was used to investigate HO2, radicals appearing at 77K photolysis of frozen H2O2/H2O2 solutions and RO2 radicals obtained by radiolisis of polytetraflubrobthylene. Slight differencies of g-values were detected which correlate with structure and stability of radicals. 2mm spectra proved to be sensitive to be sensitive to details of molecular motions

Keywords

Photolysis PTFE Peroxy 

Reference

  1. 1.
    O.Ya.Grinberg, A.A.Dubinsky, V.F.Shuvalov, V.I.Kurochkin, L.G.Oransky, Ya.S.Lebedev, Doklady Acad. Nauk SSSR, 230, 884 (1976).Google Scholar
  2. 2.
    A.A.Dubinsky, 0.Ya.Grinberg, A.A.Tabachni, Ya.S.Lebedev, Doklady Acad. Nauk SSSR, 215, 631 (1974).Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1979

Authors and Affiliations

  • O. Ya. Grinberg
    • 1
  • A. A. Dubinsky
    • 1
  • A. P. Moravsky
    • 1
  • V. F. Shuvalov
    • 1
  • Ya. S. Lebedev
    • 1
  1. 1.Institute of Chemical Physics of Academy of Sciences of the USSRMoscowUSSR

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