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Proton Chemical Shift and Dipolar Spectra of Cluster Hydrides

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Magnetic Resonance and Related Phenomena
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Abstract

Structured proton NMR dipolar lineshapes for the compounds H2Os3(CO)10, H4Os4(CO)12, and H4Ru4(CO)12 are reported and interpreted in terms of an analytical calculation for four dipolar-coupled spin 1/2 nuclei. Chemical shift tensors for the metal-bridging protons are reported and discussed.

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References

  1. A.T, Nicol, PhD Thesis, 1978, University Microfilms, Ann Arbor, Michigan.

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  2. G.M. Sheldrick, private communication.

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  3. A.T. Nicol and R.W. Vaughan, to be published.

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  4. R.W. Vaughan, D. D. Elleman, L.M. Stacey, W-K. Rhim, and J.W. Lee, Rev. Sci. Instrum. 43, 1356 (1972).

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  5. C.R. Dybowski and R.W. Vaughan, Macromolecules 8, 50 (1975).

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© 1979 Springer-Verlag Berlin Heidelberg

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Nicol, A.T., Vaughan, R.W. (1979). Proton Chemical Shift and Dipolar Spectra of Cluster Hydrides. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_40

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  • DOI: https://doi.org/10.1007/978-3-642-81344-3_40

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-81346-7

  • Online ISBN: 978-3-642-81344-3

  • eBook Packages: Springer Book Archive

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