Stereospecificity of Selective Proton Relaxation Times in Rigid Organic Molecules

  • Yu. Yu. Samitov
  • R. H. Saddykov
Conference paper

Abstract

Spin dynamics in a coupled four spin system of the AA’BB’ type are described. Experimental temperature dependence of the longitudinal relaxation time of axial and equatorial methylene protons (HA and HB) have been studied in 2,2-dimethyl-propanediol-1,3-sulfite. It is shown that spin--rotation interaction contributes to the relaxation of these methylene protons.

Keywords

Sulfite 

References

  1. 1.
    R. Freeman and S. Wittekoek, J. Magn. Res. 1, 238 (1969).ADSGoogle Scholar
  2. 2.
    Yu.Yu. Samitov, Dokl. Akad. Nauk SSSR 164, 347 (1965).Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1979

Authors and Affiliations

  • Yu. Yu. Samitov
    • 1
  • R. H. Saddykov
    • 1
  1. 1.Chemical FacultyKazan State UniversityKazanUSSR

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