On Discrimination Between Various Mechanisms of Orientational Relaxation in Liquids

  • A. I. Burshtein
  • S. I. Temkin
Conference paper


The correction to the Hubbard relation between the orientational and rotational relaxation times in liquids has been found in the impact approximation. This correction depends on how effectively collisions change the molecular angular moment and, in principle, allows the situations of strong and weak collisions to be discriminated experimentally.


Relaxation Time Rotational Diffusion Angular Moment Impact Theory Orientational Relaxation 
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Copyright information

© Springer-Verlag Berlin Heidelberg 1979

Authors and Affiliations

  • A. I. Burshtein
    • 1
  • S. I. Temkin
    • 1
  1. 1.Institute of Chemical Kinetics and CombustionAcademy of Sciences, Siberian BranchNovosibirskUSSR

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