Skip to main content

Multiple Pulse NMR of Solid Polymers: Dynamics of Polytetrafluoroethylene

  • Conference paper
Magnetic Resonance and Related Phenomena
  • 12 Accesses

Abstract

19F NMR chemical shift spectra of polytetrafluoroethylene have been obtained using an eight pulse homonuclear line narrowing multiple pulse sequence. These spectra have been obtained as a function of polymer crystallinity and temperature. The polymer crystallinity is quite precisely determined and the lineshapes allow identification of different types of molecular motion in crystalline and amorphous fractions as a function of temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. D. W. McCall, D. C. Douglass, and D. R. Falcone, J. Phy. Chem. 71, 998 (1967).

    Article  Google Scholar 

  2. D. Ellett, U. Haeberlen, J. S. Waugh, Polymer Letters 7, 71 (1969).

    Article  Google Scholar 

  3. b) A. N. Garroway, D. C. Stalker, P. Mansfield, Polymer 16, 161 (1975).

    Article  Google Scholar 

  4. c) M. Mehring, R. S. Mehring, J. S. Waugh, J. Chem. Phys. 55, 746 (1971).

    Article  ADS  Google Scholar 

  5. W.-K. Rhim, D. D. Elleman, and R. W. Vaughan, J. Chem. Phys. 59, 3740 (1973).

    Article  ADS  Google Scholar 

  6. A. J. Vega and R. W. Vaughan, J. Chem. Phys. 68, 1958 (1978).

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1979 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

English, A.D., Vega, A.J. (1979). Multiple Pulse NMR of Solid Polymers: Dynamics of Polytetrafluoroethylene. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_39

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-81344-3_39

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-81346-7

  • Online ISBN: 978-3-642-81344-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics