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High Resolution 13C NMR of Polycrystalline TTF-TCNQ

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Magnetic Resonance and Related Phenomena

Abstract

High resolution low field 13C NMR spectrum of the TTF-TCNQ complex consists of several well-resolved lines, three of which correspond to the peripheral carbons of the TCNQ- ion radical and display large diamagnetic Knight shifts, caused by the conduction electrons. The resonance of the TCNQ cyano groups is a triplet with field-dependent splitting, caused by dipole-dipole interaction with the 14N nucleus.

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References

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© 1979 Springer-Verlag Berlin Heidelberg

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Lippmaa, E., Alla, M., Raude, H., Teeäär, R., Heinmaa, I., Kundla, E. (1979). High Resolution 13C NMR of Polycrystalline TTF-TCNQ. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_22

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  • DOI: https://doi.org/10.1007/978-3-642-81344-3_22

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-81346-7

  • Online ISBN: 978-3-642-81344-3

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