The Spin-Lattice Relaxation of Methyl Groups in Solids

  • R. J. Baarda
  • S. Emid
  • J. Kupers
  • D. Ligthelm
  • J. F. J. M. Pourquié
  • J. Smidt
  • R. A. Wind
Conference paper

Abstract

The influence of symmetry-restricted spin-diffusion on the spin-lattice relaxation of rapidly reorienting methyl groups in solids is considered. It is shown how the T1 Z-measurements and their interpretation can go wrong if this influence is not taken into account.

Keywords

Piperazine cosB 

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References

  1. 1).
    E.A. Stejskal and H.S. Gutowsky, J. Chem. Phys. 28, 388 (1958).ADSCrossRefGoogle Scholar
  2. 2).
    S. Emid and R.A.Wind, Chem. Phys. Lett. 27, 312 (1974).Google Scholar
  3. 3).
    R.L. Hilt and P.S. Hubbard, Phys. Rev. Lett. 134, 392 (1964).ADSGoogle Scholar
  4. 4).
    S. Emid, R.A. Wind and S. Clough, Phys. Rev. Lett. 33, 769 (1974).ADSCrossRefGoogle Scholar
  5. 5).
    S. Emid and R.A. Wind, Chem. Phys. Lett. 33, 269 (1975).ADSCrossRefGoogle Scholar
  6. 6).
    R.A. Wind, S. Emid, J.F.J.M. Pourquié and J. Smidt, J. Chem. Phys. 67, 2436 (1977).ADSCrossRefGoogle Scholar
  7. 7).
    )R.A. Wind and S. Emid, Phys. Rev. Lett. 33, 1422 (1974).ADSCrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1979

Authors and Affiliations

  • R. J. Baarda
    • 1
  • S. Emid
    • 1
  • J. Kupers
    • 1
  • D. Ligthelm
    • 1
  • J. F. J. M. Pourquié
    • 1
  • J. Smidt
    • 1
  • R. A. Wind
    • 1
  1. 1.Department of Applied PhysicsDelft University of TechnologyDelftThe Netherlands

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