Abstract
The influence of symmetry-restricted spin-diffusion on the spin-lattice relaxation of rapidly reorienting methyl groups in solids is considered. It is shown how the T1 Z-measurements and their interpretation can go wrong if this influence is not taken into account.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
E.A. Stejskal and H.S. Gutowsky, J. Chem. Phys. 28, 388 (1958).
S. Emid and R.A.Wind, Chem. Phys. Lett. 27, 312 (1974).
R.L. Hilt and P.S. Hubbard, Phys. Rev. Lett. 134, 392 (1964).
S. Emid, R.A. Wind and S. Clough, Phys. Rev. Lett. 33, 769 (1974).
S. Emid and R.A. Wind, Chem. Phys. Lett. 33, 269 (1975).
R.A. Wind, S. Emid, J.F.J.M. Pourquié and J. Smidt, J. Chem. Phys. 67, 2436 (1977).
)R.A. Wind and S. Emid, Phys. Rev. Lett. 33, 1422 (1974).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1979 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Baarda, R.J. et al. (1979). The Spin-Lattice Relaxation of Methyl Groups in Solids. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_18
Download citation
DOI: https://doi.org/10.1007/978-3-642-81344-3_18
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-81346-7
Online ISBN: 978-3-642-81344-3
eBook Packages: Springer Book Archive