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A CIDNP Approach to Signal Enhancement in Magnetic Resonance

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Magnetic Resonance and Related Phenomena
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Abstract

CIDNP allows selective NMR signal enhancement of aromatics, aldehydes, ketones, alcohols, amines, olefines, etc. via heat or photoexcitation of certain reagent systems. The CIDNP typically stems from radical pairs, but occasionally from triplets via the Overhauser Triplet Mechanism (quinones). The latter may act intermolecularly, in which case nonselective enhancement is possible.

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References

  1. J. Bargon, H. Fischer and U. Johnsen, Z. Naturfschg. 20a, 1551, (1967).

    ADS  Google Scholar 

  2. H. R. Ward, and R. G. Lawler, J. Am. Chem. Soc. 89, 5518 (1967).

    Article  Google Scholar 

  3. J. Bargon and H. Fischer, Z. Naturfschg. 20a, 1556 (1967).

    ADS  Google Scholar 

  4. R. G. Lawler, 89, 5518 (1967).

    Google Scholar 

  5. K. H. Hausser and D. Stehlik. Adv. Mag. Res. 3, 79, (1968).

    Article  Google Scholar 

  6. G. L. Gloss, J. Am. Chem. Soc. 91, 4552 (1969).

    Article  Google Scholar 

  7. G. L. Close and A. D. Trifunac, J. Am. Chem. Soc. 92, 2183, (1970).

    Article  Google Scholar 

  8. R. Kaptein and J. L. Oosterhoff, Chem. Phys. Lett. 4, 195, 214 (1969)

    Article  ADS  Google Scholar 

  9. “Chemically Induced Magnetic Polarization”, L. T. Muus et al. eds., Nato Adv. Study Inst. Series C34, Reidel rub. Co., Dordrecht (1977).

    Google Scholar 

  10. M. L. Manion Schilling, R. S. Hutton and H. D. Roth, J. Am. Chem. Soc. 99, 7792 (1977).

    Article  Google Scholar 

  11. J. Bargon and K. G. Seifert. Ber. Bunsenges. Phys. Chem. 78, 1180, (1974).

    Google Scholar 

  12. V. A. Kalibabchuk and V. S. Ruts, Teor. Eksp. Khim. 78, 1180, (1974).

    Google Scholar 

  13. G. Vermeersch, N. Febray-Garot, S. Kaplain and Lablache Combier, Tstrahed. Lett. 2991 (1975).

    Google Scholar 

  14. F. J. Adrian, ref. 5, page 369.

    Google Scholar 

  15. P. W. Atkins, ref. 5 page 191.

    Google Scholar 

  16. K. A. Muszkat, unpublished results.

    Google Scholar 

  17. J. Bargon, J. Am. Chem. Soc. 93, 4630 (1971)

    Google Scholar 

  18. J. Bargon, Ind. Chia. Belg. 36, 1061 (1971).

    Google Scholar 

  19. A. Borer, R. Kirchmayer and G. Rist, Helvetica Chia. Act. 61, 305 (1978).

    Article  Google Scholar 

  20. B. Blank, P. G. Mennitt and H. Fischer, Spec. Lect. XXII rd Intern. Congr. Pure & Appl. Chem. 4, 1 (1971).

    Google Scholar 

  21. G. L. Uoss and A. D. Trifunac, J. am. Chem. Soc. 92, 7227 (1970).

    Article  Google Scholar 

  22. R. Benn and H. Dreeskamp, Z. Phys. Chem. NF 101, 11 (1976).

    Article  Google Scholar 

  23. K. G. Seifert and J. Sargon, Angew Chem. Int. Ed. 12, 763 (1973).

    Article  Google Scholar 

  24. R. G. Lawler in ref. 5 page 267.

    Google Scholar 

  25. H. D, Roth, Mol. Photochem 5, 91, (1973).

    Google Scholar 

  26. G. L. Gloss and M. Czeropski, J. Am. Chem. Soc. 99, 6127 (1977).

    Article  Google Scholar 

  27. J. Sargon, J. Am. Chem. Soc. 99, 8350 (1977).

    Article  Google Scholar 

  28. H. D. Roth in ref. 5 page 39.

    Google Scholar 

  29. J. Bargon and G. P. Gardini, to be published.

    Google Scholar 

  30. K. A. Muszkat, J. Chem. Soc., Chem. Comm. 872 (1977).

    Google Scholar 

  31. K. A. Muszkat and C. Gilon, Nature 271, 685 (1978).

    Article  ADS  Google Scholar 

  32. R. Kaptein, Paper to be presented XXth Congress Ampere (1978).

    Google Scholar 

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© 1979 Springer-Verlag Berlin Heidelberg

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Bargon, J. (1979). A CIDNP Approach to Signal Enhancement in Magnetic Resonance. In: Kundla, E., Lippmaa, E., Saluvere, T. (eds) Magnetic Resonance and Related Phenomena. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81344-3_11

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  • DOI: https://doi.org/10.1007/978-3-642-81344-3_11

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-81346-7

  • Online ISBN: 978-3-642-81344-3

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