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Solid-State Spectroscopy

  • Chapter
Synchrotron Radiation

Part of the book series: Topics in Current Physics ((TCPHY,volume 10))

Abstract

A complete survey of the vacuum ultraviolet and soft X-ray spectroscopy of solids should include not only reflection and transmission spectroscopy, but X-ray and ultraviolet photoemission spectroscopy, electron energy loss spectroscopy, several other spectroscopies, and the theoretical bases for their interpretation, for all deal with the same microscopic phenomena. This chapter will be limited, of necessity, to absorption, reflection, luminescence, and modulation spectroscopy of solids in the 6–300 eV region. (The dividing line between soft X-ray and vacuum ultraviolet is not well-defined and will shift several times during this chapter). There is an enormous literature to cover, for conventional discharge sources have been in use for many years, and improved versions are still widely used. Synchrotron radiation has a number of advantages over them, and its use has led to the discovery of new kinds of spectral features. For example, the high intensity and temporal stability of synchrotron radiation permit high-resolution and modulation spectroscopy to be carried out almost routinely, revealing previously unresolved structure, and the polarization allows work on anisotropic materials. Because synchrotron radiation has a continuous spectrum over several decades of energy the search for spectral features can be carried out thoroughly. This chapter describes work done almost exclusively with synchrotron radiation, although some of it could have been carried out with conventional sources. In fact, some has been so carried out, often earlier, but space does not permit adequate referencing of much of such work.

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Lynch, D.W. (1979). Solid-State Spectroscopy. In: Kunz, C. (eds) Synchrotron Radiation. Topics in Current Physics, vol 10. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-81297-2_7

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