Abstract
Integral excess free energy for a ternary system can be estimated from the constituting binary excess by applying geometrical formalisms. Generalized expressions for mass balance is derived relating a ternary composition to its limiting binary compositions. It is found that the geometrical formalisms do not satisfy the mass balance constraint. Comparison of results obtained using geometrical formalisms with available experimental data revealed interesting correlation among various formalisms.
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© 1998 Springer-Verlag Berlin Heidelberg
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Ganesan, R., Vana Varamban, S. (1998). Thermochemical Modeling of Ternary Alloys from Binary Systems. In: Kumar, V., Sengupta, S., Raj, B. (eds) Frontiers in Materials Modelling and Design. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-80478-6_12
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DOI: https://doi.org/10.1007/978-3-642-80478-6_12
Publisher Name: Springer, Berlin, Heidelberg
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