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Recent Advances in the Measurement of High-Temperature Bimolecular Rate Constants

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Gas Phase Chemical Reaction Systems

Part of the book series: Springer Series in Chemical Physics ((CHEMICAL,volume 61))

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Abstract

Recent advances in the measurement of high-temperature reaction rate constants are discussed. The studies carried out by shock tube methods are particularly considered because these results are important not only in theoretical chemical kinetics but also in practical applications. The work on five chemical reactions are reviewed in detail. These are: D + H2, Cl + H2, H + O2, CH3 + CH3, and H + NO2.

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References

  1. M. Bodenstein, Z. phys. Chem. 13, 56 (1894); 22, 1 (1897); 29, 295 (1899).

    Google Scholar 

  2. A. Fontijn and S. C. Kurzius, Chem. Phys. Lett. 13, 507 (1972); (b)W. Felder, A. Fontijn, H. N. Volltrauer, and D. R. Voorhees, Rev. Sci. Inst. 51, 195 (1980).

    Article  ADS  Google Scholar 

  3. G. Burns and D. F. Hornig, Can. J. Chem. 38, 1702 (1960)

    Article  Google Scholar 

  4. J. Ernst, H. Gg. Wagner, and R. Zellner, Ber. Bunsenges.. Phys. Chem. 82, 409 (1978)

    Google Scholar 

  5. K. J. Niemitz, H. Gg. Wagner, and R. Zellner, Z. phys. Chem. 124, 155 (1981)

    Article  Google Scholar 

  6. J. V. Michael, J. W. Sutherland and R. B. Klemm, Int. J. Chem. Kin. 17, 315 (1985).

    Article  Google Scholar 

  7. J. N. Bradley, Shock Waves in Chemistry and Physics, Wiley, New York, NY, 1962.

    Google Scholar 

  8. W. Tsang and A. Lifshitz, Annu. Rev. Phys. Chem. 41, 559 (1990).

    Article  ADS  Google Scholar 

  9. J. V. Michael and K. P. Lim, Annu. Rev. Phys. Chem. 44, 429 (1993).

    Article  ADS  Google Scholar 

  10. J. V. Michael, Advances in Chemical Kinetics and Dynamics, Vol. 1, J. R. Barker, Ed., JAI Press, Greenwich, CT, 1992, p. 47.

    Google Scholar 

  11. J. V. Michael, Isotope Effects in Gas-Phase Chemistry, ACS Symp. Ser. 502, J. A. Kaye, Ed., American Chemical Society, Washington, 1992, p. 80.

    Chapter  Google Scholar 

  12. J. V. Michael and J. W. Sutherland, Int. J. Chem. Kinet. 18, 409 (1986).

    Article  Google Scholar 

  13. J. V. Michael and J. R. Fisher, Seventeenth International Symposium on Shock Waves and Shock Tubes; Y. K. Kim, Ed.; American Institute of Physics, New York, NY, 1989, p. 210.

    Google Scholar 

  14. J. V. Michael, J. Chem. Phys. 92, 3394 (1990).

    Article  ADS  Google Scholar 

  15. J. V. Michael and J. R. Fisher, J. Phys. Chem. 94, 3318 (1990).

    Article  Google Scholar 

  16. J. V. Michael, J. Chem. Phys. 90, 189 (1989).

    Article  ADS  Google Scholar 

  17. M.-C. Su, K. P. Lim, J. V. Michael, J. Hranisavljevic, Y. M. Xun, and A. Fontijn, J. Phys. Chem. 98, 8411 (1994).

    Article  Google Scholar 

  18. D. F. Davidson and R. K. Hanson, Int. J. Chem. Kinet. 22, 843 (1990).

    Article  Google Scholar 

  19. M. Koshi, M. Yoshimura, K. Fukuda, H. Matsui, K. Saito, M. Watanabe, A. Imamura, and C. Chen, J. Chem. Phys. 93, 8703 (1990).

    Article  ADS  Google Scholar 

  20. J. V. Michael and K. P. Lim, J. Chem. Phys. 97, 3228 (1992).

    Article  ADS  Google Scholar 

  21. S.S. Kumaran, K. P. Lim, J. V. Michael, and A. F. Wagner, J. Phys. Chem. 99, 8673 (1995).

    Article  Google Scholar 

  22. S. S. Kumaran, M.-C. Su, K. P. Lim, and J. V. Michael, Chem. Phys. Lett., in press.

    Google Scholar 

  23. M.-C. Su, S. S. Kumaran, K. P. Lim, and J. V. Michael, Rev. Sci. Inst., in press.

    Google Scholar 

  24. S.S. Kumaran, M.-C. Su, K. P. Lim, J. V. Michael, and A. F. Wagner, J. Phys. Chem., submitted.

    Google Scholar 

  25. M.-C. Su, S. S. Kumaran, K. P. Lim, A. F. Wagner, L. B. Harding, and J. V. Michael, in preparation.

    Google Scholar 

  26. J. V. Michael, J. R. Fisher, J. M. Bowman, and Q. Sun, Science 249, 269 (1990).

    Article  ADS  Google Scholar 

  27. B. A. Ridley, W. R. Schulz, and D. J. Le Roy, J. Chem. Phys. 44, 3344 (1966).

    Article  ADS  Google Scholar 

  28. D. N. Mitchell and D. J. Le Roy, J. Chem. Phys. 58, 3449 (1973).

    Article  ADS  Google Scholar 

  29. W. R. Schulz and D. J. Le Roy, Can. J. Chem. 42, 2480 (1964).

    Article  Google Scholar 

  30. W. R. Schulz and D. J. Le Roy, J. Chem. Phys. 42, 3869 (1965).

    Article  ADS  Google Scholar 

  31. A. A. Westenberg and N. de Haas, J. Chem. Phys. 47,1393 (1967).

    Article  ADS  Google Scholar 

  32. I. S. Jayaweera and P. D. Pacey, J. Phys. Chem. 94, 3614 (1990).

    Article  Google Scholar 

  33. B. Liu, J. Chem. Phys. 58, 1925 (1973).

    Article  ADS  Google Scholar 

  34. P. Siegbahn and B. Liu, J. Chem. Phys. 68, 2457 (1978).

    Article  ADS  Google Scholar 

  35. D. G. Truhlar and C. J. Horowitz, J. Chem. Phys. 68, 2466 (1978).

    Article  ADS  Google Scholar 

  36. A. J. C. Varandas, F. B. Brown, C. A. Mead, D. G. Truhlar, and N. C. Blais, J. Chem. Phys. 86, 6258 (1987).

    Article  ADS  Google Scholar 

  37. D. L. Diedrich and J. B. Anderson, Science 258, 786 (1992).

    Article  ADS  Google Scholar 

  38. A. I. Boothroyd, W. J. Keogh, P. G. Martin, and M. R. Peterson, J. Chem. Phys. 95, 4343 (1991).

    Article  ADS  Google Scholar 

  39. B. C. Garrett and D. G. Truhlar, Proc. Natl. Acad. Sci. 76, 4755 (1979).

    Article  ADS  Google Scholar 

  40. ibid., J. Chem. Phys. 72, 3460 (1980).

    Article  ADS  Google Scholar 

  41. Q. Sun and J. M. Bowman, J. Phys. Chem. 94, 718 (1990).

    Article  Google Scholar 

  42. B. C. Garrett, D. G. Truhlar, A. J. C. Varandas, and N. C. Blais, Int. J. Chem. Kinet. 18, 1065 (1986).

    Article  Google Scholar 

  43. T. N. Kitsopoulos, M. A. Buntine, D. P. Baldwin, R. N. Zare, and D. W. Chandler, Science 260, 1605 (1993), and references therein.

    Article  ADS  Google Scholar 

  44. Y.-S. M. Wu and A. Kuppermann, Chem. Phys. Lett. 235, 105 (1995).

    Article  ADS  Google Scholar 

  45. T. J. Park and J. C. Light, J. Chem. Phys. 94, 2946 (1991); 96, 8853 (1992).

    Article  ADS  Google Scholar 

  46. S. L. Mielke, G. C. Lynch, D. G. Truhlar, and D. W. Schwenke, J. Phys. Chem. 98, 8000 (1994).

    Article  Google Scholar 

  47. D. Wang and J. M. Bowman, J. Phys. Chem. 98, 7994 (1994).

    Article  Google Scholar 

  48. I. D. Reid, D. M. Garner, L. Y. Lee, M. Senba, D. J. Arseneau, and D. G. Fleming, J. Chem. Phys. 86, 5578 (1987).

    Article  ADS  Google Scholar 

  49. D. K. Biondi, D. C. Clary, J. N. L. Connor, B. C. Garrett, and D. G. Truhlar, J. Chem. Phys. 76, 4986 (1982).

    Article  ADS  Google Scholar 

  50. G. C. Schatz, J. Chem. Phys. 83, 3441 (1985); K. Tsuda, K. Moribayashi, and H. Nakamura, Chem. Phys. Lett. 231, 439 (1994).

    Article  ADS  Google Scholar 

  51. W. Nernst, Z. Elektrochem. 24, 335 (1918).

    Google Scholar 

  52. A. Wheeler, B. Topley, and H. Eyring, J. Chem. Phys. 4, 178 (1936).

    Article  ADS  Google Scholar 

  53. R. E. Weston, Jr., J. Phys. Chem. 83, 61 (1979).

    Article  Google Scholar 

  54. For a review see, S. C. Tucker, D. G. Truhlar, B. C. Garrett, and A. D. Isaacson, J. Chem. Phys. 82, 4102 (1985).

    Article  ADS  Google Scholar 

  55. S. S. Kumaran, K. P. Lim, and J. V. Michael, J. Phys. Chem. 101, 9587 (1994).

    Google Scholar 

  56. M. W. Chase, Jr., C. A. Davies, J. R. Downey, Jr., D. J. Frurip, R. A. McDonald, and A. N. Syverud, J. Phys. Chem. Ref. Data 14, Suppl. 1 (1985).

    Google Scholar 

  57. L. B. Harding, private communication.

    Google Scholar 

  58. M. Alagia, N. Balucani, P. Casavecchia, E. H. van Kleef, and G. G. Volpi, 13th International Symposium on Gas Kinetics, paper A4, Dublin, Sept., 1994.

    Google Scholar 

  59. C. K. Westbrook and F. L. Dryer, Prog. Energy Combust. Sci. 10, 1 (1984).

    Article  Google Scholar 

  60. J. A. Miller and C. T. Bowman, ibid. 15, 287 (1989), and references therein.

    Article  Google Scholar 

  61. D. L. Baulch, D. D. Drysdale, D. G. Horne, and A. C. Lloyd, Evaluated Data for High Temperature Reactions, Vol. 1, Butterworths, London (1972).

    Google Scholar 

  62. N. Cohen, and K. R. Westberg, J. Phys. Chem. Ref. Data 12, 531 (1983).

    Article  ADS  Google Scholar 

  63. J. Warnatz, Combustion Chemistry, W. C. Gardiner, Jr., Ed., Springer-Verlag, New York, 1984.

    Google Scholar 

  64. J. V. Michael, Prog. Energy Combust. Sci. 18, 327 (1992).

    Article  Google Scholar 

  65. D. Gutman and G. L. Schott, J. Chem. Phys. 46 4576 (1967).

    Article  ADS  Google Scholar 

  66. D. Gutman, E. A. Hardwidge, F. A. Dougherty, and R. W. Lutz, J. Chem. Phys. 47, 4400 (1967).

    Article  ADS  Google Scholar 

  67. G. L. Schott, Symp. (Int.) Combust., [Proc.] 12, 569 (1968).

    Article  Google Scholar 

  68. G. L. Schott, Combust. Flame 13, 357 (1973).

    Article  Google Scholar 

  69. K. M. Pamidimukkala and G. B. Skinner, Thirteenth International Symposium on Shock Waves and Shock Tubes, SUNY Press, Albany, 1981, p. 585.

    Google Scholar 

  70. P. Frank and Th. Just, Ber. Bunsenges.. Phys. Chem. 89, 181 (1985).

    Google Scholar 

  71. N. Fujii and K. Shin, Chem. Phys. Lett. 151, 461 (1988).

    Article  ADS  Google Scholar 

  72. N. Fujii, T. Sato, H. Miyama, K. S. Shin, and W. C. Gardiner, Jr., Current Topics in Shock Waves, Seventeenth International Symposium on Shock Waves and Shock Tubes, Y. W. Kim, Ed., American Institute of Physics, New York, 1989, p. 456.

    Google Scholar 

  73. A. N. Pirraglia, J. V. Michael, J. W. Sutherland, and R. B. Klemm, J. Phys. Chem. 93, 282 (1989).

    Article  Google Scholar 

  74. D. A. Masten, R. K. Hanson, and C. T. Bowman, J. Phys. Chem. 94, 7119 (1990).

    Article  Google Scholar 

  75. T. Yuan, C. Wang, C.-L. Yu, M. Frenklach, and M. J. Rabinowitz, J. Phys. Chem. 95, 1258 (1991).

    Article  Google Scholar 

  76. K. S. Shin and J. V. Michael, J. Chem. Phys. 95, 262 (1991).

    Article  ADS  Google Scholar 

  77. H. Du and J. P. Hessler, J. Chem. Phys. 96, 1077 (1992).

    Article  ADS  Google Scholar 

  78. H. Yang, W. C. Gardiner, Jr., K. S. Shin, and N. Fujii, Chem. Phys. Lett. 231, 449 (1994).

    Article  ADS  Google Scholar 

  79. C.-L. Yu, M. Frenklach, D. A. Masten, R. K. Hanson, and C. T. Bowman, J. Phys. Chem. 98, 4770 (1994).

    Article  Google Scholar 

  80. S.-O. Ryu, S. M. Hwang, and M. J. Rabinowitz, J. Phys. Chem., in press.

    Google Scholar 

  81. J. A. Miller, J. Chem. Phys. 74, 5120 (1981).

    Article  ADS  Google Scholar 

  82. J. A. Miller, J. Chem. Phys. 75, 5349 (1981).

    Article  ADS  Google Scholar 

  83. J. A. Miller, J. Chem. Phys. 84, 6170 (1986).

    Article  ADS  Google Scholar 

  84. S. N. Rai and D. G. Truhlar, J. Chem. Phys. 79, 6046 (1983).

    Article  ADS  Google Scholar 

  85. C. J. Cobos, H. Hippler, and J. Troe, J. Phys. Chem. 89, 342 (1985).

    Article  Google Scholar 

  86. J. Troe, ibid. 90, 3485 (1986).

    Article  Google Scholar 

  87. D. C. Clary and H. J. Werner, Chem. Phys. Lett. 112, 346 (1984).

    Article  ADS  Google Scholar 

  88. M. M. Graff and A. F. Wagner, J. Chem. Phys. 92, 2423 (1990).

    Article  ADS  Google Scholar 

  89. M. R. Pastrana, L. A. M. Quintales, J. Brand/ao, and A. J. C. Varandas, J. Phys. Chem. 94, 8073 (1990).

    Article  Google Scholar 

  90. A. J. C. Varandas, J. Brand, and M. R. Pastrana, J. Chem. Phys. 96, 5137 (1992).

    Article  ADS  Google Scholar 

  91. C. F. Melius and R. J. Blint, Chem. Phys. Lett. 64, 183 (1979).

    Article  ADS  Google Scholar 

  92. K. P. Lim and J. V. Michael, Symp. (Int.) Combust., [Proc.] 25, 713 (1994).

    Article  Google Scholar 

  93. P. Frank and M. Braun-Unkhoff, Proceedings of the Sixteenth Symposium on Shock Tubes and Waves, VCH, Weinheim, 1988, p. 379.

    Google Scholar 

  94. D. Walter, H.-H. Grotheer, J. W. Davies, M. J. Pilling, and A. F. Wagner, Symp. (Int.) Combust., [Proc.] 23, 107 (1990).

    Article  Google Scholar 

  95. W. A. Rosser and H. Wise, J. Phys. Chem. 85, 532, 2227 (1961).

    Article  Google Scholar 

  96. P. G. Ashmore and B. J. Tyler, Trans. Faraday Soc. 58, 1108 (1962).

    Article  Google Scholar 

  97. L. F. Phillips and H. I. Schiff, J. Chem. Phys. 37, 1233 (1962).

    Article  ADS  Google Scholar 

  98. H. Gg. Wagner, U. Welzbacher, and R. Zellner, Ber. Bunsenges. Phys. Chem. 80, 1023 (1976).

    Google Scholar 

  99. M. A. A. Clyne and P. B. Monkhouse, J. Chem. Soc. Faraday Trans. II 73, 298 (1977).

    Article  Google Scholar 

  100. P. P. Bemand and M. A. A. Clyne , J. Chem. Soc. Faraday Trans. II 73, 394 (1977).

    Article  Google Scholar 

  101. J. V. Michael, D. F. Nava, W. A. Payne, and L. J. Stief, J. Phys. Chem. 83, 2818 (1979).

    Article  Google Scholar 

  102. S. J. Wategaonkar and D. W. Setser, J. Chem. Phys. 90, 251 (1989).

    Article  ADS  Google Scholar 

  103. T. Ko and A. Fontijn, J. Phys. Chem. 95, 3984 (1991).

    Article  Google Scholar 

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Authors and Affiliations

  1. Chemistry Division, Argonne National Laboratory, 60439, Argonne, IL, USA

    J. V. Michael

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  1. J. V. Michael
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Editors and Affiliations

  1. Physikalisch-Chemisches Institut, Universität Heidelberg, Im Neuenheimer Feld 253, D-69120, Heidelberg, Germany

    J. Wolfrum  & H.-R. Volpp  & 

  2. Institut für Angewandte Mathematik, Universität Heidelberg, Im Neuenheimer Feld 293, D-69120, Heidelberg, Germany

    R. Rannacher

  3. Interdisziplinäres Zentrum für Wissenschaftliches Rechnen, Universität Heidelberg, Im Neuenheimer Feld 368, D-69120, Heidelberg, Germany

    J. Warnatz

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© 1996 Springer-Verlag Berlin Heidelberg

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Michael, J.V. (1996). Recent Advances in the Measurement of High-Temperature Bimolecular Rate Constants. In: Wolfrum, J., Volpp, HR., Rannacher, R., Warnatz, J. (eds) Gas Phase Chemical Reaction Systems. Springer Series in Chemical Physics, vol 61. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-80299-7_13

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  • DOI: https://doi.org/10.1007/978-3-642-80299-7_13

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