Skip to main content
SpringerLink
Log in

Atom Transfer Radical Polymerization Including Degenerative Transfer: Novel and General Pathways Towards “Living” / Controlled Radical Polymerization

  • Conference paper
New Macromolecular Architecture and Functions

Abstract

A novel and general “living” radical polymerization, namely, Atom Transfer Radical Polymerization, ATRP, affords various pathways towards the synthesis of tailor — made (co)polymers with predetermined molecular weights up to Mn ≈ 105 and molecular weight distributions as narrow as 1.05. This paper describes four different approaches to “living” ATRP, i.e., iodide-based degenerative transfer, alkyl halide / transition metal species promoted halogen atom transfer, R-X / Mt n / Lx; radical initiator / transition metal species promoted halogen atom transfer, I-I / Mt n+1 / Lx; and alkyl halide/radical initiator / transition metal species promoted halogen atom transfer, R-X / I-I / Mt n+1 / Lx.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Curran, D. P. Synthesis, 1988, 489.

    Google Scholar 

  2. Curran, D. P. in Comprehensive Organic Synthesis, Trost, B. M., Fleming, I., Eds., Pergamon: Oxford, 1991, Vol. 4, p 715, and reference therein.

    Chapter  Google Scholar 

  3. (a) Nagashima, H.; Wakamatsu, H.; Ozaki, N., Ishii, T.; Watanabe, M.; Tajima, T.; Itoh, K. J. Org. Chem. 1992, 57, 1682

    Article  CAS  Google Scholar 

  4. Udding, J. H.; Tuijp, K. J. M.; van Zanden, M. N. A.; Hiemstra, H.; Speckamp, W. N. J. Org. Chem. 1994, 59, 1993.

    Article  CAS  Google Scholar 

  5. (a) Matyjaszewski, K.; Gaynor, S.; Wang, J.S. Macromolecules, 1995, 28, 2093

    Google Scholar 

  6. Gaynor, S.; Wang, J.S.; Matyjaszewski, K. Polym. Prep. (Am. Chem. Soc., Polym. Chem. Div.), 1995, 36 (1), 467

    CAS  Google Scholar 

  7. Wang, J.S.; Gaynor, S.; Matyjaszewski, K. Polym. Prep. (Am. Chem. Soc., Polym. Chem. Div.), 1995, 36 (1), 465

    CAS  Google Scholar 

  8. Matyjaszewski, K.; Gaynor, S.; Wang, J.S. Macromolecules, submitted

    Google Scholar 

  9. (a) Wang, J.S.; Matyjaszewski, K. J. Am. Chem. Soc. 1995, 117, 5614

    Article  CAS  Google Scholar 

  10. Matyjaszwski, K.; Wang, J.S. U. S. Pat. Pending

    Google Scholar 

  11. Wang, J.S.; Matyjaszewski, K. Macromolecules, in press

    Google Scholar 

  12. Wang, J.S.; Matyjaszewski, K. Macromolecules, submitted.

    Google Scholar 

  13. a) Boutevin, B.; Pietrasanta, Y. In Comprehensive Polymer Science, Allen, G.;, Aggarwal, S. L.; Russo, S. Eds., Pergamon: Oxford, 1991, vol. 3, p 185

    Google Scholar 

  14. Bamford, C. H. In Comprehensive Polymer Science (First Supplement), Allen, G.; Aggarwal, S. L.; Russo, S. Eds., Pergamon: Oxford, 1992, p 1.

    Google Scholar 

  15. Muller, A.H.E.; Zhuang, R.; Yan, D.; Litvinenko, G. Macromolecules 1995, 28, 4326

    Article  Google Scholar 

  16. (a) Danen, W. C., in Methods in Free Radical Chemistry, Huyser, E. L. S. Ed., Dekker, New York, 1974, vol. 5, p. 1

    Google Scholar 

  17. Poutsma, M. in Free Radicals, Kochi, J.K. Ed., Wiley, New York, 1973, vol. 2, p. 113.

    Google Scholar 

  18. (a) Otsu, T.; Yoshida, M. Makromol. Chem., Rapid Commun. 1982, 3, 127, 133

    Article  CAS  Google Scholar 

  19. Solomon, D. H.; Rizzardo, E.; Cacioli, P.; U.S. Patent 4,581,429, March 27, 1985.

    Google Scholar 

  20. Georges, M.K.; Veregin, R.P.N.; Kazmaier, P.M.; Hamer, G. K. Macromolecules 1993, 26, 2987

    Google Scholar 

  21. Wayland, B. B.; Poszmik, G.; Mukerjee, S.L.; Fryd, M. J. Am. Chem. Soc. 1994, 116, 7943.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA, 15213, USA

    Scott G. Gaynor, Dorota Greszta, Jin-Shan Wang & Krzysztof Matyjaszewski

Authors
  1. Scott G. Gaynor
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dorota Greszta
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jin-Shan Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Krzysztof Matyjaszewski
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Dept. of Macromolecular Science, Osaka University, 560, Toyonaka, Osaka, Japan

    Mikiharu Kamachi  & Akira Nakamura  & 

Rights and permissions

Reprints and permissions

Copyright information

© 1996 Springer-Verlag Berlin Heidelberg

About this paper

Cite this paper

Gaynor, S.G., Greszta, D., Wang, JS., Matyjaszewski, K. (1996). Atom Transfer Radical Polymerization Including Degenerative Transfer: Novel and General Pathways Towards “Living” / Controlled Radical Polymerization. In: Kamachi, M., Nakamura, A. (eds) New Macromolecular Architecture and Functions. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-80289-8_1

Download citation

  • DOI: https://doi.org/10.1007/978-3-642-80289-8_1

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-80291-1

  • Online ISBN: 978-3-642-80289-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation