Fragmentation of gold clusters stored in a Penning trap

  • St. Becker
  • G. Dietrich
  • H.-U. Hasse
  • N. Klisch
  • H.-J. Kluge
  • D. Kreisle
  • St. Krückeberg
  • M. Lindinger
  • K. Lützenkirchen
  • L. Schweikhard
  • H. Weidele
  • J. Ziegler
Conference paper

Abstract

The collision-induced dissociation of positively charged gold clusters (2 to 23 atoms) stored in a Penning trap has been studied. After collisions with rare gases, excited clusters predominantly decay by emission of one or two atoms. The loss of two atoms occurs most likely through the emission of a dimer rather than a sequential evaporation. The minimum kinetic energies of clusters required to induce dissociation exhibit a pronounced odd-even effect. Clusters with an even number of delocalized electrons are more stable than the odd ones.

Keywords

Nickel Xenon Krypton 

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Copyright information

© Springer-Verlag Berlin Heidelberg 1995

Authors and Affiliations

  • St. Becker
    • 1
  • G. Dietrich
    • 2
  • H.-U. Hasse
    • 1
  • N. Klisch
    • 1
  • H.-J. Kluge
    • 1
  • D. Kreisle
    • 3
  • St. Krückeberg
    • 1
  • M. Lindinger
    • 1
  • K. Lützenkirchen
    • 2
  • L. Schweikhard
    • 1
  • H. Weidele
    • 3
  • J. Ziegler
    • 1
  1. 1.Institut für PhysikUniverität MainzMainzGermany
  2. 2.Institut für KernchemieUniverität MainzMainzGermany
  3. 3.Institut für PhysikUniverität KonstanzMainzGermany

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