Abstract
Mercury (Hg) contamination has attracted more attention than many other trace elements in the past few years. Local contamination due to mining activities and to industrial use of Hg, as well as increased deposition into the soils of regions far from industrial emission sources, has been detected (Lindquist et al. 1991; Glass et al. 1991; Iverfeld 1991). The emission of Hg is mainly caused by the combustion of fossil fuels, by waste incineration, by chlor-alkali plants, and by the processing of other metals (Pacyna and Munch 1991). The hazard potential of soil contaminations depends mainly on the type of bond, which controls toxicity and mobility. Due to redox- and pH-conditions of the soil and to the adsorption capacity of the different soil components, Hg can be associated with clay minerals, iron oxides, or organic material (Anderson 1979). The strong affinity of Hg to organic materials, especially to humic acids, has been shown by many authors (e. g. Strohal and Huljev 1971; Kerndorff and Schnitzer 1980; Johannsson et al. 1991; Mierle and Ingram 1991). Natural Hg anomalies are usually related to ore deposits where Hg occurs predominantly as cinnabar. Cinnabar shows very low solubility and strong resistance against weathering; thus, the bioavailibility of this form is low.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Allard B, Arsenie I (1991) Abiotic reduction of mercury by humic substances in aquatic system. An important process for the mercury cycle. Water Air Soil Poll. 56: 457–464
Anderson A (1979) Mercury in soils. In: Nriagu JW (ed.): The biochemistry of mercury in the environment. Elsevier, Amsterdam, pp 79–112
Azzaria LM, Afiabi A (1991) Stepwise thermal analysis technique for estimating mercury phases in soils and sediments. Water Air Soil Poll 56: 203–217
Di Giulio RT, Ryan EA (1987) Mercury in soils and clams from a North Carolina peatland. Water Air Soil Poll 33: 205–219
Dües G (1987) Untersuchungen zu den Bindungsformen und ökologisch wirksamen Fraktionen ausgewählter toxischer Schwermetalle in ihrer Tiefenverteilung in Hamburger Böden. Hamburger Bodenkundliche Arbeiten 9: 265
Glass GE, Sorensen JA, Schmidt KW, Rapp GR, Yap D, Fräser D (1991) Mercury deposition and sources for the upper Great Lakes region. Water Air Soil Poll 56: 235–249
Hess A. (1992) Verteilung, Mobilität und Verfügbarkeit von Quecksilber in Böden und Sedimenten am Beispiel zweier hochbelasteter Industriestandorte: Idrija/Slowenien und
Frankfurt/M.- Griesheim. Unpubl. PhD. thesis, University of Heidelberg, 171p
Iverfeldt A. (1991) Occurrence and turnover of atmospheric mercury over the nordic countries. Water Air Soil Poll 56: 251–265
Johannsson K, Aastrup M, Andersson A, Bringmark L, Iverfeldt A (1991) The coupling of mercury and organic matter in the biogeochemical cycle towards a mechanistic model for the boreal forest zone. Water Air Soil Poll, 56: 267–281
Kerndorf H, Schnitzer M (1980) Sorption of metals on humic acid. Geochim Cosmochim Acta, 44: 1701–1708
Kosta L, Byrne AR, Zelenko V, Stegnar P, Dermelj M, Ravnik V (1974) Studies on the uptake, distribution and transformations of mercury in living organisms in the Idrija region and comparative areas. Vestnik SDK, 21: 49–76
Lindquist O, Johannsson K, Aastrup M, Andersson A, Bringmark L, Hovsenius G, Hikanson L, Iverfeld A, Meili M, Timm B (1991) Mercury in the Swedish environment - recent research on causes, consequences and corrective methods. Water Air Soil Poll, 55: 261
Mierle G, Ingram R (1991) The role of humic substances in the mobilization of mercury from watersheds. Water Air Soil Poll, 56: 349–357
Mlakar I, Drovenik M (1971) Structural and genetic particularities of the Idrija mercury ore deposit. Geologija, 14: 67–128
Neville GA (1967) Toxicity of mercury vapour. Can Chem Educa, 3, no 1: 4 - 7
Pacyna JM, Munch J (1991) Anthropogenic mercury emission in Europe. Water Air Soil Poll, 56: 51–61
Papp C, Filipek LH, Smith, KS (1991) Selectivity and effectiveness of extractants used to release metals associated with organic matter. Appl Geochem, 6: 349–353
Peng A, Wang Z (1985) Mercury in river sediments. In: Environ Inorg Chem, VCH Publishers, Inc. Weinheim, 21: 393–400
Pirc S (1991) Mercury in the atmosphere of Idrija and surroundings.-(Zivo srebo v ozracju nad Idrijo in okolico). Idrijski razgledi XXXV, 1990/ 1-2, Izdal Mestni muzei Idrija, Idrija, p 1
Revis NW, Osborne TR, Holdsworth G, Hadden C (1989) Distribution of mercury species in soil from a mercury-contaminated site. Water Air Soil Poll, 45: 105–113
Schuster E (1991) The behaviour of mercury in the soil with special emphasis on complexation and adsorption processes - a review of the literature. Water Air Soil Poll, 56: 667–680
Strohal P, Huljev D (1971) Investigation of mercury-pollutant interaction with humic acids by means of radiotracers. Proc Symp: Nucl Techn Environ Poll, IAEA, Vienna, p 349
Watling RL (1981) The identification and significance of mercury compounds in estuarine sediments. Int Conf Heavy Metals in the Enviroment, CEP Consultants Ltd., Amsterdam, p 591
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1996 Springer-Verlag Berlin Heidelberg
About this chapter
Cite this chapter
Biester, H., Hess, A., Müller, G. (1996). Investigations on Different Mercury-Phases in Soils of a Mercury-Mining Area by a Pyrolysis Technique. In: Reuther, R. (eds) Geochemical Approaches to Environmental Engineering of Metals. Environmental Science. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-79525-1_4
Download citation
DOI: https://doi.org/10.1007/978-3-642-79525-1_4
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-79527-5
Online ISBN: 978-3-642-79525-1
eBook Packages: Springer Book Archive