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Enantiomorphic Sites and Stereospecific Polymerization of Chiral 1-Olefins

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Book cover Ziegler Catalysts

Abstract

The main objective of the present contribution is on the one side to show the diagnostic potentiality offered by the use of chiral monomers and on the other side to discuss relationships between stereochemistry at the prochiral face and side chain in the monomer.

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Abbreviations

(R)(S)4MH:

is racemic 4 methyl-l-hexene

(R)(S)3MP:

is racemic 3-methyl-1 -pentene

(R)(S)DMO:

is racemic 3,7-dimethyl-l-octene

(S)3MP:

is optically active (5)-3-methyl-1-pentene

(R)(S)3MR :

is racemic 3-methyl-1-hexene

EB:

is “internal” Lewis base

EB:

is “external” Lewis base

EtB:

is ethyl benzoate

PC:

is p-cresol

MT:

is p-methyl toluate

(-)MtB:

is (-)-menthyl benzoate

(-)MA:

is (-)-menthyl anisate

(-)MtP:

is (-)-dimenthyl terephthalate

MP:

is dimethyl terephthalate

EA:

is ethyl anisate

TEA:

is triethylaluminium

TIBA:

is triistfbutylaluminium

PMA:

is (R)-N, N-diethyl-α-phenylethylamine

PIN:

is(-)-α-pinene

MtA:

is(-)menthyl acetate

(S)2MBP:

is bis[(S)-2-methylbutyl] phthalate

PES:

is phenyltriethoxysilane

[α]D25 :

is specific optical rotation

D763 and D732 :

are the optical densities of the IR bands

Pp = Pm(l—C)/C, where Pm :

is the optical purity of the non-polymerized monomer and C is the conversion

Pp :

is the optical purity of polymerized monomer

E = Pp/([B*]/[Ti]) (%), where [B*]:

is the concentration of optically active Lewis base in the catalyst

R p (R)/R p (S) :

is the ratio of the polymerization rates of (R)- and (S)- enantiomer of the monomer, respectively

CW:

catalyst = MgCl2/ IB/PC/AlEt3/TiCl4/Al(iBu)3-EB

CH:

type catalyst was obtained from a soluble MgCl2-ROH adduct

MAO:

is methylalumoxane

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Author information

Authors and Affiliations

  1. Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, 56100, Pisa, Italy

    Francesco Ciardelli & Angelina Altomare

  2. Centro CNR delle Macromolecole Stereoordinate ed Otticamente Attive, Via Risorgimento 35, 56100, Pisa, Italy

    Francesco Ciardelli

  3. Dipartimento di Chimica Industriale e dei Materiali, Università di Bologna, Viale Risorgimento 4, 40136, Bologna, Italy

    Carlo Carlini

Authors
  1. Francesco Ciardelli
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  2. Carlo Carlini
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  3. Angelina Altomare
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Editor information

Editors and Affiliations

  1. Max-Planck-Institut für Kohlenforschung, D-45470, Kaiser-Wilhelm-Platz 1, Mülheim, Germany

    Gerhard Fink

  2. Institut für Makromolekulare Chemie, Albert-Ludwigs-Universität Freiburg, Hermann-Staudinger-Haus, D-79104, Stefan-Meier-Straße 31, Freiburg, Germany

    Rolf Mülhaupt

  3. Universität Konstanz, D-78434, Konstanz, Germany

    Hans H. Brintzinger

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© 1995 Springer-Verlag Berlin Heidelberg

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Ciardelli, F., Carlini, C., Altomare, A. (1995). Enantiomorphic Sites and Stereospecific Polymerization of Chiral 1-Olefins. In: Fink, G., Mülhaupt, R., Brintzinger, H.H. (eds) Ziegler Catalysts. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-79136-9_26

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  • DOI: https://doi.org/10.1007/978-3-642-79136-9_26

  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-642-79138-3

  • Online ISBN: 978-3-642-79136-9

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