New Analytical Techniques for Cuticle Chemical Analysis

  • Hans-Rolf Schulten
Conference paper
Part of the NATO ASI Series book series (volume 36)

Abstract

The analytical methodology of pyrolysis-gas chromatography/mass spectrometry (Py- GC/MS) and direct pyrolysis-mass spectrometry (Py-MS) using soft ionization techniques by high electric fields (FI) are briefly described. Recent advances of Py-GC/MS and Py-FIMS for the analyses of complex organic matter such as plant materials, humic substances, dissolved organic matter in water (DOM) and soil organic matter (SOM) in agricultural and forest soils are given to illustrate the potential and limitations of the applied methods.

Keywords

Surfactant Quartz Dioxide Phenol Carbohydrate 

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References

  1. Hemplfling R, Simmleit N, and Schulten H-R (1991) Characterization and chemodynamics of plant constituents during maturation, senescence and humus genesis in spruce ecosystems. Biogeochemistry 13: 27–60Google Scholar
  2. Schnitzer M (1991) Soil organic matter — the next 75 years. Soil Sci 151: 41–58CrossRefGoogle Scholar
  3. Schnitzer M and Schulten H-R (1992) The analysis of soil organic matter by pyrolysis-field ionization mass spectrometry. Soil Sci Soc Am J 56: 1811–1817CrossRefGoogle Scholar
  4. Schulten H-R (1993) Analytical pyrolysis of humic substances and soils: geochemical, agricultural and ecological consequences. J Anal Appl Pyrolysis 25: 97–122CrossRefGoogle Scholar
  5. Schulten H-R, Murray KE, and Simmleit N (1987) Natural waxes investigated by soft ionization mass spectrometry. Z Naturforsch 42c: 178–190Google Scholar
  6. Schulten H-R, Schnitzer M (1992) Structural studies on soil humic acids by Curie-point pyrolysis-gas chromatography/mass spectrometry. Soil Sei 153: 205–224Google Scholar
  7. Schulten H-R, Simmleit N (1986) Impact of ozone on high-molecular constituents of beech leaves. Naturwissenschaften 73: 618–620Google Scholar
  8. Schulten H-R, Simmleit N, and Müller R (1987) High-temperature, high-sensitivity pyrolysisfield ionization mass spectrometry. Anal Chem 59: 2903–2908Google Scholar
  9. Schulten H-R, Simmleit N, and Müller R (1989) Characterization of plant materials by pyrolysis- field ionization mass spectrometry: high resolution mass spectrometry, time-resolved high resolution mass spectrometry, and pyrolysis-gas chromatography/mass spectrometry of spruce needles. Anal Chem 61: 221–227Google Scholar
  10. Schulten H-R, Simmleit N, and Rump HH (1986a) Soft ionization mass spectrometry of epicuticular waxes isolated from coniferous needles. Chem Phys Lipids 41: 209–224Google Scholar
  11. Schulten H-R, Simmleit N, and Rump HH (1987b) Forest damage: characterization of spruce needles by pyrolysis-field ionization mass spectrometry. Intern J Environ Anal Chem 27: 241–264Google Scholar
  12. Simmleit N, Herrmann R, Wild A, Forschner W, Gärtner E, Eichhorn J, and Schulten H-R (1990) Multivariate statistical evaluation of biometric, physiological, and chemical parameters describing the vitality of Norway spruce trees. Sei Total Environ 106: 195–219CrossRefGoogle Scholar
  13. Simmleit N, Schulten H-R (1989a) Differentiation of spruce needles by integrated field ionization mass spectra and principal component analysis. Biomed Environ Mass Spectrom 18: 1023–1029CrossRefGoogle Scholar
  14. Simmleit N, Schulten H-R (1989b) Pattern recognition of spruce trees: an integrated, analytical approach to forest damage. Environ Sei Technol 23: 1000–1006CrossRefGoogle Scholar
  15. Simmleit N, Schulten H-R (1989c) Analytical pyrolysis and environmental research. J Anal Appl Pyrolysis 15: 3–28CrossRefGoogle Scholar
  16. Simmleit N, Toth A, Szekely T, and Schulten H-R (1989) Characterization of particles adsorbed on plant surfaces. J Environ Anal Chem 36: 7–11CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 1994

Authors and Affiliations

  • Hans-Rolf Schulten
    • 1
  1. 1.Department of Trace AnalysisFachhochschule FreseniusWiesbadenGermany

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