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Applications of Synchrotron Radiation pp 65–126Cite as

High-Resolution Core-Level Photoelectron Spectroscopy of Surfaces and Adsorbates

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Part of the book series: Springer Series in Surface Sciences ((SSSUR,volume 35))

Abstract

In the present chapter we will discuss some general aspects of core-level photoelectron spectroscopy for the investigation of surfaces and adsorbates. We will focus on a few aspects of this spectroscopy. In Sect. 3.2 some experimental comments will be given of a general nature and referring to the systems which have been used in most of the studies reviewed in this contribution. Sections 3.3-5 deal with core-level shifts, Section 3.3 gives a general introduction and discusses the role of initial and final state effects, Section 3.4 treats shifts of adsórbate lines, and Sect. 3.5 deals with surface core-level shifts for metals. Section 3.6-8 discuss core-level line shapes and core-level satellites. In Sect. 3.6 the most important contributions to the line shape are reviewed. Section 3.7 discusses vibrational broadening, and Sect. 3.8 then deals with shake-up satellites for adsorbates.

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References

  1. K. Siegbahn, C. Nordling, G. Johansson, J. Hedman, P.F. Heden, K. Hamrin, U. Gelius, T. Bergmark, L.O. Werme, R. Manne, Y. Baer: ESC A Applied to Free Molecules (North- Holland, Amsterdam 1969)

    Google Scholar 

  2. C.S. Fadley: Electron Spectroscopy: Theory, Techniques and Applications (Academic Press, New York 1978) Vol. 2

    Google Scholar 

  3. B. Feuerbacher, B. Fitton, R.F. Willis (eds.): Photoemission and the Electronic Properties of Surfaces (Wiley, New York 1978)

    Google Scholar 

  4. D. Menzel: In Chemistry and Physics of Solid Surfaces, ed. by R. Vanselow. (CRC Press, Boca Raton, FL 1979) Vol. II, p. 277

    Google Scholar 

  5. H. Siegbahn, L. Karlsson: In Corpuscles and Radiation in Matter, ed. by W. Mehlhorn, Handbuch der Physik, Vol. 31 (Springer, Berlin, Heidelberg 1982), vol. XXXI

    Google Scholar 

  6. M. Scheffler, A.M. Bradshaw: In The Chemical Physics of Solid Surfaces and Heterogenous Catalysis, ed. by D.A. King, D.P. Woodruff, (Elsevier, Oxford 1983) Vol. 2, p. 165

    Google Scholar 

  7. E.W. Plummer, C.T. Chen, W.K. Ford, W. Eberhardt, R.P. Messner, H. J. Freund: Surf. Sei. 158, 58 (1985)

    CAS  Google Scholar 

  8. W.F. Egelhoff: Surf. Sei. Reps. 6, 253 (1986)

    CAS  Google Scholar 

  9. N. Mårtensson, A. Nilsson: J. Elec. Spec, and Relat. Phenom. 52, 1 (1990)

    Google Scholar 

  10. J. Stöhr: NEXAFS Spectroscopy Springer Ser. Surf. Sei., Vol. 25 (Springer, Berlin, Heidelberg 1992)

    Google Scholar 

  11. A. Nilsson, E. Zdansky, H. Tillborg, O. Björneholm, N. Mårtensson, J.N. Andersen, R. Nyholm: Chem. Phys. Lett. 197, 12 (1992)

    CAS  Google Scholar 

  12. J.C. Fuggle: In Electron Spectroscopy IV ed. by C.R. Brundle, A.D. Baker, (Academic London 1981) p. 85

    Google Scholar 

  13. O. Björneholm, A. Sandell, A. Nilsson, N. Mårtensson, J.N. Andersen: Physica Scripta T41, 217 (1992)

    Google Scholar 

  14. J. Nordgren, N. Wassdahl: Physica Scripta T 31, 103 (1990)

    Google Scholar 

  15. N. Wassdahl, A. Nilsson, T. Wiell, H. Tillborg, L.-C. Duda, J.H. Guo, N. Mårtensson, J. Nordgren, J.N. Andersen, R. Nyholm, Phys. Rev. Lett. 69, 812 (1992)

    CAS  Google Scholar 

  16. C.S. Fadley, In Synchrotron Radiation Research: Advances in Surface and Interface Science, ed. by R.Z. Bachrach (Plenum, New York 1992) p. 421

    Google Scholar 

  17. A. Nilsson, A. Stenborg, O. Björneholm, N. Mårtensson, J.N. Andersen, C. Wigren (to be published)

    Google Scholar 

  18. N. Mårtensson, A. Stenborg, O. Björneholm, A. Nilsson, J.N. Andersen: Phys. Rev. Lett. 60, 1731 (1988)

    Google Scholar 

  19. A. Nilsson, B. Eriksson, N. Mårtensson, J.N. Andersen, J. Onsgaard: Phys. Rev. B 38, 10357 (1988)

    CAS  Google Scholar 

  20. T.A. Carlsson: Phys. Rev. 156, 142 (1967)

    Google Scholar 

  21. N. Mårtensson, S. Svensson, U. Gelius: J. Phys. B 20, 6243 (1987)

    Google Scholar 

  22. S. Svensson, B. Eriksson, N. Mårtensson, U. Gelius, G. Wendin: J. Elec. Spec, and Relat. Phenom. 47, 327 (1988)

    CAS  Google Scholar 

  23. L.J. Saethre, T.D. Thomas, L. Ungier: J. Elec. Spec, and Relat. Phenom. 33, 381 (1984)

    CAS  Google Scholar 

  24. L. Asplund, U. Gelius, S. Hedman, K. Helenelund, K. Siegbahn, P.E.M. Siegbahn: J. Phys. B 18, 1569 (1985)

    CAS  Google Scholar 

  25. U. Gelius, S. Svensson, H. Siegbahn, E. Basilier, Ä. Faxälv, K. Siegbahn: Chem. Phys. Lett. 28, 1 (1974)

    CAS  Google Scholar 

  26. A. Nilsson, N. Mårtensson: Solid State Commun. 70, 923 (1989)

    CAS  Google Scholar 

  27. A. Nilsson, N. Mårtensson: Phys. Rev. Lett. 63, 1483 (1989)

    CAS  Google Scholar 

  28. N. Mårtensson: P. Baltzer, P.A. Brühwiler, J. Forsell, A. Nilsson, A. Stenborg, B. Wannberg, J. Elec. Spec, and Relat. Phenom., In press

    Google Scholar 

  29. P. Baltzer, L. Karlsson, M. Lundqvist, B. Wannberg: Rev. Sei. Instrum. 64, 2174 (1993)

    Google Scholar 

  30. J.N. Andersen, O. Björneholm, A. Sandell, R. Nyholm, J. Forsell, L. Thänell, A. Nilsson, N. Mårtensson: Synchrotron Radiation News 4, 15 (1991)

    Google Scholar 

  31. A. Nilsson, N. Mårtensson: Phys. Rev. B 40, 10249 (1989)

    CAS  Google Scholar 

  32. U. Gelius, L. Asplund, E. Basilier, S. Hedman, K. Helenelund, K. Siegbahn, Nucl. Instrum. and Meth. B 1, 85 (1984)

    Google Scholar 

  33. B. Johansson, N. Mårtensson: Phys. Rev. B 21, 4427 (1980)

    CAS  Google Scholar 

  34. A. Nilsson, H. Tillborg, N. Mårtensson, Phys. Rev. Lett. 67, 1015 (1991)

    CAS  Google Scholar 

  35. W.F. Egelhoff Jr.: Surf. Sei 141, L324 (1984)

    CAS  Google Scholar 

  36. H. Antonsson, A. Nilsson, N. Mårtensson, I. Panas, P.E.M. Siegbahn: J. Elec. Spec, and Relat. Phenom. 54/55, 601 (1990)

    Google Scholar 

  37. A. Nilsson, H. Antonsson, A. Sandeil, N. Mårtensson: In The Structure of Surfaces III Springer Ser. Surf, Sei, Vol. 24 (Springer, Berlin, Heidelberg 1991) p. 467

    Google Scholar 

  38. H. Baseh: J. Elec. Spec, and Relat. Phenom. 5, 463 (1974)

    Google Scholar 

  39. U. Gelius: J. Elec. Spec, and Relat. Phenom. 5, 985 (1974)

    CAS  Google Scholar 

  40. A. Nilsson, R.E. Palmer, H. Tillborg, B. Hernnäs, R.J. Guest, N. Mårtensson: Phys. Rev. Lett. 68, 982 (1992)

    CAS  Google Scholar 

  41. M. Larsson, P. Baltzer, S. Svensson, B. Wannberg, N. Mårtensson, A. Naves de Brito, N. Correia, M.P. Keane, M. Carlsson-Göthe, L. Karlsson: J. Phys. B 23, 1175 (1990)

    CAS  Google Scholar 

  42. R.M. Lambert, M.E. Bridge: In The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis, ed. by D.A. King, D.P. Woodruff, (Elsevier, New York 1984), Vol. 3B

    Google Scholar 

  43. A. Sandell, A. Nilsson, N. Mårtensson: Surf. Sei.251/252, 971 (1991)

    Google Scholar 

  44. P. Uvdal, P.A. Karlsson, C. Nyberg, S. Andersson, N.V. Richardsson: Surf. Sei. 202,167 (1988)

    CAS  Google Scholar 

  45. H. Tillborg, A. Nilsson, N. Mårtensson: Surf. Sei. 273, 47 (1992)

    CAS  Google Scholar 

  46. L. Westerlund, L. Jönsson, S. Andersson: Surf. Sei. 199, 109 (1988)

    CAS  Google Scholar 

  47. P.R. Norton, J.W. Goodale, E.B. Selkirk: Surf. Sei. 83, 189 (1979)

    CAS  Google Scholar 

  48. H. Tillborg, A. Nilsson, N. Mårtensson: To be published

    Google Scholar 

  49. A. Sandell, A. Nilsson, N. Mårtensson, Surf. Sei. 241, LI (1991)

    Google Scholar 

  50. J. Stöhr, R. Jaeger: Phys. Rev. B 26, 411 (1982)

    Google Scholar 

  51. J.L. Gland, B.A. Sexton, G.B. Fisher: Surf. Sei. 95, 587 (1980)

    CAS  Google Scholar 

  52. W. Wurth, J. Stöhr, P. Feulner, X. Pan, K.R. Bauchspiess, Y. Baba, E. Hudel, G. Rocker, D. Menzel: Phys. Rev. Lett. 65, 2426 (1990)

    CAS  Google Scholar 

  53. R.J. Guest, O. Björneholm, B. Hernnäs, A. Nilsson, R.E. Palmer, P. Bennich, N. Mårtensson: Surf. Sei. 278, 239 (1992)

    CAS  Google Scholar 

  54. G. Odörfer, R. Jaeger, G. Illing, H. Kuhlenbeck, H.J. Freund: Surf. Sei. 233, 44 (1990)

    Google Scholar 

  55. R.E. Palmer, P.J. Rous: Rev. Mod. Phys. 64, 383 (1992)

    CAS  Google Scholar 

  56. R.J. Guest, A. Nilsson, O. Björneholm, B. Hernnäs, A. Sandell, R.E. Palmer, N. Mårtensson: Surf. Sei. 269/270, 432 (1992)

    Google Scholar 

  57. H. Tillborg, A. Nilsson, B. Hernnäs, N. Mårtensson, R.E. Palmer: Surf. Sei. 295, 1 (1993)

    CAS  Google Scholar 

  58. T.-C. Chiang, G. Kaindl, T. Mandel: Phys. Rev. B 33, 695 (1986)

    CAS  Google Scholar 

  59. G. Kaindl, T.C. Chiang, D.E. Eastman, F.J. Himpsel: Phys. Rev. Lett. 45, 1808 (1980)

    CAS  Google Scholar 

  60. K. Jacobi, H.H. Rotermund: Surf. Sei. 116, 435 (1982)

    CAS  Google Scholar 

  61. T. Mandel, M. Domke, G. Kaindl, C. Laubschat, M. Prietsch, U. Middelman, K. Horn: Surf. Sei. 162, 453 (1985)

    CAS  Google Scholar 

  62. K. Jacobi: Phys. Rev. B 38, 6291 (1988)

    CAS  Google Scholar 

  63. D. Nordfors, H. Ågren, K.V. Mikkelsen: Chem. Phys. Lett. 164, 173 (1992)

    CAS  Google Scholar 

  64. B. Johansson, N. Mårtensson: Helvetica Physica Acta 56, 405 (1983)

    CAS  Google Scholar 

  65. P.H. Citrin, G.K. Wertheim: Phys. Rev. B 27, 3176 (1983)

    Google Scholar 

  66. D. Spanjard, C. Guillot, M.C. Desjonqueres: Surf. Sei. Rep. 5, 1 (1985)

    Google Scholar 

  67. A. Flodsröm, R. Nyholm, B. Johansson: In Synchrotron Radiation Research: Advances in Surface and Interface Science, ed. by R.Z. Bachrach. (Plenum, New York 1992) Vol. 1, p. 199

    Google Scholar 

  68. W.F. Egelhoff Jr.: Crit. Rev. of Solid State and Mathematical Sei. 16, 213 (1990)

    CAS  Google Scholar 

  69. N. Mårtensson, H.B. Saalfeld, H. Kuhlenbeck, M. Nuemann: Phys. Rev. B 39, 8181 (1989)

    Google Scholar 

  70. D. Tomänek, V. Kumar, S. Holloway, K. H. Bennemann: Solid State Commun. 41, 273 (1982)

    Google Scholar 

  71. A. Rosengren, B. Johansson: Phys. Rev. B 22, 3706 (1980)

    CAS  Google Scholar 

  72. A. Nilsson, O. Björneholm, A. Sandell, P. Bennich, B. Hernnäs, C. Puglia, N. Mårtensson: To be published

    Google Scholar 

  73. A. Sandell, P. Bennich, A. Nilsson, B. Hernnäs, O. Björneholm, N. Mårtensson: Surf. Sei., 310, 16 (1994)

    CAS  Google Scholar 

  74. O. Björneholm, A. Nilsson, H. Tillborg, P. Bennich, A. Sandell, B. Hernnäs, C. Puglia, N. Mårtensson: Surf. Sei., In press

    Google Scholar 

  75. M. Tüshaus, E. Schweizer, P. Hollins, A.M. Bradshaw: J Elec. Spec, and Relat. Phenom. 44, 305 (1987)

    Google Scholar 

  76. M.O. Krause, J.H. Oliver: J. Phys. and Chem. Ref. Data 8, 329 (1979)

    CAS  Google Scholar 

  77. S. Svensson, N. Mårtensson, E. Basilier, P.-Å. Malmquist, U. Gelius, K. Siegbahn: Physica Scripta 14, 141 (1976)

    CAS  Google Scholar 

  78. G. Wendin, M. Ohno: Physica Scripta 14, 148 (1976)

    CAS  Google Scholar 

  79. S. Doniach, M. Sunjic: J. Phys. C 3, 285 (1970)

    CAS  Google Scholar 

  80. S. Tougaard: Phys. Rev. B 34, 6779 (1986)

    CAS  Google Scholar 

  81. H. Wiedemann: Particle Accelerator Physics (Springer, Berlin, Heidelberg 1993)

    Google Scholar 

  82. M. Bader, C. Ocal, B. Hillert, J. Haase, A.M. Bradshaw: Phys. Rev. B 35, 5900 (1987)

    CAS  Google Scholar 

  83. L. Wenzel, D. Arvanitis, W. Daum, H.H. Rotermund, J. Stöhr, K. Baberschke, H. Ibach: Phys. Rev. B 36, 7689 (1987)

    CAS  Google Scholar 

  84. J. Stöhr, R. Jaeger, T. Kendelewicz: Phys. Rev. Lett. 49, 142 (1982)

    Google Scholar 

  85. W. Daum, S. Lehwald, H. Ibach: Surf. Sei. 178, 528 (1986)

    CAS  Google Scholar 

  86. M. Rocca, S. Lehwald, H. Ibach, T.S. Rahman: Phys. Rev. B 35, 9510 (1987)

    CAS  Google Scholar 

  87. M. Rocca, S. Lehwald, H. Ibach: Surf. Sei. 163, L738 (1985)

    CAS  Google Scholar 

  88. N. Mårtensson, A. Nilsson: Surf Sei. 211/212, 303 (1989)

    Google Scholar 

  89. J. Schirmer, G. Angonoa, S. Svensson, D. Nordfors, U. Gelius: J. Phys. B 20, 6031 (1987)

    CAS  Google Scholar 

  90. A.P. Hitchcock, C.E. Brion: J. Elec. Spec, and Relat. Phenom. 18, 1 (1980)

    CAS  Google Scholar 

  91. A. Nilsson, N. Mårtensson, S. Svensson, L. Karlsson, D. Nordfors, U. Gelius, H. Ågren: J. Chem. Phys. 96, 8770 (1992)

    CAS  Google Scholar 

  92. S. Andersson, Solid State Commun. 21, 75 (1977)

    CAS  Google Scholar 

  93. R. Berndt, J.P. Toennies, C. Wöll: J. Elec. Spec. 44, 183 (1987)

    CAS  Google Scholar 

  94. N.V. Richardson, A.M. Bradshaw: Surf. Sei. 88, 255 (1979)

    CAS  Google Scholar 

  95. A.M. Lahee, J.P. Toennies, C. Wöll: Surf. Sei. 177, 371 (1986)

    CAS  Google Scholar 

  96. G. Doyen, G. Ertl: Surf. Sei. 69, 157 (1977)

    CAS  Google Scholar 

  97. R.L. Martin, D.A. Shirley: Phys. Rev. A 13, 1475 (1976)

    CAS  Google Scholar 

  98. R. Arneberg, J. Müller, R. Manne: Chemical Physics 64, 249 (1982)

    CAS  Google Scholar 

  99. T. Äberg: Ann. Acad. Sei. Fennicae (Ser. A) IV, 308 (1969)

    Google Scholar 

  100. R. Manne, T. Äberg: Chem. Phys. Lett. 7, 282 (1970)

    CAS  Google Scholar 

  101. B.I. Lundqvist: Phys. Kondens. Materie 9, 236 (1969)

    CAS  Google Scholar 

  102. A. Sandell, A. Nilsson, P. Bennich, N. Mårtensson: Phys. Rev. Lett. 72, 2604 (1994)

    CAS  Google Scholar 

  103. A. Hoffman, G.L. Nyberg, J. Liesegang: Phys. Rev. B 45, 5679 (1992)

    CAS  Google Scholar 

  104. A. Nilsson, O. Björneholm, A. Sandell, B. Hernnäs, N. Mårtensson: Surf. Sei. 293, L835 (1993)

    CAS  Google Scholar 

  105. N. Mårtensson, R. Nyholm, B. Johansson: Phys. Rev, B 29 (1984)

    Google Scholar 

  106. C.W. Bates, G.K. Wertheim, D.N.E. Buchanan, Phys. Lett. A 72, 178 (1979)

    Google Scholar 

  107. R.A. Pollak, L. Ley, F.R. McFeely, S.P. Kowalczyk, D.A. Shirley: J. Elec. Spec, and Relat. Phenom. 3, 381 (1974)

    CAS  Google Scholar 

  108. D. Lovric, B. Gumhalter: Phys. Rev. B 38, 10323 (1988)

    CAS  Google Scholar 

  109. A. Nilsson, N. Mårtensson: Chem. Phys. Lett. 182, 147 (1991)

    CAS  Google Scholar 

  110. E. Zdansky, A. Nilsson, H. Tillborg, O. Björneholm, N. Mårtensson, J.N. Andersen, R. Nyholm: Phys. Rev. B 48, 2632 (1993)

    CAS  Google Scholar 

  111. H. Tillborg, A. Nilsson, T. Wiell, N. Wassdahl, N. Mårtensson, J. Nordgren: Phys. Rev. B 47, 16464 (1993)

    CAS  Google Scholar 

  112. C.E. Moore: Atomic Energy Levels (National Bureau of Standards, Washington, DC 1949 Vol. 1

    Google Scholar 

  113. C.W. Bauschlichter: J. Chem. and Phys. 84, 250 (1986)

    Google Scholar 

  114. A. Bosch, H. Feil, G.A. Sawatzky, N. Mårtensson, Solid State Commun. 41, 355 (1982)

    CAS  Google Scholar 

  115. J.C. Fuggle, U.E, D. Menzel, K. Wandelt, C.R. Brundle: Solid State Commun. 27, 65 (1978)

    CAS  Google Scholar 

  116. E. Umbach: Surf. Sei. 117, 482 (1982)

    CAS  Google Scholar 

  117. K. Schönhammer, O. Gunnarsson: Solid State Commun. 23, 691 (1977)

    Google Scholar 

  118. O. Gunnarsson, K. Schönhammer: Phys. Rev. Lett. 41, 1608 (1978)

    CAS  Google Scholar 

  119. P.S. Bagus, M. Seel: Phys. Rev. B 23, 2065 (1981)

    CAS  Google Scholar 

  120. H.-J. Freund, E.W. Plummer: Phys. Rev. B 23, 4859 (1981)

    CAS  Google Scholar 

  121. R.P. Messmer, S.H. Lamson, D.R. Salahub: Phys. Rev. B 25, 3576 (1982)

    CAS  Google Scholar 

  122. H.J. Freund, F. Greuter, D. Heskett, E.W. Plummer, Phys. Rev. B 28, 1727 (1983)

    CAS  Google Scholar 

  123. E. Umbach: Solid State Commun. 51, 365 (1984)

    CAS  Google Scholar 

  124. H.-J. Freund, R.P. Messmer, C.M. Kao, E.W. Plummer: Phys. Rev. B 31, 4848 (1985)

    CAS  Google Scholar 

  125. D. Lovric, B. Gumhalter, K. Wandelt: Surf. Sei. 278, 1 (1992)

    CAS  Google Scholar 

  126. H. Tillborg, A. Nilsson, N. Mårtensson: J. Elec. Spec, and Relat. Phenom. 62, 73 (1993)

    CAS  Google Scholar 

  127. O. Björneholm, A. Nilsson, E. Zdansky, A. Sandell, H. Tillborg, B. Hernnäs, N. Mårtensson, J.N. Andersen: Phys. Rev. B 47, 2308 (1993)

    Google Scholar 

  128. P. Avouris, N.J. Dinardo, J.E. Demuth: J. Chem. and Phys. 80, 491 (1984)

    CAS  Google Scholar 

  129. J. Burstad, C. Engkvist, S. Lunell, H. Tillborg, A. Nilsson, S. Osborne, N. Mårtensson, S. Svensson: Chem. Phys. 179, 303 (1994)

    Google Scholar 

  130. O. Björneholm, A. Nilsson, E. Zdansky, A. Sandell, H. Tillborg, N. Mårtensson, J.N. Andersen, R. Nyholm: Phys. Rev. B 46, 10353 (1992)

    Google Scholar 

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  1. N. Mårtensson
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  1. Institut für Festkörperforschung, KFA Jülich, 52425, Jülich, Germany

    Wolfgang Eberhardt

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Mårtensson, N., Nilsson, A. (1995). High-Resolution Core-Level Photoelectron Spectroscopy of Surfaces and Adsorbates. In: Eberhardt, W. (eds) Applications of Synchrotron Radiation. Springer Series in Surface Sciences, vol 35. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-79024-9_3

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