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High-Resolution Core-Level Photoelectron Spectroscopy of Surfaces and Adsorbates

  • N. Mårtensson
  • A. Nilsson
Part of the Springer Series in Surface Sciences book series (SSSUR, volume 35)

Abstract

In the present chapter we will discuss some general aspects of core-level photoelectron spectroscopy for the investigation of surfaces and adsorbates. We will focus on a few aspects of this spectroscopy. In Sect. 3.2 some experimental comments will be given of a general nature and referring to the systems which have been used in most of the studies reviewed in this contribution. Sections 3.3-5 deal with core-level shifts, Section 3.3 gives a general introduction and discusses the role of initial and final state effects, Section 3.4 treats shifts of adsórbate lines, and Sect. 3.5 deals with surface core-level shifts for metals. Section 3.6-8 discuss core-level line shapes and core-level satellites. In Sect. 3.6 the most important contributions to the line shape are reviewed. Section 3.7 discusses vibrational broadening, and Sect. 3.8 then deals with shake-up satellites for adsorbates.

Keywords

Potential Energy Curve Lower Binding Energy Bridge Site Core Ionization Core Hole 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 3.1
    K. Siegbahn, C. Nordling, G. Johansson, J. Hedman, P.F. Heden, K. Hamrin, U. Gelius, T. Bergmark, L.O. Werme, R. Manne, Y. Baer: ESC A Applied to Free Molecules (North- Holland, Amsterdam 1969)Google Scholar
  2. 3.2
    C.S. Fadley: Electron Spectroscopy: Theory, Techniques and Applications (Academic Press, New York 1978) Vol. 2Google Scholar
  3. 3.3
    B. Feuerbacher, B. Fitton, R.F. Willis (eds.): Photoemission and the Electronic Properties of Surfaces (Wiley, New York 1978)Google Scholar
  4. 3.4
    D. Menzel: In Chemistry and Physics of Solid Surfaces, ed. by R. Vanselow. (CRC Press, Boca Raton, FL 1979) Vol. II, p. 277Google Scholar
  5. 3.5
    H. Siegbahn, L. Karlsson: In Corpuscles and Radiation in Matter, ed. by W. Mehlhorn, Handbuch der Physik, Vol. 31 (Springer, Berlin, Heidelberg 1982), vol. XXXIGoogle Scholar
  6. 3.6
    M. Scheffler, A.M. Bradshaw: In The Chemical Physics of Solid Surfaces and Heterogenous Catalysis, ed. by D.A. King, D.P. Woodruff, (Elsevier, Oxford 1983) Vol. 2, p. 165Google Scholar
  7. 3.7
    E.W. Plummer, C.T. Chen, W.K. Ford, W. Eberhardt, R.P. Messner, H. J. Freund: Surf. Sei. 158, 58 (1985)Google Scholar
  8. 3.8
    W.F. Egelhoff: Surf. Sei. Reps. 6, 253 (1986)Google Scholar
  9. 3.9
    N. Mårtensson, A. Nilsson: J. Elec. Spec, and Relat. Phenom. 52, 1 (1990)Google Scholar
  10. 3.10
    J. Stöhr: NEXAFS Spectroscopy Springer Ser. Surf. Sei., Vol. 25 (Springer, Berlin, Heidelberg 1992)Google Scholar
  11. 3.11
    A. Nilsson, E. Zdansky, H. Tillborg, O. Björneholm, N. Mårtensson, J.N. Andersen, R. Nyholm: Chem. Phys. Lett. 197, 12 (1992)Google Scholar
  12. 3.12
    J.C. Fuggle: In Electron Spectroscopy IV ed. by C.R. Brundle, A.D. Baker, (Academic London 1981) p. 85Google Scholar
  13. 3.13
    O. Björneholm, A. Sandell, A. Nilsson, N. Mårtensson, J.N. Andersen: Physica Scripta T41, 217 (1992)Google Scholar
  14. 3.14
    J. Nordgren, N. Wassdahl: Physica Scripta T 31, 103 (1990)Google Scholar
  15. 3.15
    N. Wassdahl, A. Nilsson, T. Wiell, H. Tillborg, L.-C. Duda, J.H. Guo, N. Mårtensson, J. Nordgren, J.N. Andersen, R. Nyholm, Phys. Rev. Lett. 69, 812 (1992)Google Scholar
  16. 3.16
    C.S. Fadley, In Synchrotron Radiation Research: Advances in Surface and Interface Science, ed. by R.Z. Bachrach (Plenum, New York 1992) p. 421Google Scholar
  17. 3.17
    A. Nilsson, A. Stenborg, O. Björneholm, N. Mårtensson, J.N. Andersen, C. Wigren (to be published)Google Scholar
  18. 3.18
    N. Mårtensson, A. Stenborg, O. Björneholm, A. Nilsson, J.N. Andersen: Phys. Rev. Lett. 60, 1731 (1988)Google Scholar
  19. 3.19
    A. Nilsson, B. Eriksson, N. Mårtensson, J.N. Andersen, J. Onsgaard: Phys. Rev. B 38, 10357 (1988)Google Scholar
  20. 3.20
    T.A. Carlsson: Phys. Rev. 156, 142 (1967)Google Scholar
  21. 3.21
    N. Mårtensson, S. Svensson, U. Gelius: J. Phys. B 20, 6243 (1987)Google Scholar
  22. 3.22
    S. Svensson, B. Eriksson, N. Mårtensson, U. Gelius, G. Wendin: J. Elec. Spec, and Relat. Phenom. 47, 327 (1988)Google Scholar
  23. 3.23
    L.J. Saethre, T.D. Thomas, L. Ungier: J. Elec. Spec, and Relat. Phenom. 33, 381 (1984)Google Scholar
  24. 3.24
    L. Asplund, U. Gelius, S. Hedman, K. Helenelund, K. Siegbahn, P.E.M. Siegbahn: J. Phys. B 18, 1569 (1985)Google Scholar
  25. 3.25
    U. Gelius, S. Svensson, H. Siegbahn, E. Basilier, Ä. Faxälv, K. Siegbahn: Chem. Phys. Lett. 28, 1 (1974)Google Scholar
  26. 3.26
    A. Nilsson, N. Mårtensson: Solid State Commun. 70, 923 (1989)Google Scholar
  27. 3.27
    A. Nilsson, N. Mårtensson: Phys. Rev. Lett. 63, 1483 (1989)Google Scholar
  28. 3.28
    N. Mårtensson: P. Baltzer, P.A. Brühwiler, J. Forsell, A. Nilsson, A. Stenborg, B. Wannberg, J. Elec. Spec, and Relat. Phenom., In pressGoogle Scholar
  29. 3.29
    P. Baltzer, L. Karlsson, M. Lundqvist, B. Wannberg: Rev. Sei. Instrum. 64, 2174 (1993)Google Scholar
  30. 3.30
    J.N. Andersen, O. Björneholm, A. Sandell, R. Nyholm, J. Forsell, L. Thänell, A. Nilsson, N. Mårtensson: Synchrotron Radiation News 4, 15 (1991)Google Scholar
  31. 3.31
    A. Nilsson, N. Mårtensson: Phys. Rev. B 40, 10249 (1989)Google Scholar
  32. 3.32
    U. Gelius, L. Asplund, E. Basilier, S. Hedman, K. Helenelund, K. Siegbahn, Nucl. Instrum. and Meth. B 1, 85 (1984)Google Scholar
  33. 3.33
    B. Johansson, N. Mårtensson: Phys. Rev. B 21, 4427 (1980)Google Scholar
  34. 3.34
    A. Nilsson, H. Tillborg, N. Mårtensson, Phys. Rev. Lett. 67, 1015 (1991)Google Scholar
  35. 3.35
    W.F. Egelhoff Jr.: Surf. Sei 141, L324 (1984)Google Scholar
  36. 3.36
    H. Antonsson, A. Nilsson, N. Mårtensson, I. Panas, P.E.M. Siegbahn: J. Elec. Spec, and Relat. Phenom. 54/55, 601 (1990)Google Scholar
  37. 3.37
    A. Nilsson, H. Antonsson, A. Sandeil, N. Mårtensson: In The Structure of Surfaces III Springer Ser. Surf, Sei, Vol. 24 (Springer, Berlin, Heidelberg 1991) p. 467Google Scholar
  38. 3.38
    H. Baseh: J. Elec. Spec, and Relat. Phenom. 5, 463 (1974)Google Scholar
  39. 3.39
    U. Gelius: J. Elec. Spec, and Relat. Phenom. 5, 985 (1974)Google Scholar
  40. 3.40
    A. Nilsson, R.E. Palmer, H. Tillborg, B. Hernnäs, R.J. Guest, N. Mårtensson: Phys. Rev. Lett. 68, 982 (1992)Google Scholar
  41. 3.41
    M. Larsson, P. Baltzer, S. Svensson, B. Wannberg, N. Mårtensson, A. Naves de Brito, N. Correia, M.P. Keane, M. Carlsson-Göthe, L. Karlsson: J. Phys. B 23, 1175 (1990)Google Scholar
  42. 3.42
    R.M. Lambert, M.E. Bridge: In The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis, ed. by D.A. King, D.P. Woodruff, (Elsevier, New York 1984), Vol. 3BGoogle Scholar
  43. 3.43
    A. Sandell, A. Nilsson, N. Mårtensson: Surf. Sei.251/252, 971 (1991)Google Scholar
  44. 3.44
    P. Uvdal, P.A. Karlsson, C. Nyberg, S. Andersson, N.V. Richardsson: Surf. Sei. 202,167 (1988)Google Scholar
  45. 3.45
    H. Tillborg, A. Nilsson, N. Mårtensson: Surf. Sei. 273, 47 (1992)Google Scholar
  46. 3.46
    L. Westerlund, L. Jönsson, S. Andersson: Surf. Sei. 199, 109 (1988)Google Scholar
  47. 3.47
    P.R. Norton, J.W. Goodale, E.B. Selkirk: Surf. Sei. 83, 189 (1979)Google Scholar
  48. 3.48
    H. Tillborg, A. Nilsson, N. Mårtensson: To be publishedGoogle Scholar
  49. 3.49
    A. Sandell, A. Nilsson, N. Mårtensson, Surf. Sei. 241, LI (1991)Google Scholar
  50. 3.50
    J. Stöhr, R. Jaeger: Phys. Rev. B 26, 411 (1982)Google Scholar
  51. 3.51
    J.L. Gland, B.A. Sexton, G.B. Fisher: Surf. Sei. 95, 587 (1980)Google Scholar
  52. 3.52
    W. Wurth, J. Stöhr, P. Feulner, X. Pan, K.R. Bauchspiess, Y. Baba, E. Hudel, G. Rocker, D. Menzel: Phys. Rev. Lett. 65, 2426 (1990)Google Scholar
  53. 3.53
    R.J. Guest, O. Björneholm, B. Hernnäs, A. Nilsson, R.E. Palmer, P. Bennich, N. Mårtensson: Surf. Sei. 278, 239 (1992)Google Scholar
  54. 3.54
    G. Odörfer, R. Jaeger, G. Illing, H. Kuhlenbeck, H.J. Freund: Surf. Sei. 233, 44 (1990)Google Scholar
  55. 3.55
    R.E. Palmer, P.J. Rous: Rev. Mod. Phys. 64, 383 (1992)Google Scholar
  56. 3.56
    R.J. Guest, A. Nilsson, O. Björneholm, B. Hernnäs, A. Sandell, R.E. Palmer, N. Mårtensson: Surf. Sei. 269/270, 432 (1992)Google Scholar
  57. 3.57
    H. Tillborg, A. Nilsson, B. Hernnäs, N. Mårtensson, R.E. Palmer: Surf. Sei. 295, 1 (1993)Google Scholar
  58. 3.58
    T.-C. Chiang, G. Kaindl, T. Mandel: Phys. Rev. B 33, 695 (1986)Google Scholar
  59. 3.59
    G. Kaindl, T.C. Chiang, D.E. Eastman, F.J. Himpsel: Phys. Rev. Lett. 45, 1808 (1980)Google Scholar
  60. 3.60
    K. Jacobi, H.H. Rotermund: Surf. Sei. 116, 435 (1982)Google Scholar
  61. 3.61
    T. Mandel, M. Domke, G. Kaindl, C. Laubschat, M. Prietsch, U. Middelman, K. Horn: Surf. Sei. 162, 453 (1985)Google Scholar
  62. 3.62
    K. Jacobi: Phys. Rev. B 38, 6291 (1988)Google Scholar
  63. 3.63
    D. Nordfors, H. Ågren, K.V. Mikkelsen: Chem. Phys. Lett. 164, 173 (1992)Google Scholar
  64. 3.64
    B. Johansson, N. Mårtensson: Helvetica Physica Acta 56, 405 (1983)Google Scholar
  65. 3.65
    P.H. Citrin, G.K. Wertheim: Phys. Rev. B 27, 3176 (1983)Google Scholar
  66. 3.66
    D. Spanjard, C. Guillot, M.C. Desjonqueres: Surf. Sei. Rep. 5, 1 (1985)Google Scholar
  67. 3.67
    A. Flodsröm, R. Nyholm, B. Johansson: In Synchrotron Radiation Research: Advances in Surface and Interface Science, ed. by R.Z. Bachrach. (Plenum, New York 1992) Vol. 1, p. 199Google Scholar
  68. 3.68
    W.F. Egelhoff Jr.: Crit. Rev. of Solid State and Mathematical Sei. 16, 213 (1990)Google Scholar
  69. 3.69
    N. Mårtensson, H.B. Saalfeld, H. Kuhlenbeck, M. Nuemann: Phys. Rev. B 39, 8181 (1989)Google Scholar
  70. 3.70
    D. Tomänek, V. Kumar, S. Holloway, K. H. Bennemann: Solid State Commun. 41, 273 (1982)Google Scholar
  71. 3.71
    A. Rosengren, B. Johansson: Phys. Rev. B 22, 3706 (1980)Google Scholar
  72. 3.72
    A. Nilsson, O. Björneholm, A. Sandell, P. Bennich, B. Hernnäs, C. Puglia, N. Mårtensson: To be publishedGoogle Scholar
  73. 3.73
    A. Sandell, P. Bennich, A. Nilsson, B. Hernnäs, O. Björneholm, N. Mårtensson: Surf. Sei., 310, 16 (1994)Google Scholar
  74. 3.74
    O. Björneholm, A. Nilsson, H. Tillborg, P. Bennich, A. Sandell, B. Hernnäs, C. Puglia, N. Mårtensson: Surf. Sei., In pressGoogle Scholar
  75. 3.75
    M. Tüshaus, E. Schweizer, P. Hollins, A.M. Bradshaw: J Elec. Spec, and Relat. Phenom. 44, 305 (1987)Google Scholar
  76. 3.76
    M.O. Krause, J.H. Oliver: J. Phys. and Chem. Ref. Data 8, 329 (1979)Google Scholar
  77. 3.77
    S. Svensson, N. Mårtensson, E. Basilier, P.-Å. Malmquist, U. Gelius, K. Siegbahn: Physica Scripta 14, 141 (1976)Google Scholar
  78. 3.78
    G. Wendin, M. Ohno: Physica Scripta 14, 148 (1976)Google Scholar
  79. 3.79
    S. Doniach, M. Sunjic: J. Phys. C 3, 285 (1970)Google Scholar
  80. 3.80
    S. Tougaard: Phys. Rev. B 34, 6779 (1986)Google Scholar
  81. 3.81
    H. Wiedemann: Particle Accelerator Physics (Springer, Berlin, Heidelberg 1993)Google Scholar
  82. 3.82
    M. Bader, C. Ocal, B. Hillert, J. Haase, A.M. Bradshaw: Phys. Rev. B 35, 5900 (1987)Google Scholar
  83. 3.83
    L. Wenzel, D. Arvanitis, W. Daum, H.H. Rotermund, J. Stöhr, K. Baberschke, H. Ibach: Phys. Rev. B 36, 7689 (1987)Google Scholar
  84. 3.84
    J. Stöhr, R. Jaeger, T. Kendelewicz: Phys. Rev. Lett. 49, 142 (1982)Google Scholar
  85. 3.85
    W. Daum, S. Lehwald, H. Ibach: Surf. Sei. 178, 528 (1986)Google Scholar
  86. 3.86
    M. Rocca, S. Lehwald, H. Ibach, T.S. Rahman: Phys. Rev. B 35, 9510 (1987)Google Scholar
  87. 3.87
    M. Rocca, S. Lehwald, H. Ibach: Surf. Sei. 163, L738 (1985)Google Scholar
  88. 3.88
    N. Mårtensson, A. Nilsson: Surf Sei. 211/212, 303 (1989)Google Scholar
  89. 3.89
    J. Schirmer, G. Angonoa, S. Svensson, D. Nordfors, U. Gelius: J. Phys. B 20, 6031 (1987)Google Scholar
  90. 3.90
    A.P. Hitchcock, C.E. Brion: J. Elec. Spec, and Relat. Phenom. 18, 1 (1980)Google Scholar
  91. 3.91
    A. Nilsson, N. Mårtensson, S. Svensson, L. Karlsson, D. Nordfors, U. Gelius, H. Ågren: J. Chem. Phys. 96, 8770 (1992)Google Scholar
  92. 3.92
    S. Andersson, Solid State Commun. 21, 75 (1977)Google Scholar
  93. 3.93
    R. Berndt, J.P. Toennies, C. Wöll: J. Elec. Spec. 44, 183 (1987)Google Scholar
  94. 3.94
    N.V. Richardson, A.M. Bradshaw: Surf. Sei. 88, 255 (1979)Google Scholar
  95. 3.95
    A.M. Lahee, J.P. Toennies, C. Wöll: Surf. Sei. 177, 371 (1986)Google Scholar
  96. 3.96
    G. Doyen, G. Ertl: Surf. Sei. 69, 157 (1977)Google Scholar
  97. 3.97
    R.L. Martin, D.A. Shirley: Phys. Rev. A 13, 1475 (1976)Google Scholar
  98. 3.98
    R. Arneberg, J. Müller, R. Manne: Chemical Physics 64, 249 (1982)Google Scholar
  99. 3.99
    T. Äberg: Ann. Acad. Sei. Fennicae (Ser. A) IV, 308 (1969)Google Scholar
  100. 3.100
    R. Manne, T. Äberg: Chem. Phys. Lett. 7, 282 (1970)Google Scholar
  101. 3.101
    B.I. Lundqvist: Phys. Kondens. Materie 9, 236 (1969)Google Scholar
  102. 3.102
    A. Sandell, A. Nilsson, P. Bennich, N. Mårtensson: Phys. Rev. Lett. 72, 2604 (1994)Google Scholar
  103. 3.103
    A. Hoffman, G.L. Nyberg, J. Liesegang: Phys. Rev. B 45, 5679 (1992)Google Scholar
  104. 3.104
    A. Nilsson, O. Björneholm, A. Sandell, B. Hernnäs, N. Mårtensson: Surf. Sei. 293, L835 (1993)Google Scholar
  105. 3.105
    N. Mårtensson, R. Nyholm, B. Johansson: Phys. Rev, B 29 (1984)Google Scholar
  106. 3.106
    C.W. Bates, G.K. Wertheim, D.N.E. Buchanan, Phys. Lett. A 72, 178 (1979)Google Scholar
  107. 3.107
    R.A. Pollak, L. Ley, F.R. McFeely, S.P. Kowalczyk, D.A. Shirley: J. Elec. Spec, and Relat. Phenom. 3, 381 (1974)Google Scholar
  108. 3.108
    D. Lovric, B. Gumhalter: Phys. Rev. B 38, 10323 (1988)Google Scholar
  109. 3.109
    A. Nilsson, N. Mårtensson: Chem. Phys. Lett. 182, 147 (1991)Google Scholar
  110. 3.110
    E. Zdansky, A. Nilsson, H. Tillborg, O. Björneholm, N. Mårtensson, J.N. Andersen, R. Nyholm: Phys. Rev. B 48, 2632 (1993)Google Scholar
  111. 3.111
    H. Tillborg, A. Nilsson, T. Wiell, N. Wassdahl, N. Mårtensson, J. Nordgren: Phys. Rev. B 47, 16464 (1993)Google Scholar
  112. 3.112
    C.E. Moore: Atomic Energy Levels (National Bureau of Standards, Washington, DC 1949 Vol. 1Google Scholar
  113. 3.113
    C.W. Bauschlichter: J. Chem. and Phys. 84, 250 (1986)Google Scholar
  114. 3.114
    A. Bosch, H. Feil, G.A. Sawatzky, N. Mårtensson, Solid State Commun. 41, 355 (1982)Google Scholar
  115. 3.115
    J.C. Fuggle, U.E, D. Menzel, K. Wandelt, C.R. Brundle: Solid State Commun. 27, 65 (1978)Google Scholar
  116. 3.116
    E. Umbach: Surf. Sei. 117, 482 (1982)Google Scholar
  117. 3.117
    K. Schönhammer, O. Gunnarsson: Solid State Commun. 23, 691 (1977)Google Scholar
  118. 3.118
    O. Gunnarsson, K. Schönhammer: Phys. Rev. Lett. 41, 1608 (1978)Google Scholar
  119. 3.119
    P.S. Bagus, M. Seel: Phys. Rev. B 23, 2065 (1981)Google Scholar
  120. 3.120
    H.-J. Freund, E.W. Plummer: Phys. Rev. B 23, 4859 (1981)Google Scholar
  121. 3.121
    R.P. Messmer, S.H. Lamson, D.R. Salahub: Phys. Rev. B 25, 3576 (1982)Google Scholar
  122. 3.122
    H.J. Freund, F. Greuter, D. Heskett, E.W. Plummer, Phys. Rev. B 28, 1727 (1983)Google Scholar
  123. 3.123
    E. Umbach: Solid State Commun. 51, 365 (1984)Google Scholar
  124. 3.124
    H.-J. Freund, R.P. Messmer, C.M. Kao, E.W. Plummer: Phys. Rev. B 31, 4848 (1985)Google Scholar
  125. 3.125
    D. Lovric, B. Gumhalter, K. Wandelt: Surf. Sei. 278, 1 (1992)Google Scholar
  126. 3.126
    H. Tillborg, A. Nilsson, N. Mårtensson: J. Elec. Spec, and Relat. Phenom. 62, 73 (1993)Google Scholar
  127. 3.127
    O. Björneholm, A. Nilsson, E. Zdansky, A. Sandell, H. Tillborg, B. Hernnäs, N. Mårtensson, J.N. Andersen: Phys. Rev. B 47, 2308 (1993)Google Scholar
  128. 3.128
    P. Avouris, N.J. Dinardo, J.E. Demuth: J. Chem. and Phys. 80, 491 (1984)Google Scholar
  129. 3.129
    J. Burstad, C. Engkvist, S. Lunell, H. Tillborg, A. Nilsson, S. Osborne, N. Mårtensson, S. Svensson: Chem. Phys. 179, 303 (1994)Google Scholar
  130. 3.130
    O. Björneholm, A. Nilsson, E. Zdansky, A. Sandell, H. Tillborg, N. Mårtensson, J.N. Andersen, R. Nyholm: Phys. Rev. B 46, 10353 (1992)Google Scholar

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© Springer-Verlag Berlin Heidelberg 1995

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  • N. Mårtensson
  • A. Nilsson

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