Abstract
A continuous-flow chemical reactor is described which uses shock waves to effect pyrolysis of hydrocarbons for the commercial manufacture of olefins. In this reactor, heat is added to an inert carrier gas, which is cooled to sub-pyrolysis temperatures by expansion to supersonic speed, and mixed with a supersonic flow of feedstock. Deceleration of the mixture by a standing shock wave initiates pyrolysis. Short reaction durations and high pyrolysis temperatures result in higher olefin yields than are attainable with conventional reactors. A simulation of ethane pyrolysis using the shock wave reactor predicts a 20% increase in ethylene yield and a 15% decrease in energy consumption compared to conventional reactors.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Albright LF, Tsai TC (1983) Importance of surface reactions in pyrolysis units. Chapter 10 in: Albright LF et al. (eds) Pyrolysis: Theory and Industrial Practice, Academic Press NY, pp 233–254
Burch R, Tsang SC (1990) Investigation of the partial oxidation of hydrocarbons on methane coupling catalysts. Appl. Catal. 65: 259–280
Hertzberg A, Mattick AT, Russell DA (1993) Apparatus for initiating pyrolysis using a shock wave. U.S. Patent 5, 219, 530
Mattick AT, Hertzberg A, Russell DA (1991) Shock controlled reactors. In: Takayama K (ed) Shock Waves, Proc. 18th Intl. Symp. on Shock Waves, pp 1289–1294
Merkli PE (1976) Pressure recovery in rectangular constant area supersonic diffusers. AIAA J 14 (2): 168–172
Mol A (1983) Transfer line exchangers. Chapter 18 in: Albright LF et al. (eds) Pyrolysis: Theory and Industrial Practice, Academic Press NY, pp 451–471
Orriss R, Yamaguchi H (1987) Idemitsu’s Chiba ethylene plant proves modern technology. Oil and Gas J Mar 9: 27–30
Ranzi E, Dente M, Pierucci S, Barendregt S, Cronin P (1985) Coking simulation aids on-stream time. Oil and Gas J Sept 2: 49–52
Russell DA (1974) Fluid mechanics of high-power grid-nozzle lasers. AIAA Paper 74–223
Sundaram KM, Froment GF (1978) Modeling of thermal cracking kinetics 3: radical mechanisms for the pyrolysis of simple paraffins, olefins and their mixtures. Ind. Eng. Chem. Fundam. 17: 174–182
Tsai FW, Che SC, Minet RG (1985) Why retrofit furnaces? Hydrocarbon Proc. Aug: 41–47
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1995 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Mattick, A.T., Russell, D.A., Hertzberg, A., Knowlen, C. (1995). Shock-Controlled Chemical Processing. In: Brun, R., Dumitrescu, L.Z. (eds) Shock Waves @ Marseille II. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78832-1_35
Download citation
DOI: https://doi.org/10.1007/978-3-642-78832-1_35
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-78834-5
Online ISBN: 978-3-642-78832-1
eBook Packages: Springer Book Archive