Abstract
This paper describes “Hydroboration Polymerization” as a novel methodology for the preparation of organoboron polymers. A polyaddition between diene and thexylborane produced a polymer consisting of C-B bonds in the main chain. The resulting organoboron polymers can be regarded as a polymer homologue of trialkylborane and can be expected as a novel type of reactive polymers. On the other hand, hydroboration polymerization of diene with monobromoborane produced poly(organoboron halide)s as a polymeric Lewis acid. Furthermore, hydroboration polymerization of dicyano compounds such as isophthalonitrile with t-butylborane produced an air-stable boroncontaining polymer (polycyclodiborazane) having B-N four-membered rings via dimerization of iminoborane species.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Brown HC (1962) Hydroboration, Benjamin WA, Inc., New York
For example, Chung TC, Rhubright D (1991) Macromolecules, 24: 970
Chujo Y, Tornita I, Saegusa T (1993) MakromoL Chem., Macromol. Symp., 70 /71: 47
Chujo Y, Tornita I, Hashiguchi Y, Tanigawa H, Ihara E, Saegusa T (1991) Macromolecules, 24: 345
Chujo Y, Tornita I, Saegusa T (1992) Polym. Bull, 27: 375
Pelter A, Smith K, Brown HC (1988) Borane Reagents, Academic Press, London
Chujo Y, Tornita I, Hashiguchi Y, Saegusa T (1991) Macromolecules, 24: 3010
Chujo Y, Tornita I, Hashiguchi Y, Saegusa T (1991) Polym. Bull., 25: 1
Chujo Y, Tornita I, Hashiguchi Y, Saegusa T (1991) Polym. Bull., 26: 165
Chujo Y, Morimoto M, Tornita I (1993) Polym. J., 25: 891
Chujo Y, Morimoto M, Tornita I (1992) Polym. Bull., 29: 617
Chujo Y, Tornita I, Hashiguchi Y, Saegusa T (1992) Macromolecules, 25: 33
Chujo Y, Tornita I, Saegusa T (1990) Macromolecules, 23: 687
Chujo Y, Takizawa N, Sakurai T (1994) J. Chem. Soc., Chem. Commun., in press
Teach WC, Green J (1965) Encyclopedia of Polym. Sci. and Tech., 2: 581
Hawthorne MF (1962) Tetrahedron, 17: 112
Chujo Y, Tornita I, Saegusa T (1992) Macromolecules, 25: 3005
Chujo Y, Tornita I, Asano T, Saegusa T (1994) Polym. J., 26: 87
Chujo Y, Tornita I, Murata N, Mauermann H, Saegusa T (1992) Macromolecules, 25: 27
Chujo Y, Tornita I, Saegusa T (1993) Polym. Bull., 31: in press
Chujo Y, Tornita I, Saegusa T (1993) Polym. Bull., 31: in press
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1994 Springer-Verlag Berlin Heidelberg
About this paper
Cite this paper
Chujo, Y. (1994). Hydroboration Polymerization. In: Ghiggino, K.P. (eds) Progress in Pacific Polymer Science 3. Springer, Berlin, Heidelberg. https://doi.org/10.1007/978-3-642-78759-1_4
Download citation
DOI: https://doi.org/10.1007/978-3-642-78759-1_4
Publisher Name: Springer, Berlin, Heidelberg
Print ISBN: 978-3-642-78761-4
Online ISBN: 978-3-642-78759-1
eBook Packages: Springer Book Archive